Maximum,meaning the most. And ion,which is an atom or group of atoms with an electrical charge.

VOA: special.2010.05.30

And in this case, the tie-breaker goes to the molecule in which the negative charge is on the most electronegative atom.

而在这种情况下，我们需要进行“附加赛“,也就是看看分子中带有负的,形式电荷的原子是不是电负性最高的。

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So why don't you tell me what the formal charge should be on the sulfur atom of thionyl chloride?

那么请大家来告诉我亚硫酰氯中,的硫原子应该有多少形式电荷？

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So, I've got this tiny volume with, in the case of gold 79 plus of charge, and I've got some electrons out here somewhere, and the vast majority of the atom is nothing.

我认为这个小体积里面，比如金的79个正电荷，电子在外面的某些地方，原子里面大部分是空心的。

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So that means that the more stable molecule is going to be this molecule here, which actually puts the negative charge on be more electronegative atom.

因此这意味着更稳定的分子,应该是这一个，它真正把负的电荷放到了,电负性更高的原子上。

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It turns out, and we're going to get the idea of shielding, so it's not going to actually +18 feel that full plus 18, but it'll feel a whole lot more than it will just feel in terms of a hydrogen atom where we only have a nuclear charge of one.

结果是我们会有,屏蔽的想法,所以它不会是完整的，但是它会比原子核电荷量,吸引力要大很多,只有1的氢原子的。

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So even if we strip an atom of all of its electrons, we still have that same amount of positive charge in the nucleus.

所以即使把一个原子的所有电子都拿走,原子核还是带那么多的正电。

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So when we talk about formal charge, basically formal charge is the measure of the extent to which an individual atom within your molecule has either gained or lost an electron.

说到形式电荷，基本上形式电荷就是,单个原子在形成分子之后,是得到了电子还是失去了电子的一种量度。

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So, the question then is what is the spatial distribution of charge inside the atom?

因此，接下来的问题是,原子内部的电荷,在空间如何分布？

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And what's important to keep in mind about formal charge is if we have a neutral atom, such as we did in thionyl chloride here, the sum of the individual formal charges on individual atoms within the molecule have to equal 0.

而关于形式电荷记住一点是很重要的,那就是如果我们有一个中性原子，比如亚硫酰氯，那么这个分子中的所有原子的,形式电荷之和应该等于零。

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So when we talk about the size of multi-electron orbitals, they're actually going to be smaller because they're being pulled in closer to the nucleus because of that stronger attraction because of the higher charge of the nucleus in a multi-electron atom compared to a hydrogen atom.

所以当我们讨论,多电子轨道的尺寸，它们实际上会变得更小,因为多电子原子的原子核,相比于氢原子,有更高的电荷量所以,有更强的吸引力,所以可以拉的更近。

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Often a good thing to start with is to put the lowest ionization energy atom in the middle, and if you don't have charge separation then go with that structure, but if you do find you have a lot of separation, such as the case in negative 2, positive 2, and minus 1, then you want to say wait a second, this is really bad in terms of formal charge, let me go ahead and see what other options I have here.

通常一开始把电离能最低的原子,放在中心位置就很好了，如果你发现电荷没有分开,那么这个结构就没问题了，但是如果你发现有很多分开的电荷，比如这种情况，有负二，正二和负一，那么你会想要说等一下，从形式电荷来看这很不好，让我去看看其它可能的选择。

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So, let's say we have an atomic number of 3, 3 that means we have 3 electrons, so we better hope to get our neutral atom that we have a charge of plus 3in the nucleus.

这也是很合理的，因为Z就是原子序数，假设原子序数是，那就有3个电子，那我们就希望,性原子有个带3个正电荷的原子核。

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