• What he did was took de Broglie motion of the electron as a wave and developed a wave equation for such matter waves.

    他所做的就是,用电子的德布罗意运动,作为波并且对于那种物质波,给出波动方程。

    麻省理工公开课 - 固态化学导论课程节选

  • And it is moving around and we are sitting on that electron watching it go about its daily affairs.

    它正在运动,我们正置身与电子上面,观察它时刻发生的事件。

    麻省理工公开课 - 固态化学导论课程节选

  • So, if we do this calculation for an electron, saying it moves at 10 to the 5 meters per second, then what we end up with for a wavelength is 7 times 10 to the -9 meters.

    如果我们已知电子以,10的5次方每秒的速度运动,那么做一个计算,可以得知它的波长是,7乘以10的负9次方米。

    麻省理工公开课 - 化学原理课程节选

  • If de Broglie is correct, we could then model the electron in its orbit not moving as a particle, but let's model it as a wave.

    如果德布罗意是对的,那么我们可以在电子轨道中建立电子模型,不是像粒子一样运动,而是像波一样运动

    麻省理工公开课 - 固态化学导论课程节选

  • If a photon which has no mass can behave as a particle, does it follow then an electron which has mass can behave as a wave? 1920.

    如果一个没有质量的光子,能像粒子一样运动,那么它能像一个,没有质量的电子那样以波的形式运动吗。

    麻省理工公开课 - 固态化学导论课程节选

  • That is why we don't worry about the motion of the nucleus 1 because the ratio of mass is about 2,000 to one.

    这就解释了为什么我们不担心,原子核运动起来,因为原子核和电子的质量比约为2000:

    麻省理工公开课 - 固态化学导论课程节选

  • So because we're feeling a stronger attractive force from the nucleus, we're actually pulling that electron in closer, which means that the probability squared of where the electron is going to be is actually a smaller radius.

    因为我们能感到来自原子核,的更强的吸引力,我们实际上会将电子拉的更近,那意味着电子运动的,概率半径是,事实上是一个更小的半径。

    麻省理工公开课 - 化学原理课程节选

  • And the thing about what Schrodinger did was all he imposed on a system was the electron behaves as a wave and is bound.

    薛定谔所做的,是建立在一个系统之上,电子是像波一样运动的并且是有界限的。

    麻省理工公开课 - 固态化学导论课程节选

  • The total energy of the system, which we are going to get from postulate number four, which says the energy of the electron, which is the energy of the system, is the sum of the kinetic and the potential energy.

    这个系统的总能量,也就是我们将从第四个假设中算出的能量,也就是电子运动产生的能量,也就是整个系统的能量,是动能和位能的总和。

    麻省理工公开课 - 固态化学导论课程节选

  • The electron is not moving at the speed of light.

    电子不是以光速运动的。

    麻省理工公开课 - 固态化学导论课程节选

  • And then over here this electron will continue.

    然后这,这个电子将会继续运动下去。

    麻省理工公开课 - 固态化学导论课程节选

  • c We know it's very specific for light because in this equation is c, the speed of light. So any time you go to use this equation, if you're trying to use it for an electron, just ask yourself first, does an electron travel at the speed of light?

    我们知道它只对光适用是因为在这个方程里有,光速,所以下次你们用这个方程前,如果你们要把它用到一个电子上,先问问你自己,电子运动速度是光速吗?

    麻省理工公开课 - 化学原理课程节选

  • And the electrical energy is the product of the charge on the electron times the voltage which is the potential difference through which the electron was accelerated. And so this allows me to, by increasing the voltage, increase the energy on the electron.

    电子能量是电子上的电荷数,乘以电压的结果,这是种内在的差距,通过它电子运动得以加速,这也让我,通过增强电压,来增加电子能量。

    麻省理工公开课 - 固态化学导论课程节选

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