• He said that the percent ionic character, and this is within a bond, not for a compound, for a covalent bond.

    他提到离子百分数,是指一根键中,并非一个分子中。

    麻省理工公开课 - 固态化学导论课程节选

  • A covalent bond is any time we have a pair of electrons that is shared between two different atoms.

    所谓共价键就是我们有两个原子,共用一对电子。

    麻省理工公开课 - 化学原理课程节选

  • Likewise, the element that is a good electron acceptor in an electron transfer reaction is going to be the element that is going to hog the electrons in a covalent bond.

    同样的,这个元素在一个电子转移反应中,是个很好的受赠者它将成为在共价电子,中吸引电子的元素。

    麻省理工公开课 - 固态化学导论课程节选

  • He introduced the concept of electronegativity which was a measure, therefore, it is quantitative, of the atom's ability to attract electrons within a covalent bond and developed a scale of electronegativity.

    他引入了电负性这一概念,一个反映着原子在成共价键时吸引电子的能力的数据标度,因此这是数量上的,在共价电子中,电子原子能吸引电子,并发展为一定规模的电负性。

    麻省理工公开课 - 固态化学导论课程节选

  • Well, if it is a good electron donor in an electron transfer reaction, if the same element finds itself in a covalent bond, it is going to be a good electron donor, although it is not full transfer.

    如果它是一个在电子反应中,的好捐赠者,如果相同电子发现他在共价电子里,它将成为一个好的捐赠者,虽然没有完全转换。

    麻省理工公开课 - 固态化学导论课程节选

  • The ability of an atom to attract electrons, and in particular, in a covalent bond.

    原子对电子的吸引能力,特别是在共价键中。

    麻省理工公开课 - 固态化学导论课程节选

  • So, in fact, yes, we did confirm that these covalent bond, at least in the case of hydrogen, we have confirmed by the numbers that we are at a lower energy state when we talk about the bonded atom versus the individual atom.

    因此,事实上,是的,我们证实了共价键,至少在氢这种情况下,我们通过数据证实了,成键的原子处于能量更低的状态,当其与单个的原子相对比时。

    麻省理工公开课 - 化学原理课程节选

  • So, we see is when we use the octet rule to look at fluorine molecule, we're combining two fluorine atoms, and what we end up with is an f f molecule where they're sharing two electrons, so making that covalent bond.

    那么,我们看到把八隅体规则用到氟分子上,就是把两个氟原子组合起来,最终得到的氟分子中两个原子,共用一对电子,这就构成了共价键。

    麻省理工公开课 - 化学原理课程节选

  • OK, he also, let me see, he also, lastly, to close us out, he also developed an analytical expression for the energy of that covalent bond, which is really what we want.

    好的,他也,让我看看,他也,最终接近我们的,他也发明了一种分析方式,对于共价键能量来说,这是我们真正想要的。

    麻省理工公开课 - 固态化学导论课程节选

  • What's the definition of the covalent bond?

    共价键的定义是什么?

    麻省理工公开课 - 固态化学导论课程节选

  • So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.

    那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。

    麻省理工公开课 - 化学原理课程节选

  • So, if we look at this graph where what we're charting is the internuclear distance, so the distance between these two hydrogen atoms, as a function of energy, -- what we are going to see is a curve that looks like this -- this is the general curve that you'll see for any covalent bond, and we'll explain where that comes from in a minute.

    因此,如果我们来看一看这幅曲线图,这里我们画的横坐标是核间距,也就是这两个氢原子之间的距离,纵坐标是能量,我们看到的这是能量关于核间距的曲线-,这是一条普遍的曲线,在研究任何共价键时你都会遇到,我们马上就会解释一下它是怎么来的。

    麻省理工公开课 - 化学原理课程节选

  • When we're talking about r for internuclear distance, we're talking about the distance between two different nuclei in a bond, in a covalent bond.

    当我们说,r,代表的是核间距的时候,我们讨论的是一个距离,在一个键--一个共价键的两端的原子核之间的距离。

    麻省理工公开课 - 化学原理课程节选

  • So, that's his gift to us: the Lewis structure, and the idea that you could share electrons and form a covalent bond.

    这就Lewis给我们的礼物,Lewis结构,你能够通过公用电子,形成共价键。

    麻省理工公开课 - 固态化学导论课程节选

  • This is purely covalent because all it is is homonuclear bond energies.

    是一个完全的共价成分,他的理由是他们都是同核共价。

    麻省理工公开课 - 固态化学导论课程节选

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