• The researchers found the presence of carbon thirteen, a version of the carbon atom that is usually found in space.

    VOA: special.2009.09.30

  • PROFESSOR: All right, start again, what's the hybridization of the carbon atom?

    好了,再说一遍,碳原子的杂化轨道是什么?

    麻省理工公开课 - 化学原理课程节选

  • So again, if we think about that shape of that carbon atom, it's going to be trigonal planar, 120° it's going to have bond angles of 120 degrees, because we have this set up of having three hybrid orbitals.

    如果我们考虑碳原子的形状,它是平面三角形,键角是,因为我们有这三个杂化轨道。

    麻省理工公开课 - 化学原理课程节选

  • So if you picture this as our s p 2 carbon atom where we have three hybrid orbitals, and then one p y orbital coming right out at us.

    如果你把这想象成sp2碳原子,这里有3个杂化轨道,然后一个py轨道朝向我们。

    麻省理工公开课 - 化学原理课程节选

  • If we have, coming along this z axis, another carbon atom, we can actually form one bond between the two carbon atoms there.

    如果我们在z方向,有另外一个碳原子,我们可以在,两个碳原子之间形成一个键。

    麻省理工公开课 - 化学原理课程节选

  • All right, so in terms of s p 3 hybrid orbitals, let's combine all four together on one axis, because this is what's going to happen in an s p 3 carbon atom.

    对于sp3杂化轨道,让我们把4个结合起来,因为这是sp3碳原子中发生的情况。

    麻省理工公开课 - 化学原理课程节选

  • So essentially, we have two ethene or ethylene molecules here to start with where these blue are our 2 s p 2 hybrid orbitals, so you can see that for each carbon atom, one is already used up binding to another carbon atom.

    本质上,我们从两个乙烯分子开始,蓝色的是2sp2杂化轨道,你可以看到,对于每一个碳原子,其中一个已经用来和另外一个碳原子成键。

    麻省理工公开课 - 化学原理课程节选

  • So if we take our carbon atom here, which has two electrons in the 2 s orbital, and we promote one of these electrons into a 2 p orbital, what we see now is that yes, we do, we have four unpaired electrons.

    这是碳原子,2s轨道里有两个电子,我们把一个电子激发到2p轨道里,我们看到现在,是的,我们有4个未配对电子。

    麻省理工公开课 - 化学原理课程节选

  • So in terms of the first step of skeletal structure, this is actually going to be easier because we don't have a central atom, we just have carbon and nitrogen here.

    对于第一步画出骨架,其实比刚才更容易,因为我们没有一个中心原子,我们这里只有碳和氮两个原子。

    麻省理工公开课 - 化学原理课程节选

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