• And if we put that in our bond here, we have 1, 2, 3 bonds, plus we have one lone pair left over.

    如果我们把它们放到键里,我们有1,2,3个键,还剩下一对孤对在这里。

    麻省理工公开课 - 化学原理课程节选

  • /2 So the bond order is going to be equal to 1/2, and then it will be 2 minus 2.

    它的键序等于,然后乘以2减去2。

    麻省理工公开课 - 化学原理课程节选

  • The price of the two-period bond is 1/2 and the price of the one-period bond is 1/.

    所以两年期债券的价格是1/^2,一年期债券的价格则是1/

    耶鲁公开课 - 金融市场课程节选

  • This means it is not a strict bond one-to-one.

    这意味着不是严格11的键。

    麻省理工公开课 - 固态化学导论课程节选

  • Let's re-draw this, so it looks a little bit neater, where we have a triple bond in the middle instead, and again, we need our negative 1 charge there.

    让我们重写这个,这样看起来更整洁一点,我们有一个三键在中间,同样地,我们这里需要一个负电荷。

    麻省理工公开课 - 化学原理课程节选

  • Then minus 1/2 of 2, because we only have one bond or 2 electrons in a bond.

    然后减去二的二分之一,因为我们只有一个键,一个键就是两个电子。

    麻省理工公开课 - 化学原理课程节选

  • So we know that it's 1, because we have 1, 2, 3, 4 bonding, minus 2 anti-bonding, and 1/2 of that is a bond order of 1.

    我们知道它是,因为我们有1,2,3,4个成键,减去2个反键,它的一半就是键序为1

    麻省理工公开课 - 化学原理课程节选

  • For hydrogen our bond order is going to equal 1/2, 2 minus 0.

    对于氢原子键序等于1/2,2减去。

    麻省理工公开课 - 化学原理课程节选

  • So it's going to be a sigma bond, 1s and we have oxygen 2 s p 3 and hydrogen 1 s.

    它是sigma键,我们有氧2sp3和氢。

    麻省理工公开课 - 化学原理课程节选

  • /2 So this would mean the bond order is equal to 1/2, and in terms of valence electrons, how many bonding valence electrons do we have?

    这意味着键序等于,对于价电子,有多少个成键价电子?

    麻省理工公开课 - 化学原理课程节选

  • So for the bond order we want to take 1/2 of the total number of bonding electrons, so that's going to be 4 minus anti-bonding is 4, so we end up getting a bond order that's equal to 0.

    键序等于1/2乘以,总的成键电子数,也就是4,减去反键电子数,也就是4。,所以最后得到键序为0。

    麻省理工公开课 - 化学原理课程节选

  • /2 PROFESSOR: Yup, it's going to be a 1 and 1/2 bond.

    嗯,是11/2。它是1又。

    麻省理工公开课 - 化学原理课程节选

  • What kind of a bond is a bond order of 1?

    什么样的键键序是1

    麻省理工公开课 - 化学原理课程节选

  • But since in drawing Lewis structures actually, in some cases you do, you can draw a dotted line that means a 1 and 1/2 bond, but most in most cases, we just draw out both resonance structures, and the way that we say it's a resonance structure is that we put it in the brackets and we put an arrow between it.

    但是由于在画路易斯结构时,其实,在某些情况下是可以的,你可以画一条虚线来表示一又二分之一键,但是在多数情况下,我们就把两个结构都画出来,而我们说这是一个共振结构的表示的方法是,把它们放在括号里,并在中间放一个双箭头。

    麻省理工公开课 - 化学原理课程节选

  • r1 is the yield on the one-period bond and r2 is the yield on the two-period bond.

    1是一年期债券的收益率,r2则是两年期债券的收益率

    耶鲁公开课 - 金融市场课程节选

  • The way that we can figure this out is using something called bond order, and bond order is equal to 1/2 times the number of bonding electrons, minus the number of anti-bonding electrons.

    我们可以用叫做,键序的概念来弄明白它,键序等于1/2乘以成键电子,数目减去反键电子数目。

    麻省理工公开课 - 化学原理课程节选

  • And the bond order you get out will either be, for example, zero, which would mean that you have no bond, 5 or you could have 1, a single bond, 1 . 5, a 1 and 1/2 bond, 2, a double bond, and so on.

    你得到的键序要么是比如说是零,这意味着没有键,或者你会得到1,单键1。,1又二分之一键,2,一个双键,等等等等。

    麻省理工公开课 - 化学原理课程节选

  • It's a 1 and 1/2 because it's halfway between a double bond and a single bond.

    是因为它介于,单键和双键中间。

    麻省理工公开课 - 化学原理课程节选

  • So we would predict a bond order of 1.

    所以我们预测键序是。

    麻省理工公开课 - 化学原理课程节选

  • So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.

    所以它是沿着键轴方向的,而且这里是一个碳sp2杂化轨道,和一个氢的1s轨道的结合,在这里我们可以合并他们。

    麻省理工公开课 - 化学原理课程节选

  • The reason that it's a sigma bond is sp3 because the s p 3 hybrid orbital is directly interacting with the 1 s orbital of the hydrogen atom, and that's going to happen on the internuclear axis, they're just coming together.

    它是sigma键的原因,是因为,杂化轨道直接和氢原子1s轨道相互作用,它们作用发生在核间轴上,它们会到一起。

    麻省理工公开课 - 化学原理课程节选

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