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I'm going to write it like this three moles of hydrogen which is a gas one bar 100 degrees Celsius.
我会写成这样：,三摩尔氢分子，气体,1巴，100摄氏度。
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The molar volume is being changed a little bit trying to make things collide with each other, they can't occupy the same volume.
摩尔体积发生了很小的改变,如果你试图使气体分子间相互碰撞，他们不能占据同一个位置。
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If we have too much gas in here, in other words, if the gas is at too high a pressure, the collisions with the gas molecules will consume the energy of the electrons and, again, we will see nothing.
假设这里有过多气体，换句话说，如果气体处在一个高压状态下，气体分子间的碰撞将会消耗,电子的能量，同样，什么也没有。
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This is the fact that we occupy a finite volume in space, because they're little hard spheres in this molecule.
这是由气体分子在空间中,占据有限体积造成的,因为事实上它们是硬的小圆球。
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Higher entropy basically because you're forming molecules of gas where there weren't any before, and there's more disorder in the gas phase than in the liquid. That is, the gas phase molecules have more freedom to roam.
高的熵是因为,我们产生了以前不存在的气体分子,气体的无序程度比液体大，换句话说,气相的分子，有更多的到处游荡的自由度。
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So instead of v bar, we write p v bar minus b, equal r t.
现在考虑，这些气体分子之间。
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There's p1 here, and p2 here So I'm starting at p1, V1. I'm starting right here And I'm going to end right here.
它的分子间作用力很小,十分接近理想气体,对它做一个压缩过程。
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I would say with the aid of an energy level diagram explain the fact that helium is found as atomic gas and not molecular. How about this one?
我要说的是，在能级图的帮助下,可以解释氦气是单原子气体,而不是分子气体这一事实,那么这个呢？
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It means that the molecules or the atoms and the gas don't know about each other.
气体分子本身的体积,可以忽略不计。
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You make the volume infinitely large, the density of the gas infinitely small.
密度无限小，气体分子之间的相互作用。
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You don't have gas molecules consisting of thousands of atoms.
并没有这样的气体分子,它们是由成千上万的原子组成。
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See, this is the property of an ideal gas.
它意味着气体分子。
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I mean, if the energy is lower to occupy a smaller volume, then if I have this room and a bunch of molecules of oxygen, and nitrogen and what have you in the air, and there are weak attractions between them, why don't they all just sort of glum together and find whatever volume they like.
我的意思是，如果占据小的体积会使能量降低，如果我有这样一个空间,和一些氧气，氮气和其他空气中有的气体，并且分子之间还有微弱的相互作用，为什么他们不黏在一起,然后占据他们所想要占据的体积。
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And then V minus the excluded volume term is equal to RT. Two parameters, this is the attraction between two atoms or molecules in the gas phase.
以及V减去一个排斥项,等于RT，两个参数，这是气体状态下两个原子,或者分子之间的吸引力。
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If z is greater than 1, then the real gas means that the atoms and molecules in the real gas are repelling each other and wants to have a bigger volume.
如果Z大于,说明实际气体的分子间斥力较强,体积比理想气体要大,我们可以查表找到。
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So the real pressure is not quite the same because of this attractive force as it was, as it would be without the attractive forces.
气体压强,由于分子间的吸引作用,会比理想气体要小,这样，我们应该修正p的值。
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Let's build this up. Let's see where this comes from, where these parameters a and b comes from. So, the first thing we're going to do is we're going to take our gas in our box, let's build a box full of gases here.
参数a和b有什么含义,首先，假设研究的气体,都在一个容器里,容器里充满了气体,这些是气体分子。
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