And in this case we're going to look at silicone, and we'll say if you can point out to me which requires the least amount of energy.
这次我们要做的是关于硅的,我们来看看大家是不是,能够为我指出那一项需要消耗的能量最少。
The electron's going to come out of that highest occupied atomic orbital, that one that's the highest in energy, because that's going to be the at least amount of energy it needs to eject something.
这个电子应该是从,最高的被占据轨道上出来的,它的能级是最高的,因为这样的话发射出它,只需要消耗最少的能量。
If we have too much gas in here, in other words, if the gas is at too high a pressure, the collisions with the gas molecules will consume the energy of the electrons and, again, we will see nothing.
假设这里有过多气体,换句话说,如果气体处在一个高压状态下,气体分子间的碰撞将会消耗,电子的能量,同样,什么也没有。
The top priority on the right has become to spend energy.
而右边的则是消耗能量
So, second ionization energy simply means you've already taken one electron out, now how much energy does it take for you to take a second electron out.
第二电离能简单地说就是,在你已经拿走一个电子以后,再拿走第二个电子,所需要消耗的能量。
Alumina is really stable, which is why it takes so much energy to make aluminum.
矾土相当稳定,这就是为什么需要消耗大量的能量制备铝了。
Now this is a good place to start, because we are very familiar with ionization energy, we've been talking about it it's that minimum energy required to remove an electron from an atom.
现在这是一个开始下面内容的好地方,因为我们已经很熟悉电离能了,我们从很久以前就一直在讨论,它是从一个原子中,拿走一个电子所需要消耗的最低能量。
And when it falls back down that energy is given off.
当它回去的时候,它的能量也消耗殆尽了。
Well, electrolysis of water consumes energy.
好了,电解水消耗了能量。
And that amount of energy will be subtracted.
那些能量将会被消耗掉。
If you take in more calories than you consume, it gets stored in the fat cells, that's the energy bank that you can draw upon if you don't have enough food and starvation or famine were an issue.
如果你摄入的热量超过消耗的,热量就会存储在脂肪细胞中,这就是能量库,你可以在,食物不够以及饥饿或饥荒的时候利用它
So in the case of 12 32, that is our highest kinetic energy, it's the smallest amount of energy it takes to pop an electron out of that orbital.
因此,1232是我们能够得到的,最高的动能,它是从这个轨道中,打出一个电子需要消耗的最低能量。
And the truth is that yes, this costs energy, we're going up to a higher energy state.
事实上,它需要消耗能量,我们到了一个更高的能量状态。
In the case of energy expenditure, how many calories people were burning, there wasn't quite such a difference, but again, it was in the favor of the individuals, that the people were estimating they burned this many calories from physical activity, but this is actually the number that they burned.
就能量消耗来说,人们消耗了多少卡路里,两者之间的差异并不是如此巨大,但又一次,由于人们的一厢情愿,人们估算从体育活动中,他们消耗了这么多的卡路里,但数据是他们实际消耗的
But actually there is a little bit of an energy cost into doubling up into a single orbital, because, of course, it takes energy when you create more electron repulsion, that's not something we want to do, but we have to do it here, and it turns out that that effect predominates over, again, the energy that we gain by increasing the atomic number by one.
但实际上,在一个轨道上放两个电子,确实会亏损一点能量,因为,当你加入更多电子,引起更大的排斥能,这显然会消耗能量,这不是我们想要做的,但是在这种情况下我们不得不做,结果这一影响,超过了增加一个,原子序数所得到的能量。
So let's think about the energy required now to remove a 2 s electron, let's say we're removing it from boron plus 1 versus neutral boron.
那么让我们来想一想,拿走一个,2,s,电子所消耗的能量,假设一个是从正一价硼离子中拿走1,另一个是从中性硼原子中拿走。
p So to jump from the 2 s to the 2 p, takes more energy than we can actually compensate with by increasing the pull from the nucleus.
也就是,从,2,s,跃迁到,消耗的能量超过了,由于原子核的引力增强而补偿的能量。
And if that is the energy to go from n equals one n=2 this is the amount of energy that has to be left as kinetic energy of the electron.
如果这个能量是从n=1到,然后,to,n,equals,two,then,这些能量,会作为电子的动能,被消耗掉。
But it doesn't actually cost as much energy as you might think, because in this s orbital here we have a paired electron situation where we're moving up to a p orbital where the electron is no longer paired, so it won't feel quite as much electron repulsion, but nonetheless, this is going to cost us energy.
但它消耗的并没有,你们想象的那么多,因为s轨道里我们电子是配对的,当我们把,电子移到p轨道,电子不再配对,所以它不会感受到那么多的电子排斥,但尽管如此,这个过程还是要消耗能量的。
And the reason is simply because the energy that Z we gain in terms of moving up in z, 5 so from going to z equals 4 to z equals 5, -- is actually outweighed by the energy it takes to go into this new shell, to go into this new sub shell.
原因很简单,就是因为我们通过提升,所得到的能量--从,Z,等于,4,到,Z,等于,事实上比填充到这个新的壳层,新的亚壳层,所消耗的能量更多。
应用推荐