So if I worry about energy I have a pretty good chance of extracting out these heat capacities, right, and I don't have to worry about exactly which path and I can really mix things up.
而能量与热容有密切的关系,从能量就可以就算出这两个热容,我不需要考虑到底是哪一条路径,可以随意计算。
So you can see that we're starting to have a very complicated equation, and it turns out that it's mathematically impossible to even solve the exact Schrodinger equation as we move up to higher numbers of electrons.
所有你们可以看到我们得到了,一个非常复杂的方程,结果是它在数学上是,不可能解出确定的,薛定谔方程,当我们考虑更高的电子数目的时候。
So, for example, it's not just the 2 p that we could actually take an electron from, we could also think about ejecting an electron from the 2 s orbital.
比如,我们不只可以从,2,p,轨道上,打出一个电子,还能考虑从,2,s,轨道上,发射出一个电子。
So, if we think about this z bonding axis between the two carbon atoms, we can picture overlap of those s p hybrid orbitals, and then we can also picture bonding to hydrogen.
如果我们考虑,两个碳原子之间的z成键轴,我们可以画出sp杂化轨道的交叠,我们也可以画出和氢原子的成键。
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