So let's figure out the bond order for our two molecules here that we figured out the electron configuration for.
让我们看看这里,两个分子的键序是多少。
So why don't you go ahead and identify the correct electron configuration for carbon, 6 and I'll tell you that z is equal to 6 here.
所以你们为什么不开始,而且识别碳的正确的在你们做作业方面,电子构型,我会告诉你有效电荷量是。
So let's do this considering, for example, what it would look like if we were to write out the electron configuration for oxygen where z is going to be equal to 8.
我们来做这个考虑,举例来说,如果我们写出,有效电荷量为8的氧的电子构型。
The first thing we need to do is write the electron configuration for the atom itself, and then we need to take an electron away.
首先我们要做的是,写出原子的电子排布,然后,我们再拿走一个电子。
So, in this one we're selecting the correct electronic configuration for an ion.
那么,这次我们要做的是,选出一个离子正确的电子排布。
So, for example, if we needed to figure out the electron configuration for titanium, 4s2 it would just be argon then 4 s 2, 3d2 and then we would fill in the 3 d 2.
所以举个例子,如果我们需要解出钛的电子构型,它会是Ar然后,然后我们填充。
So this is our valence electron configuration for b 2.
这是B2的价电子构型。
The electronic configuration, all it is is the shorthand notation for that one electron approximation for the Schrodinger equation for lithium.
电子构型就是,对于锂的薛定谔方程,的单电子近似的,简化形式。
So here's the pneumonic I mentioned for writing the electron configuration and getting those orbital energies in the right order.
这里是我提到的,对于写电子构型,和以正确的顺序得到轨道能量。
So it looks like most of you got that the electron configuration that we're writing here is for copper.
看来大多数人,都看出了,这是铜原子的电子排布。
So we can write out what the electron configuration is here, and I think that I have already written that out for you in your notes.
我们可以在这里写出电子构型,我觉得我已经在你们,讲义上写出来了。
And we can also write this in an even simpler form, which is what's called electron configuration, and this is just a shorthand notation for these electron wave functions.
而且我们也可以将它,写为一个更简单的形式,它叫做电子构型,这个仅仅是这些电子波函数的。
So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.
负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。
These are all isoelectronic, they all have the same electron configuration. And we can also think about going back to atomic size for a second.
这些都是等电子的,它们都有相同的电子排布,而,我们还可以再回想一下原子尺寸的概念。
And again, I've written for you, but you can figure out what the electron configuration is just by writing up in this order here.
同样,我已经写出来了,但你们可以把这个写出来,就知道电子轨道构型是什么。
And I know there's a lot to talk about this competition, but let's just get into listening mode here and talk about how we can figure out what the correct electron configuration is for this ion.
我知道刚才关于这次比赛大家有很多话要聊,但是请大家先转换到听讲的模式,来看看如何才能弄清楚,这个离子正确的电子排布。
So for example, if we think about fluorine, 1 s 2 2 s 2 2 p 5 that has an electron configuration of 1 s 2, 2 s 2, 2 p 5, so all we would need to do is add one more electron to get the same configuration as for neon.
比如,如果我们考虑氟原子的话,它的电子排布是,因此我们所需要做的就是给它加上一个电子,使得它与氖原子的电子排布相同。
So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.
这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。
So, Lewis structures are really a model for a way to think about what the valence electron configuration is, and as I said, it's not based on quantum mechanics, it's something that Lewis observed far, far before quantum mechanics were discovered.
路易斯结构实际上是一个用来考虑价,电子排布的模型,而就像我说的,它并不以量子力学为基础,而是路易斯在以前发现的,在量子力学出现很早前。
N 2 So any chemist should be able to just look at n 2 and know that it's a triple bond, but that's not something that we've learned how did to do yet, so let's go ahead and start a new topic that's going to allow us to have some sort of sense of what the valence electron configuration, which includes whether something's a single or double or a triple bond can be figured out for any given molecule.
任何一个化学家都应该能够仅仅通过看到2,就知道它有一个三键,但是我们还没学习如何做到这点,因此下面我们就开始进入一个新的主题,它将使我们能够有一定的认识,对于价电子的排布情况,包括可以对任何一个给定分子中的键是单键双键,还是三键作出判断。
So let's think about what this valence electron configuration is for c 2.
让我们来看一下C2的,价电子构型是怎么样的。
I don't care how you do it on exams or on problem sets, but you do need to be aware that the 3 d once filled is lower in energy than the 4 s, and the reason you need to be aware of that is if you're asked for the electron configuration now of the titanium ion.
我不关心你们在考试或者,问题集中如何做它,但是你们的确需要知道3d一旦被填充,它的能量是小于4s的,你们需要知道这个的原因,是如果你现在被要求,写出钛离子的电子构型。
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