So, why don't you go ahead and tell me, keeping that in mind, which atom in terms of h c or n would you expect to be in the center of hydrogen cyanide?

那么，请大家来告诉我，并且记住它，你认为氢，碳和氮中哪个原子,应该在氰化氢的中间呢？

麻省理工公开课 - 化学原理课程节选

That energy will be absorbed by the hydrogen atom, n=1 the electron will rise from n equals one n=2 to n equals two.

这能量将会被氢原子吸收，这个电子会从,上升到。

麻省理工公开课 - 固态化学导论课程节选

So, that also tells us that the n minus ion is less stable than the neutral atom itself.

而且，这还告诉我们,负一价的氮离子不如中性氮原子稳定。

麻省理工公开课 - 化学原理课程节选

n l m s Once we have chosen a certain mix of n, l, m and s, it is used once for that particular atom.

一旦我们选定了一组量子数，它就只能被一个固定原子所有。

麻省理工公开课 - 固态化学导论课程节选

So another way to say that is, in a sense, if we're thinking about the excited state of a hydrogen atom, the first excited state, or the n equals 2 state, what we're saying is that it's actually bigger than the ground state, or the 1 s state of a hydrogen atom.

换句话说，如果我们激发一个氢原子，第一激发态或者说ｎ等于２的态，我们说它比氢原子基态,或者说１ｓ态要大。

麻省理工公开课 - 化学原理课程节选

And I want to really highlight here we're talking about for a hydrogen atom orbitals - with the same n value have the same energy.

我想强调的是,我们所说的,都是对单个的氢原子,和言的,对于同样的n值能量相同。

麻省理工公开课 - 化学原理课程节选

That's why in the earlier models of the atom, they're not horrible to sometimes think about just each n value as a little ring around.

这就是为什么在早期原子模型中，人们没有感觉到把每一个，n，都想象成,一个绕核的小圆圈有什么不妥。

麻省理工公开课 - 化学原理课程节选

So in talking about the hydrogen atom, they actually have different names for different series, which means in terms of different n values that we end in.

所以就氢原子来说，它的每个系都有不同的名字，代表了不同的末态n值。

麻省理工公开课 - 化学原理课程节选

So what we'll do is this problem here, which is let's calculate out what the wavelength of radiation n would be emitted from a hydrogen atom if we start at the n equals 3 level and we go down to the n equals 2 level.

我们来做这个问题,让我们来计算一下,从n等于3到,等于2能级氢原子辐射的波长是多少。

麻省理工公开课 - 化学原理课程节选

We're going to get to more complicated atoms eventually where we're going to have more than one electron in it, but when we're talking about a single electron atom, we know that the binding energy is equal to the negative of the Rydberg constant over n squared, so it's only depends on n.

我们以后会讲到，更加复杂的情况,那时候,不只有一个原子，但当我们讲，单个原子的时候，我们知道结合能，等于,负的Rydberg常数,除以n平方，所以它仅仅由n决定的。

麻省理工公开课 - 化学原理课程节选

But there's something you'll note here also when I point out the case of the 2 s versus the 2 p, which is what I mentioned that I would be saying again and again, which is when we look at the hydrogen atom, the energy of all of the n equals 2 orbitals are exactly the same.

但是这里有一些事情你们也会注意到,当我指出2s和2p的情况，我之前提过,我会一次又一次的说，我们在观察氢原子的时候，2层轨道的所有n的能量,是完全相同的。

麻省理工公开课 - 化学原理课程节选

So, if, for example, we were looking at a hydrogen atom in the case where we have the n equals 1 state, so the electron is in that ground state, the ionization energy, it makes sense, is going to be the difference between the ground state and the energy it takes to be a free electron.

电离氢原子所需要的能量,如果我们看n等于1的情况,电子在基态，那电离能，很合理的就是基态,和自由电子态的能量差。

麻省理工公开课 - 化学原理课程节选