• It's somewhat different when we're talking about the p or the d orbitals, and we won't go into the equation there, but this will give you an idea of what we're really talking about with this radial probability distribution.

    当我们讨论p轨道或者,d轨道的时候会有些不同,我们那时不会给出方程,但它会给你们一个,关于径向概率,分布的概念。

    麻省理工公开课 - 化学原理课程节选

  • So, we can do that by using this equation, which is for s orbitals is going to be equal to dr 4 pi r squared times the wave function squared, d r.

    用这个方程,对于s轨道,径向概率分布,4πr的平方,乘以波函数的平方,这很容易理解。

    麻省理工公开课 - 化学原理课程节选

  • So we know that we can relate to z effective to the actual energy level of each of those orbitals, and we can do that using this equation here where it's negative z effective squared r h over n squared, we're going to see that again and again.

    我们知道我们可以将有效电荷量与,每个轨道的实际能级联系起来,我们可以使用方程去解它,乘以RH除以n的平方,它等于负的有效电荷量的平方,我们将会一次又一次的看到它。

    麻省理工公开课 - 化学原理课程节选

  • The more important thing that I want you to notice when you're looking at this wave equation for a 1 s h atom, is the fact that if you look at the angular component of the wave function, you'll notice that it's a constant.

    我要你们注意的,更重要的一点是,当你们看到,这个氢原子1s轨道方程的时候,如果你们看,波函数,的角向部分,你们会发现它是一个常数。

    麻省理工公开课 - 化学原理课程节选

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