• "But the size and configuration of this facility is inconsistent with a peaceful program."

    VOA: standard.2009.09.25

  • if we're actually thinking about electron configuration and we look at lithium, sodium and potassium, these all have one valence electron.

    让我们来想一想,锂,钠,钾的电子排布,它们都只有一个价电子。

    麻省理工公开课 - 化学原理课程节选

  • So here's the pneumonic I mentioned for writing the electron configuration and getting those orbital energies in the right order.

    这里是我提到的,对于写电子构型,和以正确的顺序得到轨道能量。

    麻省理工公开课 - 化学原理课程节选

  • Six-month-olds don't, and even 12-month-olds don't find anything weird about this, while adults are sophisticated enough to understand that that's an unstable configuration and should fall over.

    六个月大的婴儿则不会这么想,即使是十二个月大的婴儿,也没有发现这个木块存在的异常,只有经历世事的成年人才会理解,这不是个稳定的结构,而这个结构是会倒塌的

    耶鲁公开课 - 心理学导论课程节选

  • And we put up this hypothesis that our observation is that octet stability seems to be an attractive electron configuration.

    我们把假设置于我们的观察之上,即8电子稳定体系,似乎是一种吸引人的电子图像。

    麻省理工公开课 - 固态化学导论课程节选

  • And we talked about a triad being a configuration of three pitches where you take the first, the third and the fifth.

    三和弦是由三个音高配置成的,你们可选取第一,第三和第五个音。

    耶鲁公开课 - 聆听音乐课程节选

  • God's extremely peculiar configuration of the human body You read this and you realize that Samson is really on to something here Why didn't, we ask with Samson God implant the sense of sight in human beings just as he implanted the sense of touch or feeling?

    还有上帝对人体极其古怪的构造,读这些你们就能意识到参孙在这确实知道一些意图,我们和参孙一样也想问,为什么上帝不让人类拥有视觉,就像让人类当初拥有触觉一样?

    耶鲁公开课 - 弥尔顿课程节选

  • Then something that you probably have a lot of experience with is talking about electron configuration and writing out the electron configuration.

    然后有一些事情是,你们可能有较多经验,那就是讨论电子构型以及,写出它们。

    麻省理工公开课 - 化学原理课程节选

  • So why don't you go ahead and identify the correct electron configuration for carbon, 6 and I'll tell you that z is equal to 6 here.

    所以你们为什么不开始,而且识别碳的正确的在你们做作业方面,电子构型,我会告诉你有效电荷量是。

    麻省理工公开课 - 化学原理课程节选

  • And the reason that we use it is that it is incredibly accurate, and allows us to very, very quickly predict and to predict accurately, in most cases, what the electron configuration of molecules are going to be.

    我们用它是因为它极为精确,并且能让我们非常非常快地预测,而且是准确地预测,大多数情况下,分子应该具有的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • These are all isoelectronic, they all have the same electron configuration. And we can also think about going back to atomic size for a second.

    这些都是等电子的,它们都有相同的电子排布,而,我们还可以再回想一下原子尺寸的概念。

    麻省理工公开课 - 化学原理课程节选

  • And again, I've written for you, but you can figure out what the electron configuration is just by writing up in this order here.

    同样,我已经写出来了,但你们可以把这个写出来,就知道电子轨道构型是什么。

    麻省理工公开课 - 化学原理课程节选

  • ns2p6 And,electron configuration is always ns2p6.

    而且,电子构造总是。

    麻省理工公开课 - 固态化学导论课程节选

  • So, as an example, let's take argon, I've written up the electron configuration here, and let's think about what some of the similarities might be between wave functions in argon and wave functions for hydrogen.

    所以作为一个例子我们来看看氩,我已经把它的电子构型写在这里,我们来考虑氩和,氢波函数之间的,一些相似性。

    麻省理工公开课 - 化学原理课程节选

  • And I know there's a lot to talk about this competition, but let's just get into listening mode here and talk about how we can figure out what the correct electron configuration is for this ion.

    我知道刚才关于这次比赛大家有很多话要聊,但是请大家先转换到听讲的模式,来看看如何才能弄清楚,这个离子正确的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • The first thing we need to do is write the electron configuration for the atom itself, and then we need to take an electron away.

    首先我们要做的是,写出原子的电子排布,然后,我们再拿走一个电子。

    麻省理工公开课 - 化学原理课程节选

  • Let's move on to the last topic in terms of this first exam, which is thinking about the idea of isoelectronic atoms, or isoelectronic ions. And isoelectronic is very straightforward, it just means having the same electron configuration.

