I'm going to write it like this three moles of hydrogen which is a gas one bar 100 degrees Celsius.
我会写成这样:,三摩尔氢分子,气体,1巴,100摄氏度。
HBr So for example, if I want to look at HBr there's a simple case, right, hydrogen bromine.
如果我想研究,这是个简单的例子,溴化氢。
It is a double column, You can see, it starts with hydrogen and goes to mercury in ascending order of atomic mass.
双纵栏,你们看到,从氢开始,然后到水银,按原子质量的升序排列。
So when we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding h atom orbitals.
它们的能量实际上,比对应的氢,原子轨道要低。
The ones that are most important in physiology are ones that only allow ions to go through: sodium, potassium, chloride, calcium, bicarbonate.
在生理学上这种,只能允许某种离子通过的通道十分重要,这些离子包括钠离子,钾离子,氯离子,钙离子和碳酸氢根离子
If we take hydrogen peroxide in the liquid state, it can break down to form water and oxygen.
如果我们有一些液态的过氧化氢,它会分解成水和氧气。
I mean, you would expect that the group one, absent hydrogen, would be the ones that would have the least.
我想,你们可能认为第一主族,没有氢,而氢应该是最小的。
In contrast, the dissociation energy of a bond for hydrogen, and molecular hydrogen is everywhere around us, we see 432 kilojoules per mole.
相反,氢分子在我们周围到处都是,一个氢分子的离解能,是432千焦每摩尔。
I'm not going to writegiven threemoles of hydrogen at one bar and three degrees, blah,bla I'm going to write it in a compact notation.
我不会写“给定1巴和多少度下,的三摩尔氢分子之类,我会把它写成一个紧凑的形式。
In 1896, Charles Pickering from Harvard found a series of lines in starlight which he attributed to hydrogen, even though they did not fit Balmer.
在1896年,来自哈佛的查尔斯皮克林发现,一系列的星光,他认为那是氢的作用,虽然它们与巴尔末理论不符。
So what we can actually directly compare is the dissociation energy or the bond strength of nitrogen versus hydrogen.
因此实际上我们可以直接进行比较,对氮分子与氢分子的离解能,或键的强度。
The reason is because we already have a full valence shell for our hydrogen, it doesn't want any more electrons.
原因是因为我们的氢,已经有一个排满的价壳层了,它不再需要多余的电子了。
So, for example, hydrogen or fluorine they'll never be in the middle, they'll always be on the end of a molecule.
比如,氢或者氟,永远不会在中间,它们总是会在分子中最边缘的位置。
Hydrogen gas it's in its most stable state, right at room temperature and pressure.
和常压下氢气是氢元素,最稳定的状态,这个小“0“
So what that means is that's how much energy we would have to put into a hydrogen molecule in order to get it to split apart into its two atoms.
它的意义,就是我们需要向一个氢分子中注入这么大的能量,才能将它分解成两个独立的原子。
So let's take the case of acetylene where we have two carbon atoms that are going to be triple bonded to each other, each are bonded to a carbon and then to one hydrogen.
让我们来看一看乙炔的例子,我们有两个碳原子,成三键,每个碳和一个碳一个氢相连。
Well, we would have to H+ have one of these hydrogen atoms go to an H plus, * plus an electron, right? **H --> H+ + e-** So, now we have a hydrogen ion here.
我们先要让,一个氢原子变成氢离子,加上一个电子,对么*,我们现在有一个氢离子了。
I heard some people say one, and that's a good guess, remember they're actually sharing. So these two electrons, they belong to chlorine, they also belong to hydrogen, but they do, in fact, belong to chlorine as well.
我听到有些人说的是一个,这是个很好的猜测,但要记得它们其实是被共用的,因此有两个电子,它们属于氯,同时也属于氢,但实际上它们也属于氯。
So, let's compare this to the energy of the h 2 molecule, and we find that that's negative 3,048 kilojoules per mole.
那么,让我们将它与氢分子的能量比一比,我们发现氢分子的能量是负的,3048,千焦每摩尔。
This is the homonuclear bond energy for hydrogen in pure hydrogen. There we have perfect covalency.
这是氢的同原子的共价能,在纯氢中,我们有完美的共价键。
Well, oxygen, we'll put a hydrogen here, 1 2 3 4 hydrogen here, and one, two, three, four.
如果把一个氢放在这边,另一个氢这边,然后。
And since carbon's electronegativity is higher than that of hydrogen, which you would expect from where carbon lies on the Periodic Table. Think about it.
碳的高于氢的,你也可以从碳在,元素周期表上的位置,判断出来,试想一下。
Burn coal to make it, catalytic decomposition of methane, you get the hydrogen, where does the carbon go?
通过烧煤得到,催化分解甲烷,可以得到氢,碳去哪儿了?
So let's draw the electron configuration of hydrogen, the molecule, molecular hydrogen.
让我们来画氢原子的,电子构型,分子,氢分子。
We told you that phosphorous has 5 valence electrons plus 3 from each of the hydrogens, so we have a total of 8 valence electrons.
我告诉过你们磷有5个价电子,另外氢有3个,所以我们一共有8个价电子。
If we know that this is it the dissociation energy for a hydrogen atom, we can also say the bond strength for hydrogen molecule 424 is 424.
如果我们知道了这是一个氢分子的离解能,那么我们也可以说氢分子的键的强度,就是。
And so we can actually think about how do we calculate what the dissociation energy should be for h 2, so let's go ahead and do this.
因此,我们其实可以想到应该如何计算,氢分子的离解能,那么我们开始做一下吧。
We saw the Schr?dinger equation for atomic hydrogen, but you can write it for more complex systems.
我们看过原子氢的薛定谔方程,但其实我们能把他用在更复杂的体系。
So it's going to be a sigma bond, 1s and we have oxygen 2 s p 3 and hydrogen 1 s.
它是sigma键,我们有氧2sp3和氢。
So, people are talking about the use of hydrogen in fuel cells.
人们在讨论,如何把氢用在燃料电池中。
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