The only function it is -- it doesn't care where the gas is. It only cares where the temperature is.
是温度的函数,它只是温度的函数,不管是什么气体。
In other words, now I know how to tell how the Helmholtz free energy changes as a function of temperature.
换句话说,我现在知道如何写出亥姆赫兹,自由能作为温度的函数。
are all functions of state and parameters that we can control like temperature and pressure.
公式里面的全部都是态函数,我们控制态函数的参数比如温度或者压强。
It's a state function, so we're at constant temperature and pressure, and now we want to consider some chemical change or a phase transition or you name it.
这就是态函数,我们处于恒定的温度和压强之下,然后考虑某些化学变化或者相变,或者你想考虑的东西。
You need a functional form that connects the value at one state of matter, the freezing point of water to another phase change, the boiling point of water.
你需要一个函数形式来,连接物质某个态对应的温度值,如水的冰点,和另一个相变,如水的沸点。
There's a volume, there's a temperature, than the pressure here. There's other volume, temperature and pressure here, corresponding to this system here.
温度等状态函数有本质区别,这个状态有一组,确定的体积,温度与压强。
So that you could see that for the ideal gas, u would not be a function of volume, but only of temperature.
所以我们可以看到对理想气体,内能不依赖于体积,而仅仅是温度的函数。
OK, now, we're going to look at the internal energy, and we're going to pretend that it is explicitly a function of temperature and volume.
好,我们接下来看看内能,我们假设,它是温度和体积的函数。
So for an ideal gas, we saw that u was only a function of temperature.
对于理想气体,我们知道内能只是温度的函数。
But it's allowed to say the internal energy is a function of temperature and volume.
但是我们也可以说内能,是温度和体积的函数。
Similarly for G as a function of temperature and pressure, I can go through the same procedure.
同样的G作为,温度和压强的函数,我可以采用相同的步骤。
Pressure has dropped out of the picture completely here. So there is no p dependence here.
理想气体的H只是温度的函数,这对于真实气体来说是。
That u is a function of temperature only.
内能只是温度的函数。
It's the function of temperature, as B.
它是温度的函数。
In general, temperature and volume or pressure.
一般来说写成了温度,体积和压强的函数。
Cv So, for Cp and Cv, these are often quantities that are measured as a function of temperature, and one could, in fact, calculate this integral.
一般Cp和,都是温度的函数,因此实际上,我们可以将这个积分计算出来。
Therefore, from experiments, u is only a function of temperature for an ideal gas, H and therefore from these experiments, 0 we come out with delta H dH/dp is equal to zero.
因此,从实验可以得出,对于理想气体u只是温度的态函数,因此从这些实验中我们得到Δ,偏H偏p等于。
Now, before, of course, in the first part of the class u we started out looking at u H and then looking at H not as functions of S and V or S and p, but as functions of temperature, mostly.
现在,在本课的前一部分,我们首先讨论了,然后讨论了,这两个量并未写成S和V或者S和p的函数,而是写成了温度的函数。
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