And it's always going to come down to calculating the appropriate free energy, and how it changes in the process.

这总是涉及到计算,适当的自由能，以及这些自由能在过程中如何变化。

麻省理工公开课 - 热力学与动力学课程节选

Whereas under these conditions, these quantities, if you look at free energy change, for example at constant temperature and pressure, H you can still calculate H.

但是，在这些条件下，这些物理量，如果我们考察自由能的变化,例如在恒定的温度和压强下，我们仍然可以计算。

麻省理工公开课 - 热力学与动力学课程节选

So, I just want to write a few examples down with a few values for delta u or delta H or delta S, and see whether we can get any clues from what we see.

我先写一些例子,例子包含一些内能，自由焓和熵的变化数值，然后看从中,我们能不能得到一些启示。

麻省理工公开课 - 热力学与动力学课程节选

So again with the Gibbs free energy, now I see how to determine, if I change the pressure, if I change the temperature by some modest amount, how much is the Gibbs free energy going to change?

再一次通过吉布斯自由能，我知道当我，适当的改变压强和，温度的时候，吉布斯自由能如何变化？

麻省理工公开课 - 热力学与动力学课程节选

What that's going to allow us to do is, if we say, OK I have a mixture of stuff, how does the free energy change?

我们能够说的是，如果我们有一份混合物，自由能怎么变化？

麻省理工公开课 - 热力学与动力学课程节选

We discovered that the quantity dA, under conditions of constant volume and temperature, dA TS And A is u minus TS.

我们发现在恒定的体积和温度下，亥姆赫兹自由能的变化，小于零，is，less，than，zero。,亥姆赫兹自由能A等于内能u减去。

麻省理工公开课 - 热力学与动力学课程节选