If dark matter particles exist, scientists say, they should be able to observe a small amount of light given off when they hit the nucleus of a xenon atom.
VOA: special.2009.07.21
Let's look at the energetics of one of those electrons crashing into a hydrogen atom inside the gas tube.
我们一起来考察一下,其中的一个电子的能量,在阴极射线管中,撞击到氢原子上。
OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.
后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。
Sometimes we have a very electronegative atom that's going to take more of its equal share of electron density.
有时候我们会有一个电负性很高的原子,它将会获取更多的共用电子密度。
Suppose we've got some sort of radioactive atom, which has a certain chance of decaying.
假定我们有某种放射性原子,它们以一定的几率衰变
So, what we get for the disassociation energy for a hydrogen atom is 424 kilojoules per mole.
因此,我们就得到了氢原子,离解能的大小为,424,千焦每摩尔。
Because what it tells is that we can figure out exactly what the radius of an electron and a nucleus are in a hydrogen atom.
我们可以,准确的算出,氢原子中,电子。
When it breaks this bond, that chlorine atom, a free chlorine atom comes down and reacts, this is ozone, with the ozone in the upper atmosphere.
当它打破这个化学键,氯原子,一个自由的氯原子下来,和在大气层的上方的臭氧反应,这就是臭氧,在大气上层有臭氧。
a0 This is equal to a sub nought for a hydrogen atom, and we remember that that's just our Bohr radius, which is . 5 2 9 angstroms.
它等于,我们记得,这就是波尔半径,也就是0,529埃,实际上。
Also, when we're looking at the Schrodinger equation, it allows us to explain a stable hydrogen atom, which is something that classical mechanics did not allow us to do.
当我们看一个薛定谔方程的时候,它给出一个稳定的氢原子,这是在经典力学中做不到的。
We're going to be looking at the solutions to the Schrodinger equation for a hydrogen atom, and specifically we'll be looking at the binding energy of the electron to the nucleus.
我们将研究下氢原子薛定谔方程的解,特别是电子和核子的结合能,我们将研究这部分。
So in terms of the first step of skeletal structure, this is actually going to be easier because we don't have a central atom, we just have carbon and nitrogen here.
对于第一步画出骨架,其实比刚才更容易,因为我们没有一个中心原子,我们这里只有碳和氮两个原子。
In terms of where different atoms are in a molecule, if you have a hydrogen atom or a fluorine atom, you can pretty much guarantee they're always going to be terminal atoms.
对于不同原子在分子中的位置,如果你有一个氢原子或者一个氟原子,那你基本可以保证,它们总是最末端的原子。
Whereas in molecular orbital theory, what I'm telling you is instead we understand that the electrons are spread all over the molecule, they're not just associated with a single atom or a single bond.
而在分子轨道理论里,我要告诉你们的时,我们任为电子分布在整个分子中,它们不仅仅是和,一个原子或者一个键有关。
What I just spent many lectures discussing is the fact that we can not know how far away an electron is from the nucleus, so we can't actually know the radius of a certain atom.
我花了这么多课时所讨论的正是我们,不可能知道电子离原子核有多远这一事实,因此我们不可能知道某个原子的半径。
This should make sense, because if an atom has a very high electron affinity, that means it's really happy taking an electron from another atom, or taking a free electron -- that that's very favorable.
这应该是合理的,因为如果一个原子有很高的电子亲和能,这意味着,它非常乐意从另外一个原子那里夺取一个电子,或者得到一个自由电子--这是非常利于发生的。
So again, we should be able to check all of our formal charges and make sure they add up to 0, which they do, and that makes sense, because we have a neutral atom in terms of thionyl chloride.
因此同样地,我们可以检验一下,我们所有的形式电荷是否正确,确保它们加起来等于零,而它们确实是这样,这是合理的,因为亚硫酰氯是一个中性原子。
If we want to talk about two hydrogen atoms, then we just need to double that, so that's going to be negative 2 6 2 4 kilojoules per mole that we're talking about in terms of a single hydrogen atom.
而要讨论两个氢原子,我们只需要把它乘以二,因此应该是负的,2624,千焦每摩尔,这就是单个的氢原子的情况。
So let's take two cases of shielding if we're talking about, for example, the helium, a helium nucleus or a helium atom.
所以我们来对屏蔽举两个例子,如果我们在讨论氦,举例来说一个氦原子核或者氦原子。
If we know that this is it the dissociation energy for a hydrogen atom, we can also say the bond strength for hydrogen molecule 424 is 424.
如果我们知道了这是一个氢分子的离解能,那么我们也可以说氢分子的键的强度,就是。
So, this allows us to look at a bunch of different atoms, of course, limited to the fact that it has to be a 1 electron atom.
所以这让我们可以研究很多原子,只要它们都只有一个电子。
So I said that this technique was used to experimentally determine what the different binding energies or the different ionization energies are for the different states in a multielectron atom.
我说过,这项技术被用来,在实验上确定多电子原子的,各个不同态相应的束缚能,或者电离能。
And it should make sense where we got this from, because we know that the binding energy, if we're talking about a hydrogen atom, what is the binding energy equal to?
很容易理解,我们怎么得到这个的,因为我们知道,结合能,如果,对氢原子来说,结合能等于什么?
And what is discussed is that for a 1 s hydrogen atom, that falls at an a nought distance away from the nucleus.
我们讨论了对于氢原子1s轨道,它的最可能半径在距离原子核a0处。
So, I'm asking very specifically about radial nodes here, how many radial nodes does a hydrogen atom 3 d orbital have?
我问的是径向节点,这里3d轨道的径向节点有多少个?
So, essentially you've got a positive ball which is identical to the size of the atom.
首先你要有一个和原子差不多大小的,带正电荷的球。
if we have a very electronegative atom within a certain molecule, what you'll actually find is that it does affect how the molecule is going to take place or take part in different chemical or biological reactions.
如果在某个分子中有一个电负性很高的原子,你会发现它确实会影响到,这个分子所起的作用,在不同的化学反应或者生物反应中时。
So, what this lets us do now is directly compare, for example, the strength of a bond in terms of a hydrogen atom and hydrogen molecule, compared to any kind of molecule that we want to graph on top of it.
因此,这让我们现在可以做到直接进行比较,比如,将一个氢原子,和一个氢分子的键的强度,与任何其它类型的分子进行比较,我们只需要把它的曲线也画在这幅图上。
So again, what we're saying here is that it is most likely in the 3 s orbital that we would find the electron 11 and 1/2 times further away from the nucleus than we would in a around state hydrogen atom.
同样我们,这里说的是,氢原子3s轨道中,最可能找到电子的地方,是基态的11.5倍。
These are all one electron atoms, and they are gas, a single atom.
这些都是单电子原子,它们都是气体,都是单原子。
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