• So in terms of the first step of skeletal structure, this is actually going to be easier because we don't have a central atom, we just have carbon and nitrogen here.

    对于第一步画出骨架,其实比刚才更容易,因为我们没有一个中心原子,我们这里只有碳和氮两个原子。

    麻省理工公开课 - 化学原理课程节选

  • However, for carbon and nitrogen we need 8 each.

    但是,对于碳和氮,我们都需要八个电子。

    麻省理工公开课 - 化学原理课程节选

  • What about between the carbon and nitrogen?

    那么碳和氮之间呢?

    麻省理工公开课 - 化学原理课程节选

  • So, in order to fill our octet, what we do is put two on the nitrogen and two on the carbon.

    因此,为了填满我们的“八隅体“,我们需要将两个放到氮上,将另外两个放到碳上。

    麻省理工公开课 - 化学原理课程节选

  • So, shared electrons are the ones that are shared between the carbon and the nitrogen, so we have 6 shared electrons, and we want to take 1/2 of that.

    共用电子是那些在碳和氮之间,被它们共用的电子,那么我们有六个共用电子,然后我们要给它乘上二分之一。

    麻省理工公开课 - 化学原理课程节选

  • This is very easy molecule because we know exactly where to put them without even having to think, we only have one option, and we'll make a triple bond between the carbon and the nitrogen.

    这个分子非常简单,因为我们知道应该把它们放在哪里,甚至不用去想,我们只有一个选择,我们将在碳与氮之间形成一个三键。

    麻省理工公开课 - 化学原理课程节选

  • 090 We have 1,090 for carbon, 1000 1,000 for sulfur, 1400 and 1,400 for nitrogen.

    碳的是,硫的是,而氮的是。

    麻省理工公开课 - 化学原理课程节选

  • So we can put actually all 4 of our extra electrons in between the carbon and the nitrogen.

    因此我们可以把这剩下的,四个电子都放在碳和氮之间。

    麻省理工公开课 - 化学原理课程节选

  • Now we have 6 things around the nitrogen, and we have 8 around the carbon.

    现在我们有六个成键电子在氮周围,有八个在碳周围。

    麻省理工公开课 - 化学原理课程节选

  • So that takes care of the hydrogen, what about between the carbon and the nitrogen?

    因此氢就被排除了,那么碳和氮呢?

    麻省理工公开课 - 化学原理课程节选

  • And what you find out if you do these calculations, is that you have a negative 1 for your formal charge on nitrogen, you have a negative 2 for your formal charge on carbon, and you have a positive 2 for your formal charge on sulfur.

    而如果你做了这些计算会发现,氮的形式电荷量为负一,碳的形式电荷量为负二,而硫的形式电荷量为正二。

    麻省理工公开课 - 化学原理课程节选

  • If we look at our last structure here where we have nitrogen the middle, we can also figure out all those formal charges, and in this case we have plus 1 on the nitrogen, we have minus 2 on the carbon, and then we end up with a 0 on the sulfur there.

    如果我们来看看最后一个结构,在中间的原子是氮,我们同样可以计算出所有的形式电荷,而在这种情况下,氮为正一,碳为负二,而最后硫为零。

    麻省理工公开课 - 化学原理课程节选

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