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So either a potassium cyanide or sodium cyanide, these are used in synthesis in terms of making carbon-carbon bonds.
因此无论是氰化钾还是氰化钠，都被用来在合成过程中,制造碳碳键。
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So we can have four total hydrogens bonding here, - and we can think about how to describe these carbon- carbon bonds.
我们这里一共有四个氢原子成键，我们可以考虑怎么来-,描述碳碳键。
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So in addition to having these two carbon bonds, we actually also have four carbon hydrogen bonds in addition to our carbon-carbon bonds.
在这碳碳之间的键以外，我们还有四个碳氢键,除了我们的碳碳键外。
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So let's take the case of acetylene where we have two carbon atoms that are going to be triple bonded to each other, each are bonded to a carbon and then to one hydrogen.
让我们来看一看乙炔的例子,我们有两个碳原子,成三键，每个碳和一个碳一个氢相连。
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This is very easy molecule because we know exactly where to put them without even having to think, we only have one option, and we'll make a triple bond between the carbon and the nitrogen.
这个分子非常简单,因为我们知道应该把它们放在哪里,甚至不用去想，我们只有一个选择，我们将在碳与氮之间形成一个三键。
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So if you think about any one of these carbon-carbon bonds, what type of a bond would you expect that to be?
如果你们考虑任何一个碳碳键，它是什么类型的？
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Now we have 6 things around the nitrogen, and we have 8 around the carbon.
现在我们有六个成键电子在氮周围，有八个在碳周围。
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So in terms of thinking about ethane, we actually have two bond types that we're going to be describing just in terms of the carbon-carbon bond and then the carbon h bonds.
对于乙烷，我们有两种键,我们继续讨论一下,碳碳键,和碳氢键。
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And the last bond that we have here is a carbon-carbon bond, and this is our last p orbitals that are coming together.
最后一个键是碳碳键，这是最后一个组合的p轨道。
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If we think about bringing in those last two carbons, what you can see is that for every carbon, two of its hybrid orbitals are being used to bond to other carbons.
如果我们考虑引入最后两个碳原子，你会看到的是对于每个碳原子，其中的两个杂化轨道,和另外的碳原子成键。
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So it looks a lot less messy if we just draw our Lewis structure like this for h c n, where we have h bonded to c triple bonded to n, and then a lone pair on the nitrogen there.
这看起来整洁了不少,如果我们把氰化氢的路易斯结构画成这样的话，这样我们就有氢与碳之间的单键和碳与氮之间三键，然后还有一对孤对电子在氮这里。
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So again, if we think about that shape of that carbon atom, it's going to be trigonal planar, 120° it's going to have bond angles of 120 degrees, because we have this set up of having three hybrid orbitals.
如果我们考虑碳原子的形状，它是平面三角形，键角是，因为我们有这三个杂化轨道。
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If we have the molecule ethane, then what we're going to have first is our sigma bond that we described between the two carbons.
如果我们有乙烷分子，那我们首先有,碳碳之间的sigma键。
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So if you're trying to make a more complicated organic molecule carbon-carbon bonds are one of the most difficult things to make in organic chemistry, and it turns out that c n minus is a very reactive molecule, so it's a good way, even though we'll go over some drawbacks in a second, it is a good way to make carbon-carbon bonds.
如果你要合成一个更复杂的有机分子,碳碳键是有机化学中,最难制造的键之一，而实际上氰离子是一种具有很高活性的分子，用它是一个好办法，尽管我们一会儿将看到它的一些缺点，但它的确是一个制造碳碳键的好方法。
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sigma2sp It's going to be a sigma bond. So, we have sigma 2 s p, carbon 2 s p. So they're two s p bonds combining.
是sigma键，我们有，碳2sp。，所以它们是两个sp键结合。
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So, what we end up having is three of these pi -- 2 p y 2 p y bonds, we can have one between these two carbons here.
我们剩下的有三个π键-,2py2py键，在这两个碳原子之间会有一个。
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So, if we think about what bonds are in this molecule, sp2 we actually have six of these sigma carbon s p 2, carbon s p 2 bonds.
如果我们考虑这个分子里都有什么键，我们有六个sigma碳，碳sp2键。
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So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.
所以它是沿着键轴方向的,而且这里是一个碳sp2杂化轨道，和一个氢的1s轨道的结合,在这里我们可以合并他们。
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And if we think about the six hydrogens, now each of those are going to bind by combining one of the carbon hybrid orbitals to a 1 s orbital of hydrogen.
如果我们考虑有六个氢原子，每个都会合起来,碳杂化轨道成键,每个氢的1s轨道。
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If we have, coming along this z axis, another carbon atom, we can actually form one bond between the two carbon atoms there.
如果我们在z方向，有另外一个碳原子，我们可以在,两个碳原子之间形成一个键。
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So, if we think about this z bonding axis between the two carbon atoms, we can picture overlap of those s p hybrid orbitals, and then we can also picture bonding to hydrogen.
如果我们考虑,两个碳原子之间的z成键轴，我们可以画出sp杂化轨道的交叠，我们也可以画出和氢原子的成键。
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We also have carbon s p 2 hydrogen 1 s bonds.
我们还有碳sp2氢1s键。
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So essentially, we have two ethene or ethylene molecules here to start with where these blue are our 2 s p 2 hybrid orbitals, so you can see that for each carbon atom, one is already used up binding to another carbon atom.
本质上，我们从两个乙烯分子开始,蓝色的是2sp2杂化轨道，你可以看到，对于每一个碳原子，其中一个已经用来和另外一个碳原子成键。
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And again, this is between the p orbitals, these are not hybrid orbitals, so when we name this bond we're going to name it as a pi bond here, because it's between two p orbitals, and it's going to be between the carbon 2 p y orbital, and the other carbon 2 p y orbital.
同样，这是在p轨道之间的，它们不是杂化轨道，所以当我们命名这个键时,我们要命名它为π键，因为它在两个p轨道之间，而且是在碳2py轨道，和另一个碳2py轨道之间。
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So if we still have an angle of a 109 . 5 degrees, and again, we still have four unpaired electrons available for bonding, we can make one of those bonds with another s p 3 hybridized carbon, so we're going to make up one pair here.
如果键角仍然是109。,同样，我们还有4个未配对的电子可以用来成键，我们可以用其中的一个,和另外一个sp3杂化碳原子成键，这样我们可以组成一对。
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So that's two of our types of bonds in benzene, and we have one type left, that's going to actually be the double bond or the pi bond that So we can have one bond here between this carbon's p orbital and this carbon's p orbital.
这就是苯环里的两种键，我们还剩一种，那就是这些p轨道之间，形成的双键或者π键,我们可以在这个碳的p轨道,和这个碳的p轨道之间有个键。
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