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For the simple reason that the number of possible chess games is so huge, that computers can't calculate it.
原因很简单,棋局的潜在变数相当之大,以至于计算机根本无法将其完全计算出来
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And an electron is something where, i n fact, we might be able to, if we calculate it and see how that works out, actually observe some of its wave-like properties.
如果我们对电子做计算,并且知道如何算出来的,那么我们是可以观测到,电子的一些波动性质的。
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Now remember, we went through before how it's a state function but to calculate it, you'd need to find a reversible path, along which you can figure this out.
请记住，我们不需要知道它是怎样的一个态函数,只计算就可以了，你需要找到一条可逆路径，沿着这条路径就能算得这个结果。
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It uses the binomial distribution to calculate the probability of getting any specific number of accidents.
保险公司就可以用二项分布公式,来计算特定数目事故发生的概率
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So, for example, you know, I'm going to calculate next when it hits the ground.
比如说,我下面要来算,物体何时落地
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Often, for a particular state change, it is easy to calculate two of these, but not the third.
对于一些特定的状态变化，它们中的两个很好计算，但是第三个往往不容易计算。
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This is going to be probably a homework at some point to do this. For now, let's take it for granted. Let's take it for granted that we know how to calculate this derivative from an equation of state like this.
这可能是将来的一个课后作业,现在，请把这当成理所当然的，理所当然地认为我们,知道怎样从一个状态,方程计算这样的微分式。
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We haven't actually learned how to calculate the formal charge yet, we'll learn it soon.
实际上我们还没学如何计算形式电荷，我们很快就会学到了。
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All right. So let's test what we, in fact, know about the photoelectric effect, and before we do that actually, we're going to calculate what we would predict, so when we do the demo it will be meaningful and we can tell whether we're successful or not.
好的，我们来测试一些，我们实际上懂了,多少光电效应的东西，在我们做测试之前，我们先算一下我们能预知什么，这样我们做的测试会很有意义,并且也知道我们是否成功了。
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Here is what we calculate to tell whether it happens spontaneously.
这就是我们所需要计算的物理量,它能够告诉我们变化是否会自发发生。
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What it means is if you'd release a rock at that location one second before with a certain speed that we can calculate, it would've ended up here with precisely the position and velocity it had at the beginning of our experiment.
它的意义在于,若在该处以特定速度抛出一个物体,这个速度可通过计算得到,一秒之后,物体会运动至我们设定的起点,并且速度为我们设定的初速度
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If we want to know the total heat added to the system, we can measure it, which is the straightforward thing, but sometimes you want to calculate in advance, or sometimes you want to calculate it on an exam.
如果想知道给系统的总热量，我们可以测量，这是很直接的事情，但有时候我们想事先计算它，或者需要在考试中计算。
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So we know how to calculate it. Make sense?
我们知道如何计算这个物理量，对吗？
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So, it's very easy to calculate, however, the number of radial nodes, and this works not just for s orbitals, but also for p orbitals, or d orbitals, or whatever kind of work of orbitals you want to discuss.
径向节点，的数量，这不仅对s轨道适用，对p轨道，d轨道，或者任何你们想讨论的轨道，都是适用的,它就等于。
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We can measure the heat capacity at constant volume, and now we have another term, and if we can figure out how to measure it, we'll have a complete form for this differential du which will enable us to calculate du for any process.
我们能够测量恒定体积下的热容，这里我们有另一项，如果能够知道怎么测量它，问我们就有了这个完整的微分式,就能够对任何过程计算。
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Just like u, we'd like to be able to express it in a way that allows us to calculate what happens only from equation of state data.
就像内能u一样，我们希望能够利用状态方程的数据,计算出其表达式,这些表达式能方便我们说出即将发生的过程。
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All right, so now let's see how we execute it, and do the calculations that allow us to calculate this. So, one, what's delta H in step one?
好，现在我们看看怎样操作它，怎样进行计算，第一步,步骤I的ΔH是多少？
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So let's do a sample calculation now using this Rydberg formula, and we'll switch back to emission, and the reason that we'll do that is because it would be nice to actually approve what we just saw here and calculate the frequency of one of our lines in the wavelength of one of the lines we saw.
让我们用Rydberg公式,做一个例题，我们回到发射上,这么做是因为这样,可以用我们看到的波长,来验证我们计算的频率。
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And what he came out with when he did some calculations is that there's the radius that he could calculate was equal to this number a sub nought, which is what we call the Bohr radius, and it turns out that the Bohr radius happens to be the radius most probable for a hydrogen atom.
等于这个a0的值,我们叫它波尔半径，而,波尔半径恰好是,最容易，找到电子的地方，我们对波尔模型,不做过多的解释,这是因为。
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