• So if I worry about energy I have a pretty good chance of extracting out these heat capacities, right, and I don't have to worry about exactly which path and I can really mix things up.

    而能量与热容有密切的关系,从能量就可以就算这两个热容,我不需要考虑到底是哪一条路径,可以随意计算。

    麻省理工公开课 - 热力学与动力学课程节选

  • So you can see that we're starting to have a very complicated equation, and it turns out that it's mathematically impossible to even solve the exact Schrodinger equation as we move up to higher numbers of electrons.

    所有你们可以看到我们得到了,一个非常复杂的方程,结果是它在数学上是,不可能解确定的,薛定谔方程,当我们考虑更高的电子数目的时候。

    麻省理工公开课 - 化学原理课程节选

  • So, for example, it's not just the 2 p that we could actually take an electron from, we could also think about ejecting an electron from the 2 s orbital.

    比如,我们不只可以从,2,p,轨道上,打一个电子,还能考虑从,2,s,轨道上,发射一个电子。

    麻省理工公开课 - 化学原理课程节选

  • So, if we think about this z bonding axis between the two carbon atoms, we can picture overlap of those s p hybrid orbitals, and then we can also picture bonding to hydrogen.

    如果我们考虑,两个碳原子之间的z成键轴,我们可以画sp杂化轨道的交叠,我们也可以画和氢原子的成键。

    麻省理工公开课 - 化学原理课程节选

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