• I'm going to write it like this three moles of hydrogen which is a gas one bar 100 degrees Celsius.

    我会写成这样:,三摩尔分子,气体,1巴,100摄氏度。

    麻省理工公开课 - 热力学与动力学课程节选

  • HBr So for example, if I want to look at HBr there's a simple case, right, hydrogen bromine.

    如果我想研究,这是个简单的例子,溴化

    麻省理工公开课 - 热力学与动力学课程节选

  • It is a double column, You can see, it starts with hydrogen and goes to mercury in ascending order of atomic mass.

    双纵栏,你们看到,从开始,然后到水银,按原子质量的升序排列。

    麻省理工公开课 - 固态化学导论课程节选

  • So when we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding h atom orbitals.

    它们的能量实际上,比对应的,原子轨道要低。

    麻省理工公开课 - 化学原理课程节选

  • The ones that are most important in physiology are ones that only allow ions to go through: sodium, potassium, chloride, calcium, bicarbonate.

    在生理学上这种,只能允许某种离子通过的通道十分重要,这些离子包括钠离子,钾离子,氯离子,钙离子和碳酸根离子

    耶鲁公开课 - 生物医学工程探索课程节选

  • If we take hydrogen peroxide in the liquid state, it can break down to form water and oxygen.

    如果我们有一些液态的过氧化,它会分解成水和氧气。

    麻省理工公开课 - 热力学与动力学课程节选

  • I mean, you would expect that the group one, absent hydrogen, would be the ones that would have the least.

    我想,你们可能认为第一主族,没有,而应该是最小的。

    麻省理工公开课 - 固态化学导论课程节选

  • In contrast, the dissociation energy of a bond for hydrogen, and molecular hydrogen is everywhere around us, we see 432 kilojoules per mole.

    相反,分子在我们周围到处都是,一个分子的离解能,是432千焦每摩尔。

    麻省理工公开课 - 化学原理课程节选

  • I'm not going to writegiven threemoles of hydrogen at one bar and three degrees, blah,bla I'm going to write it in a compact notation.

    我不会写“给定1巴和多少度下,的三摩尔分子之类,我会把它写成一个紧凑的形式。

    麻省理工公开课 - 热力学与动力学课程节选

  • In 1896, Charles Pickering from Harvard found a series of lines in starlight which he attributed to hydrogen, even though they did not fit Balmer.

    在1896年,来自哈佛的查尔斯皮克林发现,一系列的星光,他认为那是的作用,虽然它们与巴尔末理论不符。

    麻省理工公开课 - 固态化学导论课程节选

  • So what we can actually directly compare is the dissociation energy or the bond strength of nitrogen versus hydrogen.

    因此实际上我们可以直接进行比较,对氮分子与分子的离解能,或键的强度。

    麻省理工公开课 - 化学原理课程节选

  • The reason is because we already have a full valence shell for our hydrogen, it doesn't want any more electrons.

    原因是因为我们的,已经有一个排满的价壳层了,它不再需要多余的电子了。

    麻省理工公开课 - 化学原理课程节选

  • So, for example, hydrogen or fluorine they'll never be in the middle, they'll always be on the end of a molecule.

    比如,或者氟,永远不会在中间,它们总是会在分子中最边缘的位置。

    麻省理工公开课 - 化学原理课程节选

  • Hydrogen gas it's in its most stable state, right at room temperature and pressure.

    和常压下气是元素,最稳定的状态,这个小“0“

    麻省理工公开课 - 热力学与动力学课程节选

  • So what that means is that's how much energy we would have to put into a hydrogen molecule in order to get it to split apart into its two atoms.

    它的意义,就是我们需要向一个分子中注入这么大的能量,才能将它分解成两个独立的原子。

    麻省理工公开课 - 化学原理课程节选

  • So let's take the case of acetylene where we have two carbon atoms that are going to be triple bonded to each other, each are bonded to a carbon and then to one hydrogen.