    下面我们继续讲第一次考试的最后一个主题,也就是等电子原子,或等电子离子的概念,“等电子的“是非常直接的表达,它的意思就是具有相同电子排布的。

    麻省理工公开课 - 化学原理课程节选

  • So, Lewis structures are really a model for a way to think about what the valence electron configuration is, and as I said, it's not based on quantum mechanics, it's something that Lewis observed far, far before quantum mechanics were discovered.

    路易斯结构实际上是一个用来考虑价,电子排布的模型,而就像我说的,它并不以量子力学为基础,而是路易斯在以前发现的,在量子力学出现很早前。

    麻省理工公开课 - 化学原理课程节选

  • And resonance is the idea that sometimes one single Lewis structure does not adequately describe the electron configuration around a given molecule, so instead you need to draw two different Lewis structures to describe that more appropriately.

    而所谓共振态,就是有时候一个路易斯结构不足以,完整描述一个给定分子的电子排布,因此这时你需要同时画出两个,不同的路易斯结构来描述它,这样会更恰当。

    麻省理工公开课 - 化学原理课程节选

  • What we've done is taken this pitch and played it all the way down an octave below it so we're actually getting back to this configuration of the pitch right next to it, and we could--then of course we could go down one more step and we would get the octave, which is a duplication of two-to-one.

    我们所做的是固定一个音高,向下一路弹奏一个八度,所以事实上我们又回到了与这个固定音高相邻的音上,我们当然也可以向下再弹一组,然后得到这个八度,这其实就是两个八度对一个八度的重复。

    耶鲁公开课 - 聆听音乐课程节选

  • So we can write out what the electron configuration is here, and I think that I have already written that out for you in your notes.

    我们可以在这里写出电子构型,我觉得我已经在你们,讲义上写出来了。

    麻省理工公开课 - 化学原理课程节选

  • So, that's actually the electron configuration we have when we're talking about copper and some other exceptions in the periodic table that you're going to be looking at.

    因此,这才是铜原子真正的电子排布,而且我们在元素周期表中,会看到与铜原子类似的,其他例外的情况。

    麻省理工公开课 - 化学原理课程节选

  • And we can also write this in an even simpler form, which is what's called electron configuration, and this is just a shorthand notation for these electron wave functions.

    而且我们也可以将它,写为一个更简单的形式,它叫做电子构型,这个仅仅是这些电子波函数的。

    麻省理工公开课 - 化学原理课程节选

  • So we can go ahead and think about, well, are there any other atoms that are going to have the same electron configuration?

    那么我们可以开始想一想,好,有没有其它原子,具有相同的电子排布?

    麻省理工公开课 - 化学原理课程节选

  • s 2 2 s 2 2 p 6 This has the electron configuration of 1 s 2, 2 s 2, and 2 p 6.

    它的电子排布是。

    麻省理工公开课 - 化学原理课程节选

  • So that means that we don't have to worry about things like wave functions when we're talking about Lewis structures, but because they're so simple to use and because they so often predict the electron configuration of molecules accurately, we end up using them all the time in chemistry, so it's very valuable to know how to draw them correctly and to know how to work with them.

    因此这也就意味着我们在讨论路易斯结构的时候,不需要担心波函数之类的东西,但是由于路易斯结构不仅简单易用,而且用它来预测分子的电子排布,经常可以得到非常精确的结果,结果我们在化学中一直都在用它,因此知道如何正确地画出并运用,路易斯结构是非常有价值的。

    麻省理工公开课 - 化学原理课程节选

  • So, for example, if we needed to figure out the electron configuration for titanium, 4s2 it would just be argon then 4 s 2, 3d2 and then we would fill in the 3 d 2.

    所以举个例子,如果我们需要解出钛的电子构型,它会是Ar然后,然后我们填充。

    麻省理工公开课 - 化学原理课程节选

  • So, if we take h 2, and we want to draw the electron configuration, it's very short.

    如果我们取h2,我们要画电子构型,这很简单。

    麻省理工公开课 - 化学原理课程节选

  • I don't care how you do it on exams or on problem sets, but you do need to be aware that the 3 d once filled is lower in energy than the 4 s, and the reason you need to be aware of that is if you're asked for the electron configuration now of the titanium ion.

    我不关心你们在考试或者,问题集中如何做它,但是你们的确需要知道3d一旦被填充,它的能量是小于4s的,你们需要知道这个的原因,是如果你现在被要求,写出钛离子的电子构型。

    麻省理工公开课 - 化学原理课程节选

  • So if we write the electron configuration you see that this is the electron configuration here, 1s22s22p 1 s 2, 2 s 2, 2 p 6, 3s1 and now we're going into that third shell 3 s 1.

    现在我们来到第三层,你们会看到3s1价电子之间的区别,电子构型是,现在我们来到第三层。

    麻省理工公开课 - 化学原理课程节选

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