dT/dp is mu JT. So for a real gas like air, this is a positive number. It's not zero.
所以对于像空气这样的真实气体,这是一个正数,不等于零。
This needs to be stressed that this is the ideal gas case. Now regular gases, real gases fortunately as I said, don't obey this.
需要强调的是这是对理想气体而言的,普通气体,真实气体,就像我说过的,不遵循这个规律,这是非常重要的。
Real refrigerators actually work with liquids that go into gases so use the latent heat of the liquid, so it doesn't really work like the Joule-Thomson expansion. So this is real.
液体变成气体来工作,以运用液体的潜热,所以这不是,真正像焦耳-汤姆逊膨胀一样工作,这是真实的气体,不像焦耳。
When you expand a real gas into vacuum, the temperature goes down.
当一个真实气体,向真空膨胀咱的时候温度会下降。
u=0 And it's approximately equal to zero for all real gas processes.
在所有理想气体绝热过程中Δ,对真实气体近似为零。
Pressure has dropped out of the picture completely here. So there is no p dependence here.
理想气体的H只是温度的函数,这对于真实气体来说是。
This is real, unlike the Joule coefficient which is very small so that most gases have tiny Joule coefficients. So if you do a Joule experiment, you hardly measure a temperature change. With real gases, here you do actually measure it. You can feel it with your finger on your bicycle tire.
系数那样小以至于,大多数气体的焦耳系数,都很小,所以如果你做焦耳实验,很难测量出温度的变化,对于真实气体,你可以测量它,你能通过手指按在,自行车轮胎上来感觉到它。
If you have a real gas and you write du is Cv dT and your path is not a constant volume path, then you are making a mistake. But for an ideal gas, you can always write this. And this turns out to be very useful to remember.
对于真实气体,如果其变化过程,不是恒容的,du=Cv*dT就不成立,但对于理想气体,这条规则永远成立,这一点非常有用,请记住。
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