    让我们来看一看乙炔的例子,我们有两个碳原子,成三键,每个碳和一个碳一个相连。

    麻省理工公开课 - 化学原理课程节选

  • Well, we would have to H+ have one of these hydrogen atoms go to an H plus, * plus an electron, right? **H --> H+ + e-** So, now we have a hydrogen ion here.

    我们先要让,一个原子变成离子,加上一个电子,对么*,我们现在有一个离子了。

    麻省理工公开课 - 固态化学导论课程节选

  • I heard some people say one, and that's a good guess, remember they're actually sharing. So these two electrons, they belong to chlorine, they also belong to hydrogen, but they do, in fact, belong to chlorine as well.

    我听到有些人说的是一个,这是个很好的猜测,但要记得它们其实是被共用的,因此有两个电子,它们属于氯,同时也属于,但实际上它们也属于氯。

    麻省理工公开课 - 化学原理课程节选

  • So, let's compare this to the energy of the h 2 molecule, and we find that that's negative 3,048 kilojoules per mole.

    那么,让我们将它与分子的能量比一比,我们发现分子的能量是负的,3048,千焦每摩尔。

    麻省理工公开课 - 化学原理课程节选

  • This is the homonuclear bond energy for hydrogen in pure hydrogen. There we have perfect covalency.

    这是的同原子的共价能,在纯中,我们有完美的共价键。

    麻省理工公开课 - 固态化学导论课程节选

  • Well, oxygen, we'll put a hydrogen here, 1 2 3 4 hydrogen here, and one, two, three, four.

    如果把一个放在这边,另一个这边,然后。

    麻省理工公开课 - 固态化学导论课程节选

  • And since carbon's electronegativity is higher than that of hydrogen, which you would expect from where carbon lies on the Periodic Table. Think about it.

    碳的高于的,你也可以从碳在,元素周期表上的位置,判断出来,试想一下。

    麻省理工公开课 - 固态化学导论课程节选

  • Burn coal to make it, catalytic decomposition of methane, you get the hydrogen, where does the carbon go?

    通过烧煤得到,催化分解甲烷,可以得到,碳去哪儿了?

    麻省理工公开课 - 固态化学导论课程节选

  • So let's draw the electron configuration of hydrogen, the molecule, molecular hydrogen.

    让我们来画原子的,电子构型,分子,分子。

    麻省理工公开课 - 化学原理课程节选

  • We told you that phosphorous has 5 valence electrons plus 3 from each of the hydrogens, so we have a total of 8 valence electrons.

    我告诉过你们磷有5个价电子,另外有3个,所以我们一共有8个价电子。

    麻省理工公开课 - 化学原理课程节选

  • If we know that this is it the dissociation energy for a hydrogen atom, we can also say the bond strength for hydrogen molecule 424 is 424.

    如果我们知道了这是一个分子的离解能,那么我们也可以说分子的键的强度,就是。

    麻省理工公开课 - 化学原理课程节选

  • And so we can actually think about how do we calculate what the dissociation energy should be for h 2, so let's go ahead and do this.

    因此,我们其实可以想到应该如何计算,分子的离解能,那么我们开始做一下吧。

    麻省理工公开课 - 化学原理课程节选

  • We saw the Schr?dinger equation for atomic hydrogen, but you can write it for more complex systems.

    我们看过原子的薛定谔方程,但其实我们能把他用在更复杂的体系。

    麻省理工公开课 - 固态化学导论课程节选

  • So it's going to be a sigma bond, 1s and we have oxygen 2 s p 3 and hydrogen 1 s.

    它是sigma键,我们有氧2sp3和

    麻省理工公开课 - 化学原理课程节选

  • So, people are talking about the use of hydrogen in fuel cells.

    人们在讨论,如何把用在燃料电池中。

    麻省理工公开课 - 固态化学导论课程节选

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