This cation is attracting the chloride next to it and it is repelling the sodium as the next nearest neighbor.
这一阳离子被邻近的氯离子所吸引,并排斥钠离子,因为这是其最邻近的离子。
We started with gaseous sodium to make gaseous sodium ion and gaseous atomic chlorine to make gaseous chloride ion through electron transfer.
我们从气态的钠开始,得到气态的钠离子,从气态的氯原子,通过电子转移得到氯离子。
So the last thing I want to mention today is how we can think about electron configurations for ions.
今天我想提到的最后一件事,就是我们怎样考虑离子的,电子构型。
Because there are ions moving back and forth, there's a current that flows and there's a electrical potential that's generated.
由于离子的进进出出,就产生了电流流动,并且形成了电势差
So now, let's get a sodium here, and the chloride ion next to it to the point where they are touching.
所以,我们要有一个钠离子,和氯离子放在,相互接触的一个点上。
I can take you and immediately start designing batteries, because we need ions in motion, we need small ions in motion.
我可以从此让你快速起步设计电池,因为我们需要能运动的离子,我们需要能运动的小型离子。
But, can you see that as you get really close together the negative electronic cloud surrounding the two ions start to sense one another.
然后当你真的让它们,离得很近时,这两个离子周围的负电子云能感应到对方。
Negative 1 plus 0 should add up to negative 1, if in fact, we're correct for the c n anion.
负一加上零应该等于负一,如果是这样,我们对于氰离子的结果就是正确的。
And all ion channels are selective for a single type of ion, and we can think about how that selectivity takes place, and that's where this idea of atomic radius is going to become very important.
所有的离子通道都是仅对某一种离子具有选择性的,而我们可以来想一想这种选择性是如何发生的,这也就是原子半径这个概念将会变得,非常重要的地方。
And, that's given by the balance between the attractive force of the ions offset by the repulsive force in the electronic shells.
而那是由,在离子的电子层之间的,引力和斥力相互抵消得到的。
So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.
负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。
And this is really interesting to think about because you can imagine in our body we have concentrations of all types of ions, and specifically, some seem very, very similar to each other.
这是非常令人感兴趣的,因为大家可以想象一下,在我们的体内我们有,一定浓度的任何类型的离子,而且特别地,其中有一些非常非常地相似。
If instead we had a positive ion, a cation, what we would have to do is subtract 1.
如果我们有一个带正电的离子,一个正离子,那我们就需要再减去一个。
The ones that are most important in physiology are ones that only allow ions to go through: sodium, potassium, chloride, calcium, bicarbonate.
在生理学上这种,只能允许某种离子通过的通道十分重要,这些离子包括钠离子,钾离子,氯离子,钙离子和碳酸氢根离子
So, basically any time we have a really high positive number of electron affinity, it means that that atom or ion really wants to gain another electron, and it will be very stable and happy if it does so.
因此,基本上无论什么时候,只要我们有一个很大的正的电子亲和能,这就意味着这个原子,或离子非常希望得到一个电子,如果它得到了,会变得更稳定更开心。
Aluminum and magnesium are both made by ionic liquid electrolysis, just as I showed you last day.
铝和镁都是,由离子液体电解而成,就像我昨天讲的。
Remember in the ion, we're going to have less electrons around to counteract the pull from the nucleus.
还记得在这个离子中,在原子核周围,抵消它吸引力的电子更少。
So, that also tells us that the n minus ion is less stable than the neutral atom itself.
而且,这还告诉我们,负一价的氮离子不如中性氮原子稳定。
So, somewhere in between, the bonds are, we have a range of bonds between ionic on the one hand, and perfectly covalent on the other hand.
因此在中间,这些键,一方面是离子性,另一方面是完美的共价键。
So if we want to write out what that would be, it would just be to say that f minus is isoelectronic with neon.
那么如果我们把它写出来,它应该就是负一价的氟离子与氖原子是等电子的。
So, what happens, this is another view of a sodium channel, so this is actually looking a little bit more at the protein structure.
那么,这里发生了什么,这是钠离子通道的另一张图片,在这种蛋白质结构中,它看起来更复杂一点。
And, subsequently, we looked at photoelectron spectroscopy which is a technique that allows us to determine binding energies, ionization energies being just one example.
随后,我们看了光电子谱,这是一种只用一个样品,能够测量结合能,离子化能的技术。
And I know there's a lot to talk about this competition, but let's just get into listening mode here and talk about how we can figure out what the correct electron configuration is for this ion.
我知道刚才关于这次比赛大家有很多话要聊,但是请大家先转换到听讲的模式,来看看如何才能弄清楚,这个离子正确的电子排布。
And this is just a picture showing some of these sizes with their parent. So, for example, a lithium here, you can see how lithium plus is smaller than the actual lithium atom in its neutral state.
这是一张对比图,展示某些离子与它们的母体,比如,这里是锂,大家可以看到正一价锂离子是多么的小,与中性锂原子相比。
If you flip the Periodic Table over you will have the ionization energy of sodium, first ionization energy, 5eV and it is about 5 eV which, when you convert, 496kJ/mol is a whopping 496 kilojoules per mole.
如果浏览周期表,你可以得到钠的离子化能,第一电离能,大约,当你转换的时候,是巨大的。
so it's important to note that it's not in b, now we're talking about b plus, because we've already taken an electron out here.
其中有一个非常重要的地方需要注意,不是硼,而是正一价硼离子,因为我们已经拿走了一个电子了。
What you see is that the radius changes with atomic number for constant electron number.
对于等电子数的粒子,离子半径随着,原子数的变化而变化。
Or you can talk about the gate being open, and in this case, you can see that you will have an influx of ions.
或者你可以说闸门是打开的,就像这种情况,可以看到有离子通过它流入细胞。
In addition, the kidney controls the composition of your body of many important ions, sodium bicarbonate which is important in pH balance, potassium.
此外肾脏还能控制,体内很多重要离子的浓度,例如碳酸氢钠,它对于酸碱平衡十分重要,还有钾离子
So we could think about comparing the potassium ion to a sodium ion. They have the same charge of plus one.
我们可以想象比较一下钾离子,与钠离子,它们都同样带有正一价的电荷。
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