So by using the tabulated data, we can really determined heats of formation for most reactions that you might contemplate, OK?
所以,使用这些表格,我们就能确定大多数,你可能碰到的反应的生成热?
So we're just subtracting, in effect, zero, right, from the enthalpy of the product, but of course it's important have that established because the heat of formation is something you could measure, right?
所以从效果上说,我们只是,从生成物的焓中减去了零,但,是确立这一点很重要,因为生成热是,你能测量的东西,对吧?
Now, it used to be in the old days before I had kids, I could list off 15 current movies and help you a bit more with your dating strategy by giving you instant movie reviews, but now I have kids, I get to see precisely two movies a year, and the two movies I got to see this year were The Bourne Ultimatum and the Good Shepherd.
在我有孩子之前,我能列出15部热映的影片,我还能给你们提供不错的影评,帮助各位制定约会策略,但是现在我当爸爸了,我每年只能看两部电影,我今年看的两部就是,《谍影重重》和《特工风云》
And it's for that whole unit that you've got some heat capacity. How much heat does it take the warm the entire thing up or the insides of the thing up by a degree? It's that number right.
由这个单位你能知道,一些热容的信息,要让这整个装置,或里面放置的东西,升温一度需要多少热量?
There's an interplay between the energy inside the gas which is the heat energy which is allowing me to do all that work to be outside, and so I'm using up some of the energy that's inside the gas to do the work on the outside.
即使没有热传递,能量也能以,做功的形式传递出去,气体的一部分内能,转化成了功。
We can tabulate them. We can know them, and then when we have reactions that inter-convert different compounds, we can calculate the heat of reaction is just the difference between the heat of formation of the reactants, and the heat of formation of the products, right.
种化合物的生成热,可以把它们列成表,可以认知它们,而当我们要处理,在不同化合物间转变的反应时,我们只要计算反应物和,生成物的生成热之间的不同,就能计算出反应热。
So in principle, if I measure how much hotter, I can determine how much heat was produced, and from that, I should be able H to calculate delta H at T1.
所以原则上,如果我测量,变热了多少,我就能确定,有多少热被产生,从中我就可以计算T1下的Δ
Or I could have a non-adiabatic, I could take the same temperature change, by taking a flame, or a heat source and heating up my substance. So, clearly q is going to depend on the path.
也能改变温度,绝热指的是没有热传递,在非绝热条件下,也同样可以升温,比如用火或者热源加热,这样,q也应当与路径有关。
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