So if we think about what we would do to actually write out this configuration, we just write the energy levels that we see here or the orbital approximations.
如果我们考虑我们所做的去,实际写出电子构型,我们只是写出我们看到的能级,或者是轨道近似就可以了。
And that turns out, approximations might sometimes be fine, certainly for the small programs we've seen thus far.
结果可能是,近似处理的相当不错,当然是对于一些小项目来说。
So let's compare what some of the similarities and differences are between hydrogen atom orbitals, which we spent a lot of time studying, and now these one electron orbital approximations for these multi-electron atoms.
很长时间的氢原子轨道和,现在多电子原子中,的单个电子轨道近似,我们可以对比,它们之间,的相似性和不同。
So what you'll be hearing are approximations as best we can make them of what's going on.
因此 你们将会学到的是,我们尽可能还原的真实情况
Well we can go look up here, looking at the differential, there are no approximations here.
好的我们可以看这儿,看这个微分方程,这里没有做近似。
Rather, you reward approximations to it.
相反,你需要对接近行为进行奖励。
So now that we can do this, we can compare and think about, we know how to consider wave functions for individual electrons in multi-electron atoms using those Hartree orbitals or the one electron wave approximations.
现在我们可以做这些了,我们可以对比和考虑,我们知道如何用哈特里轨道,或者单电子波近似去考虑,多电子原子中的单个电子波函数,所以对于我们研究了。
Because you can come up with an infinite number of values but if you have a finite amount of space and certainly a computer has a finite amount of disk space or RAM, you have to make approximations.
你可能会碰到一些无限的值,如果你只有有限的空间,废话,电脑当然只有一个有限的磁盘空间,或RAM,我们得做一些近似处理。
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