Secretary Gates said that while the missile shield was never a threat to Russia, the new configuration will likely allay some of Moscow's concerns.
VOA: standard.2009.09.17
And we put up this hypothesis that our observation is that octet stability seems to be an attractive electron configuration.
我们把假设置于我们的观察之上,即8电子稳定体系,似乎是一种吸引人的电子图像。
So why don't you go ahead and identify the correct electron configuration for carbon, 6 and I'll tell you that z is equal to 6 here.
所以你们为什么不开始,而且识别碳的正确的在你们做作业方面,电子构型,我会告诉你有效电荷量是。
Six-month-olds don't, and even 12-month-olds don't find anything weird about this, while adults are sophisticated enough to understand that that's an unstable configuration and should fall over.
六个月大的婴儿则不会这么想,即使是十二个月大的婴儿,也没有发现这个木块存在的异常,只有经历世事的成年人才会理解,这不是个稳定的结构,而这个结构是会倒塌的
God's extremely peculiar configuration of the human body You read this and you realize that Samson is really on to something here Why didn't, we ask with Samson God implant the sense of sight in human beings just as he implanted the sense of touch or feeling?
还有上帝对人体极其古怪的构造,读这些你们就能意识到参孙在这确实知道一些意图,我们和参孙一样也想问,为什么上帝不让人类拥有视觉,就像让人类当初拥有触觉一样?
What we've done is taken this pitch and played it all the way down an octave below it so we're actually getting back to this configuration of the pitch right next to it, and we could--then of course we could go down one more step and we would get the octave, which is a duplication of two-to-one.
我们所做的是固定一个音高,向下一路弹奏一个八度,所以事实上我们又回到了与这个固定音高相邻的音上,我们当然也可以向下再弹一组,然后得到这个八度,这其实就是两个八度对一个八度的重复。
So if we think about what we would do to actually write out this configuration, we just write the energy levels that we see here or the orbital approximations.
如果我们考虑我们所做的去,实际写出电子构型,我们只是写出我们看到的能级,或者是轨道近似就可以了。
So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.
负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。
So let's do this considering, for example, what it would look like if we were to write out the electron configuration for oxygen where z is going to be equal to 8.
我们来做这个考虑,举例来说,如果我们写出,有效电荷量为8的氧的电子构型。
And the reason that we use it is that it is incredibly accurate, and allows us to very, very quickly predict and to predict accurately, in most cases, what the electron configuration of molecules are going to be.
我们用它是因为它极为精确,并且能让我们非常非常快地预测,而且是准确地预测,大多数情况下,分子应该具有的电子排布。
These are all isoelectronic, they all have the same electron configuration. And we can also think about going back to atomic size for a second.
这些都是等电子的,它们都有相同的电子排布,而,我们还可以再回想一下原子尺寸的概念。
So for example, if we think about fluorine, 1 s 2 2 s 2 2 p 5 that has an electron configuration of 1 s 2, 2 s 2, 2 p 5, so all we would need to do is add one more electron to get the same configuration as for neon.
比如,如果我们考虑氟原子的话,它的电子排布是,因此我们所需要做的就是给它加上一个电子,使得它与氖原子的电子排布相同。
But that's an idea of what it actually means to talk about electron configuration.
但那是一个实际了解什么是,电子构型的思路。
So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.
这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。
So, if we want to think about what the first ionization energy is of boron, what you want to do is write out the electron configuration, because then you can think about where it is that the electron's coming out of.
如果我们要考虑,硼的第一电离能,你首先要做的是写出它的电子排布,因为在这之后,你才能知道拿走的是哪里的电子。
The first thing we need to do is write the electron configuration for the atom itself, and then we need to take an electron away.
首先我们要做的是,写出原子的电子排布,然后,我们再拿走一个电子。
So, Lewis structures are really a model for a way to think about what the valence electron configuration is, and as I said, it's not based on quantum mechanics, it's something that Lewis observed far, far before quantum mechanics were discovered.
