Cv+R=Cp Cv is equal, oh Cv plus R is equal to Cp it's a relationship that we had up here that we wanted to prove.
我们就得到了,我们一开始,想要证明的。
Cp, I forgot to put my little bar on top here because it's per mole Cp dT that's my dq here.
上面的Cv我忘记加上横线了,因为它也是摩尔热容。
but right now you're going to have to take it for granted. So, if the Joule-Thomson coefficient is equal to zero, just like we wrote, du = Cv dT du = Cv dT for an ideal gas, we're going to dH = Cp dT have dH = Cp dT for an ideal gas as well.
但是现在请你们应该把它看成理所当然的,所以,如果焦耳-汤姆逊系数等于零,就像我们写的,对于理想气体,我们也可以得到对于理想气体。
Cv So, for Cp and Cv, these are often quantities that are measured as a function of temperature, and one could, in fact, calculate this integral.
一般Cp和,都是温度的函数,因此实际上,我们可以将这个积分计算出来。
By definition I'm going to define gamma by Cp over Cv by definition.
把Cp/Cv记作γ,这完全是定义。
T So we know that T dS/dT at constant volume is Cv over T, T and dS/dT at constant pressure is Cp, over T.
在恒定压强下定压比热容Cp乘以dT除以,所以在恒定体积下dS/dT等于Cv除以,在恒定压强下dS/dT等于Cp除以。
T It's Cp dT over T at constant pressure.
定容比热容Cv乘以dT除以。
UC So we can immediately write delta u C is Cv times T1 minus T2. Delta Hc C is Cp times T1 minus T2, right?
所以我们可以直接写出△,是Cv乘以,△HC是Cp乘以,对吧?
This is only true for an ideal gas. Since it's true for an ideal gas, then we can go ahead and replace this with Cv, and then we have Cp=Cv+R Cp with Cv plus R, which is what we were after.
常犯的一个错误,这只对理想气体成立,因为对理想气体成立,所以我们可以继续,用Cv代替,这项,最后得到。
There I have it Cp is equal to Cv plus R, right?
所以Cp=Cv+R,对吗?
Cv What do we know about the Cp and Cv?
关于Cp和?
Cv The only difference is it'll be Cp instead of Cv, B but there it is for pathway B. There it is for C a pathway C. So the state functions that we're familiar with are doing what we expect they ought to be doing, right? If you go around in a cycle, starting and ending at the same place the state functions have to stay the same.
是Cp而不是,这是路径,这是路径,所以我们熟悉的态函数的行为,正与我们预期的相同,对吧?,如果你沿着循环走一圈,开始和结束于同一个位置。
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