• And so this lower level is called a bonding orbital, and it is a bonding molecular orbital.

    所以能级较低的轨道叫做成键轨道,这就是成键分子轨道

    麻省理工公开课 - 固态化学导论课程节选

  • So if we think about what we would do to actually write out this configuration, we just write the energy levels that we see here or the orbital approximations.

    如果我们考虑我们所做的去,实际写出电子构型,我们只是写出我们看到的能级,或者是轨道近似就可以了。

    麻省理工公开课 - 化学原理课程节选

  • And this one here, because it is at a higher energy is called antibonding molecular orbital.

    这里的这个,因为处在一个较高的能级,被叫做反键分子轨道能级

    麻省理工公开课 - 固态化学导论课程节选

  • The electron's going to come out of that highest occupied atomic orbital, that one that's the highest in energy, because that's going to be the at least amount of energy it needs to eject something.

    这个电子应该是从,最高的被占据轨道上出来的,它的能级是最高的,因为这样的话发射出它,只需要消耗最少的能量。

    麻省理工公开课 - 化学原理课程节选

  • And as you go to higher and higher levels, those energy levels, as you saw in the case of hydrogen, are more closely spaced.

    能级变得越来越高,那些高能级轨道,就会变得越来越接近,正像你在氢原子里看到的那样。

    麻省理工公开课 - 固态化学导论课程节选

  • So what we're doing is filling in those eight electrons following the Aufbau principle, so our first electron is 1s going to go in the 1 s, and then we have no other options for other orbitals that are at that same energy, 1s so we put the second electron in the 1 s as well.

    它会是什么样子呢,我们正在做的是将这8个电子按照奥弗,堡原理进行填充,所以我们第一个电子将会进入,然后我们没有其他的,轨道的选择在同一个能级,所以我们把第二个电子也放入。

    麻省理工公开课 - 化学原理课程节选

  • Electrons fill orbitals from lowest energy to highest energy.

    电子从最低能级到最高能级,填满轨道

    麻省理工公开课 - 固态化学导论课程节选

  • So, what he did was kind of impose a quantum mechanical model, not a full one, just the idea that those energy levels were quantized on to the classical picture of an atom that has a discreet orbit.

    还不是完整的,只是这些能级,是量子化的概念,作用到原子有分立轨道的经典原子模型上,当他做了一些计算后,他得到有个半径,他算出来。

    麻省理工公开课 - 化学原理课程节选

  • Some of you might be saying in your heads, wait a second, I happen to know, I happen to remember from high school, p have different energies then, for example, s orbitals.

    有些人,可能会心里想:,等等,我记得,高中的时候学过,轨道,that,p,orbitals,和s轨道,的能级是不同的。

    麻省理工公开课 - 化学原理课程节选

  • And what we see here is now when we're combining the p, we have our 2 p x and our 2 p y orbitals that are lower in energy, and then our pi anti-bonding orbitals that are higher in energy.

    这里我们看到,当我们结合p轨道时,在低能处我们有,2px和2py轨道,π反键轨道在更高的能级处。

    麻省理工公开课 - 化学原理课程节选

  • So we know that we can relate to z effective to the actual energy level of each of those orbitals, and we can do that using this equation here where it's negative z effective squared r h over n squared, we're going to see that again and again.

    我们知道我们可以将有效电荷量与,每个轨道的实际能级联系起来,我们可以使用方程去解它,乘以RH除以n的平方,它等于负的有效电荷量的平方,我们将会一次又一次的看到它。

    麻省理工公开课 - 化学原理课程节选

  • Electrons will occupy orbitals in order of ascending energy, occupying the lowest energy first and up.

    电子是按其能量递增顺序,排布在轨道上的,首先占满第一级,即最低能级

    麻省理工公开课 - 固态化学导论课程节选

  • We also know how to figure out the energy of this orbital, and we know how to figure out the energy using this formula here, which was the binding energy, -Rh which is negative r h, we can plug it in because n equals 1, so over 1 squared, and the actual energy is here.

    我们知道如何算出,这个轨道能级,而且我们知道如何,用这个公式,算出能量,也即是结合能,等于,我们把n等于1代进来,所以除以1的平方,这就是能量。

    麻省理工公开课 - 化学原理课程节选

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