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Yes. In fact, there is not enough energy in a single photon to go ahead and eject an electron from this zinc surface.
是的，事实上，这里的光子没有足够的能量,去从锌表面逐出一个电子。
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you know, it's an energy in Hollywood that you don't find most places, you know.
你知道吗？ 好莱坞有一种大部分地方没有的能量。
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So in this case, we don't have enough energy to eject an electron, so, an electron is not ejected.
所以在这种情况下，我们没有足够的能量,去逐出一个电子，这样没有电子被逐出。
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system is the opposite of the open system, no mass and no energy can flow through the boundary.
孤立系与开系正相反，没有质量或能量,能流过它的边界。
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It is no longer tethered to the nucleus so there is no energy stored in the system.
它已经不再受原子核的吸引,所以这个系统中没有能量储存了。
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They're not interacting at all so that's why the energy is the same as that for two individual atoms, that's what we're dealing with. As we get closer together, we start get lower and lower in energy.
它们之间没有任何相互作用，因此,体系的能量就等于两个分开的原子的能量，这就是我们要处理的，而随着我们的距离越来越近，我们的能量开始变得越来越低。
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So, the take-home message is whether you have three photons or 3,000,000 photons that you're shooting at your metal, if you're not at that minimum frequency or that minimum energy that you need, nothing is going to happen.
所以，这里表明的信息是,无论是向金属发射3个光子,还是300万个光子,如果没有达到所需的最低频率,或者最小能量,什么事情都不会发生。
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The boundary is impervious to transfer of heat like a thermos Anything that happens inside of the thermos is an adiabatic change because the thermos has no connection in terms of energy to the outside world.
边界不能传递热量,像热水瓶一样,热水瓶里发生的任何事,都是绝热变化,因为热水瓶与外部世界,没有能量方面的联系。
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If we have too much gas in here, in other words, if the gas is at too high a pressure, the collisions with the gas molecules will consume the energy of the electrons and, again, we will see nothing.
假设这里有过多气体，换句话说，如果气体处在一个高压状态下，气体分子间的碰撞将会消耗,电子的能量，同样，什么也没有。
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It only cares what temperature is. If temperature is constant, there's no change in energy.
如果温度是常数,能量就没有变化，对理想气体。
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So, let's take a look here at an example of an energy diagram for the hydrogen atom, and we can also look at a energy diagram for a multi-electron atom, and this is just a generic one here, so I haven't actually listed energy numbers, but I want you to see the trend.
所以让我们来看看,一个例子氢原子的能量图，我们也可看看一个,多电子原子的能量图，这是一个普通的图谱，我没有列出能量的数字，但是我想让你们看这个趋势。
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So you don't want to put in a negative energy, that's not going to help you out, you need to put in positive energy to get an electron out of the system. So that's why you'll find binding energies are always negative, and ionization energies are always going to be positive, or you could look at the equation and see it from there as well.
因为这对电离没有帮助,你需要一个正的能量,使得电子脱离这个系统,这就是为什么你会发现,结合能总是负的而电离能总是正的,或者你们看这个方程也可以发现这一点。
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The reason it's aluminum is because aluminum has a lower z effective, so it's not being pulled in as tightly by the nucleus, and if it's not being pulled in as tightly, you're going to have to put in less energy in order to ionize it, so that's why it's actually going to have the smaller ionization energy.
原因是,铝的有效核电量更少，所以没有被原子核束缚得更紧，而如果没有被束缚得更紧，你为了电离它所需要注入的能量也就更少，这就是,它的电离能会更低的原因。
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And I have purposely made the arrow shorter to indicate that it has been slowed because we are going to argue its mass didn't change, so the only way to change its energy is to change its velocity.
我已经故意将这个箭头弄短,用来象征它变慢了,因为我们将证明它的质量没有变，只有它的能量改变了,也就是它的速度变了。
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So, we see that the two h atoms separate have a certain energy that's lower than when the electron's not with the atom.
那么，我们看到两个分开的氢原子所具有的能量,比原子中没有电子时更低。
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There's an interplay between the energy inside the gas which is the heat energy which is allowing me to do all that work to be outside, and so I'm using up some of the energy that's inside the gas to do the work on the outside.
即使没有热传递,能量也能以,做功的形式传递出去，气体的一部分内能,转化成了功。
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And what about who thinks that we will not have enough energy here?
那谁认为这种情况下,没有足够的能量呢？
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It doesn't actually have an electron in it, so we don't have to worry about whether it's very high in energy or not, we don't care that it's high in energy.
你也许会想，为什么我们不杂化这个2py轨道,它里面没有电子，所以我们不用管它的能量。
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But we haven't yet addressed why, for example, a 2 s orbital islower in energy than the 2 p orbital, or why, for example, a 3 s orbital is lower in energy than a 3 p, which in turn is lower than a 3 d orbital.
但是我们还没有强调为什么，举个例子一个2s轨道能量低于2p轨道,或者为什么，举例来说它依次低于3d轨道,屏蔽一个3s轨道的能量小于3p轨道。
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So we can compare the two electron configurations, and we can actually think about what we figure out from them, we see that two are lowered in energy, two electrons are raised in energy, so we have no net gain or no net loss in energy for h e 2.
我们可以比较两种电子构型，我们可以考虑,我们发现这，两个电子能量变低，两个电子能量升高，所以在He2里没有净的能量得失。
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