路易斯结构实际上是一个用来考虑价,电子排布的模型,而就像我说的,它并不以量子力学为基础,而是路易斯在以前发现的,在量子力学出现很早前。
And resonance is the idea that sometimes one single Lewis structure does not adequately describe the electron configuration around a given molecule, so instead you need to draw two different Lewis structures to describe that more appropriately.
而所谓共振态,就是有时候一个路易斯结构不足以,完整描述一个给定分子的电子排布,因此这时你需要同时画出两个,不同的路易斯结构来描述它,这样会更恰当。
N 2 So any chemist should be able to just look at n 2 and know that it's a triple bond, but that's not something that we've learned how did to do yet, so let's go ahead and start a new topic that's going to allow us to have some sort of sense of what the valence electron configuration, which includes whether something's a single or double or a triple bond can be figured out for any given molecule.
任何一个化学家都应该能够仅仅通过看到2,就知道它有一个三键,但是我们还没学习如何做到这点,因此下面我们就开始进入一个新的主题,它将使我们能够有一定的认识,对于价电子的排布情况,包括可以对任何一个给定分子中的键是单键双键,还是三键作出判断。
- The answer to that is definitely no -- if they had the same electron configuration, they would, in fact be neon. But we can think about different ions that have this electron configuration.
答案是绝对没有-,如果它们具有相同的电子排布,那么它们,实际上,将都是氖,但是我们可以想一想,有没有其它离子具有这种电子排布呢?
So we can go ahead and think about, well, are there any other atoms that are going to have the same electron configuration?
那么我们可以开始想一想,好,有没有其它原子,具有相同的电子排布?
We don't always want to go and solve the Schrodinger equation, and in fact, once we start talking about molecules, I can imagine none of you, as much as you love math or physics, want to be trying to solve this Schrodinger equation in that case either. So, what Lewis structures allow us to do is over 90% of the time be correct in terms of figuring out what the electron configuration is.
我们并不想每次都去解薛定谔方程,而且实际上,一旦我们开始讨论分子,我可以想象,你们中没有一个人,不管你有多么热爱数学或物理,会想去解这种情况下的薛定谔方程,总之,路易斯结构能让我们,有超过,90%,的概率判断出正确的,电子排布。
So that means that we don't have to worry about things like wave functions when we're talking about Lewis structures, but because they're so simple to use and because they so often predict the electron configuration of molecules accurately, we end up using them all the time in chemistry, so it's very valuable to know how to draw them correctly and to know how to work with them.
因此这也就意味着我们在讨论路易斯结构的时候,不需要担心波函数之类的东西,但是由于路易斯结构不仅简单易用,而且用它来预测分子的电子排布,经常可以得到非常精确的结果,结果我们在化学中一直都在用它,因此知道如何正确地画出并运用,路易斯结构是非常有价值的。
So, for example, if we needed to figure out the electron configuration for titanium, 4s2 it would just be argon then 4 s 2, 3d2 and then we would fill in the 3 d 2.
所以举个例子,如果我们需要解出钛的电子构型,它会是Ar然后,然后我们填充。
So, if we take h 2, and we want to draw the electron configuration, it's very short.
如果我们取h2,我们要画电子构型,这很简单。
So, no matter whether or not you write out the full form here, or the noble gas configuration where you write ne first or whatever the 3s1 corresponding noble gas is to the core electrons, we always write out the valence electrons here.
所以无论你是否,写出了完整形式,或者对应于价电子的惰性气体,再一次,我们可以写Ne然后,我们总是可以在这里写出价电子。
I don't care how you do it on exams or on problem sets, but you do need to be aware that the 3 d once filled is lower in energy than the 4 s, and the reason you need to be aware of that is if you're asked for the electron configuration now of the titanium ion.
我不关心你们在考试或者,问题集中如何做它,但是你们的确需要知道3d一旦被填充,它的能量是小于4s的,你们需要知道这个的原因,是如果你现在被要求,写出钛离子的电子构型。
应用推荐