So, basically any time we have a really high positive number of electron affinity, it means that that atom or ion really wants to gain another electron, and it will be very stable and happy if it does so.
因此,基本上无论什么时候,只要我们有一个很大的正的电子亲和能,这就意味着这个原子,或离子非常希望得到一个电子,如果它得到了,会变得更稳定更开心。
And this is just a picture showing some of these sizes with their parent. So, for example, a lithium here, you can see how lithium plus is smaller than the actual lithium atom in its neutral state.
这是一张对比图,展示某些离子与它们的母体,比如,这里是锂,大家可以看到正一价锂离子是多么的小,与中性锂原子相比。
So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.
这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。
It's always a good first approximation, because you need to start somewhere in terms of drawing Lewis structures, but then if you go and figure out the formal charge and you just have lots of charge separation or very high charges, like a plus 2 and a minus 2 and a minus 1 all different places in the atom, what it should tell you is maybe there's a better structure.
它总是一个好的第一近似,因为在画路易斯结构的时候,你总需要一个起点,但是如果你在算出形式电荷之后,发现有很多电荷分开了,或者说有很高的电荷,比如有一个正二,一个负二,还有一个负一1,在原子的各个地方,这应该就是在告诉你,或许还有一个更好的路易斯结构。
So let's think about the energy required now to remove a 2 s electron, let's say we're removing it from boron plus 1 versus neutral boron.
那么让我们来想一想,拿走一个,2,s,电子所消耗的能量,假设一个是从正一价硼离子中拿走1,另一个是从中性硼原子中拿走。
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