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So why don't you go ahead and identify the correct electron configuration for carbon, 6 and I'll tell you that z is equal to 6 here.
所以你们为什么不开始,而且识别碳的正确的在你们做作业方面,电子构型，我会告诉你有效电荷量是。
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For the carbon, we start with 4 valence electrons, we have 0 lone pair electrons minus 4, and we end up with a formal charge of 0.
对于碳，我们从四个价电子开始，我们有零个孤对电子，再减去四，最终我们有零个形式电荷。
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And there is this separation which is a balance of attractive forces because the chloride is net negative and the sodium is net positive, but both of them, regardless of net charge, have electrons.
这里有一个平衡,引力的平衡,由于氯离子带有负的净电荷,钠离子带有正的净电荷，但是它们两个，没有考虑净电荷，电子。
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And let's say our second electron now is really far away, such that it's actually not going to shield any of the nuclear charge at all from that first electron.
距离原子核非常非常近,我们说第二个电子处于非常远的位置,这样它不会对第一个电子,感受到的来自原子核的电荷量有任何屏蔽作用,我们最后要说的是。
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So for example, that might have a formal charge of negative 1, because to some extent it has gained that much electron density that it now has a formal charge that's negative.
比如，可能它的形式电荷为负一，因为在一定程度上它得到了这么多的共用电子密度,那么它现在就有了负的形式电荷。
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For the sulfur, we start off with 6 valence electrons, minus 4 lone pair electrons, minus 2, taking in account our bonding electrons, so we end up with a formal charge of 0.
对于硫，我们从六个价电子开始，减去四个孤对电子，再减去二，算上我们的成键电子，因此最终我们有零个形式电荷。
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And shielding is a little bit of a misnomer because it's not actually that's the electron's blocking the charge from another electron, it's more like you're canceling out a positive attractive force with a negative repulsive force.
屏蔽有一点点用词不当,因为它事实上不是,电子阻挡了来自另一个电子的电荷,它更像你在用一个负排斥力，抵消一个正吸引力,但是屏蔽是考虑这个问题,的很好的方式。
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So this is how much charge there is in a mole of electrons.
这就是在一摩尔的电子里,的电荷量。
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e The charge on the electron is minus e.
电子所带电荷应为。
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And the electrical energy is the product of the charge on the electron times the voltage which is the potential difference through which the electron was accelerated. And so this allows me to, by increasing the voltage, increase the energy on the electron.
电子能量是电子上的电荷数,乘以电压的结果,这是种内在的差距,通过它电子运动得以加速，这也让我，通过增强电压，来增加电子能量。
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So let's do this considering, for example, what it would look like if we were to write out the electron configuration for oxygen where z is going to be equal to 8.
我们来做这个考虑，举例来说,如果我们写出,有效电荷量为8的氧的电子构型。
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But what's important is not where that most probable radius is when we're talking about the z effective it feels, what's more important is how close the electron actually can get the nucleus.
但重要的不是,最可能半径,当我们谈论它感到的有效电荷量的时候，更重要的是,电子实际上。
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So if you have some charge in the nucleus, but you also have repulsion with another electron, the net attractive charge that a given electron going to feel is actually less than that total charge in the nucleus.
所以如果在原子核中，有一些电荷但是你也有来自，另一个电子的排斥力,那么一个给定电子的,吸引电荷感觉到的事实上,小于原子核中的总电荷。
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And then we end up having 6 shared electrons, 2 from each of the bonds, so we end up with a formal charge on sulfur of plus 1.
然后我们有六个共用电子，每个键两个，因此最终硫的形式电荷量为正一。
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Again we have the charge of the nucleus on plus 2, +2 but let's say this time the electron now is going to be very, very close to the nucleus.
对于我们的氦原子，我们有一次得到了原子核电荷量为,但是我们说这次电子。
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We said that that second electron was so far out of the picture, that it had absolutely no affect on what the charge was felt by that first electron.
我们说第二个电子远离这张图片,这样它就彻底的对,第一个电子感觉到的电荷没有影响了,所以。
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So when we talk about the size of multi-electron orbitals, they're actually going to be smaller because they're being pulled in closer to the nucleus because of that stronger attraction because of the higher charge of the nucleus in a multi-electron atom compared to a hydrogen atom.
所以当我们讨论,多电子轨道的尺寸，它们实际上会变得更小,因为多电子原子的原子核,相比于氢原子,有更高的电荷量所以,有更强的吸引力,所以可以拉的更近。
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So, why don't you take a look at this and tell me which are possible for a 2 s electron in a lithium atom where z 3 is going to be equal to three?
你们为什么不看一下这个然后告诉我对,于一个锂原子中的2s电子哪些是可能,的？它的有效电荷量,可能等于？
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If you look up really close, there is the elementary charge e.There is the mass of the electron.
如果你仔细找的话，会找到e表示的元电荷,也能找到电子的质量。
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The electron completely canceled out 1 it's equivalent of charge from the nucleus, such that we only saw in a z effective of 1.
电子完全抵消了来自原子核的等量电荷,这样我们仅仅看到有效的z为，在极端案例b中。
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2 So what we end up saying is that the z effective or the effective charge that that first electron feels is now going to be plus 2.
第一个电子感觉到的有效的z或者有效电荷现在是,我们再一次将它带入我们的方程。
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Remember, e represents the elementary charge, not the charge on the electron.
记住，e代表元电荷，而非电子所带电荷。
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What we need to do is get rid of the Coulomb tag that we have - that's how we measure our electron charges - charge, and so we use this epsilon nought quite often, this permativity constant of a vacuum to make that conversion.
怎么量度电子电荷,所以我们会经常用到,这个epsilon，nought记号,这是真空中的介电常数,我们还要指出,这个介电常数。
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In addition to that, we have that epsilon nought value, remember that's the permittivity constant in a vacuum, and basically that is what we use as a conversion factor to get from units. We don't want namely coulombs to units, we want that will allow us to cancel out in this equation.
这是电子的电荷，此外，我们有epsilon零，记住这是真空的介电常数，这是我们用来转换单位的转换常数,我们不想用库伦单位，我们希望这个可以在方程中约去它。
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