• This should make sense, because if an atom has a very high electron affinity, that means it's really happy taking an electron from another atom, or taking a free electron -- that that's very favorable.

    这应该是合理的,因为如果一个原子有很高的电子亲和能,这意味着,它非常乐意从另外一个原子那里夺取一个电子,或者得到一个自由电子--这是非常利于发生的。

    麻省理工公开课 - 化学原理课程节选

  • We can also look at the energy equation now for a multi-electron atom.

    我们也可以看到现在对于,一个多电子原子的能量方程。

    麻省理工公开课 - 化学原理课程节选

  • If the body view adds the no branching principle, then we can say,look,in the case of this sort of splitting-- This example is known in the to philosophical literature as fission, like nuclear fission when a big atom splits into two.

    如果肉体理论加入无分支原则,我们就能说,在这种分裂的情况下-,这种分裂在哲学文献中叫做裂变,就像原子一分为二的核裂变。

    耶鲁公开课 - 死亡课程节选

  • So when we talk about the size of multi-electron orbitals, they're actually going to be smaller because they're being pulled in closer to the nucleus because of that stronger attraction because of the higher charge of the nucleus in a multi-electron atom compared to a hydrogen atom.

    所以当我们讨论,多电子轨道的尺寸,它们实际上会变得更小,因为多电子原子的原子核,相比于氢原子,有更高的电荷量所以,有更强的吸引力,所以可以拉的更近。

    麻省理工公开课 - 化学原理课程节选

  • And we can look at precisely why that is by looking at the equations for the energy levels for a hydrogen atom versus the multi-electron atom. So, for a hydrogen atom, and actually for any one electron atom at all, this is our energy or our binding energy.

    而且我们可以精确地看看,为什么是这样的,通过看对于氢原子和,多电子原子能级的方程所以对于氢原子,事实上对于任何一个电子,这是我们的能量或者我们的结合能。

    麻省理工公开课 - 化学原理课程节选

  • So, let's take a look here at an example of an energy diagram for the hydrogen atom, and we can also look at a energy diagram for a multi-electron atom, and this is just a generic one here, so I haven't actually listed energy numbers, but I want you to see the trend.

    所以让我们来看看,一个例子氢原子的能量图,我们也可看看一个,多电子原子的能量图,这是一个普通的图谱,我没有列出能量的数字,但是我想让你们看这个趋势。

    麻省理工公开课 - 化学原理课程节选

  • A kind of consequence of this is if we're thinking about a multi-electron atom, which we'll get to in a minute where electrons can shield each other from the pull of the nucleus, we're going to say that the electrons in the s orbitals are actually the least shielded.

    这样的一个后果就是,如果我们考虑一个多电子原子,我们等会就会讨论到它,电子会互相,屏蔽原子核的吸引,我们说s轨道电子,更不容易被屏蔽。

    麻省理工公开课 - 化学原理课程节选

  • So, I said I'd tell you a little bit more about where this Bohr radius came from, and it came from a model of the atom that pre-dated quantum mechanics, and Neils Bohr is who came up with the idea of the Bohr radius, and here is hanging out with Einstein, he had pretty good company that he kept.

    我要告诉你们,波尔半径是从哪里来的,它起源于前量子力学时代的,原子模型,尼尔斯,玻尔提出了,波尔半径的概念,这是他和爱因斯坦在一起,他们是好朋友,当我们讨论这个原子模型时你们要记住的是,在1911年。

    麻省理工公开课 - 化学原理课程节选

  • And I want to really highlight here we're talking about for a hydrogen atom orbitals - with the same n value have the same energy.

    我想强调的是,我们所说的,都是对单个的氢原子,和言的,对于同样的n值能量相同。

    麻省理工公开课 - 化学原理课程节选

  • You don't need to know those, but just because it's a special case with the hydrogen atom, they do tend to be named -- the most important, of course, tends to be the Balmer series because that's what we can actually see being emitted from the hydrogen atom.

    你们不需要记住,但因为这是氢原子的特例,人们想要命名它,最重要的是当然是Balmer系,因为它是我们可以看到的,从氢原子放出来的光谱。

    麻省理工公开课 - 化学原理课程节选

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