if we're actually thinking about electron configuration and we look at lithium, sodium and potassium, these all have one valence electron.
让我们来想一想,锂,钠,钾的电子排布,它们都只有一个价电子。
But, you can see, this is right out of his notebook, and you can see he's arranged the atoms by row.
但是,你能看到,这是他的记录本的右边,你能看到他按行对原子的排布。
So it looks like most of you got that the electron configuration that we're writing here is for copper.
看来大多数人,都看出了,这是铜原子的电子排布。
So, that's actually the electron configuration we have when we're talking about copper and some other exceptions in the periodic table that you're going to be looking at.
因此,这才是铜原子真正的电子排布,而且我们在元素周期表中,会看到与铜原子类似的,其他例外的情况。
So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.
负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。
What is the filling sequence of electrons in orbitals?
什么是电子在轨道上的排布顺序呢?
That is to say the instant atom arrangement.
也就是原子的几何排布类型。
And the reason that we use it is that it is incredibly accurate, and allows us to very, very quickly predict and to predict accurately, in most cases, what the electron configuration of molecules are going to be.
我们用它是因为它极为精确,并且能让我们非常非常快地预测,而且是准确地预测,大多数情况下,分子应该具有的电子排布。
I've got two states here, three states here, two here, I need four, and if I can come up with these bonds, four, by the Hund rule I'd fill them like this.
我们已经有2个状态在这里,3个在这里,2个在这里,我需要4个,如果我能想到这些键,四个,通过洪特规则,我们就能像这样排布。
So, if we want to think about what the first ionization energy is of boron, what you want to do is write out the electron configuration, because then you can think about where it is that the electron's coming out of.
如果我们要考虑,硼的第一电离能,你首先要做的是写出它的电子排布,因为在这之后,你才能知道拿走的是哪里的电子。
These are all isoelectronic, they all have the same electron configuration. And we can also think about going back to atomic size for a second.
这些都是等电子的,它们都有相同的电子排布,而,我们还可以再回想一下原子尺寸的概念。
Electrons will occupy orbitals in order of ascending energy, occupying the lowest energy first and up.
电子是按其能量递增顺序,排布在轨道上的,首先占满第一级,即最低能级。
And then it says, OK, distribute the remaining electrons in pairs so that each atom has eight.
然后它说,接下来将剩下的电子成对排布,使每个原子都有8个电子。
And I know there's a lot to talk about this competition, but let's just get into listening mode here and talk about how we can figure out what the correct electron configuration is for this ion.
我知道刚才关于这次比赛大家有很多话要聊,但是请大家先转换到听讲的模式,来看看如何才能弄清楚,这个离子正确的电子排布。
So for example, if we think about fluorine, 1 s 2 2 s 2 2 p 5 that has an electron configuration of 1 s 2, 2 s 2, 2 p 5, so all we would need to do is add one more electron to get the same configuration as for neon.
比如,如果我们考虑氟原子的话,它的电子排布是,因此我们所需要做的就是给它加上一个电子,使得它与氖原子的电子排布相同。
The first thing we need to do is write the electron configuration for the atom itself, and then we need to take an electron away.
首先我们要做的是,写出原子的电子排布,然后,我们再拿走一个电子。
So basically, at the time he was just going on size and then traits, but what we actually know today is that we can also order things in the periodic table by electron configuration.
基本上,在当时他只能通过大小,和特性来进行,但是现在我们已经知道了,我们还可以通过电子排布来对它们进行排序。
And that is that the energy levels themselves change with electron occupancy.
就是能级本身,也会随着电子的排布发生变化。
So, in this one we're selecting the correct electronic configuration for an ion.
那么,这次我们要做的是,选出一个离子正确的电子排布。
So this would be for the actual filled, the completely neutral atom.
因此,这就是中性原子,正确的电子排布。
So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.
这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。
In the first case, so here is the electron configuration of neon.
首先,这是氖原子的电子排布。
And that something else is essentially the filling sequence.
并且这些东西对轨道排布顺序,是至关重要的。
Let's move on to the last topic in terms of this first exam, which is thinking about the idea of isoelectronic atoms, or isoelectronic ions. And isoelectronic is very straightforward, it just means having the same electron configuration.
下面我们继续讲第一次考试的最后一个主题,也就是等电子原子,或等电子离子的概念,“等电子的“是非常直接的表达,它的意思就是具有相同电子排布的。
So, Lewis structures are really a model for a way to think about what the valence electron configuration is, and as I said, it's not based on quantum mechanics, it's something that Lewis observed far, far before quantum mechanics were discovered.
路易斯结构实际上是一个用来考虑价,电子排布的模型,而就像我说的,它并不以量子力学为基础,而是路易斯在以前发现的,在量子力学出现很早前。
And resonance is the idea that sometimes one single Lewis structure does not adequately describe the electron configuration around a given molecule, so instead you need to draw two different Lewis structures to describe that more appropriately.
而所谓共振态,就是有时候一个路易斯结构不足以,完整描述一个给定分子的电子排布,因此这时你需要同时画出两个,不同的路易斯结构来描述它,这样会更恰当。
He's taken the elements, and he's arranged them.
他在排布元素。
When we talk about resonance structures, we're talking about cases that have the same arrangement of atoms the key is the atoms are the same, and the thing that is different is the arrangement of electrons here.
当我们讨论共振结构的时候,我们讨论的是原子排布相同情况,关键在于原子是相同的,不一样的只是电子排布。
- The answer to that is definitely no -- if they had the same electron configuration, they would, in fact be neon. But we can think about different ions that have this electron configuration.
答案是绝对没有-,如果它们具有相同的电子排布,那么它们,实际上,将都是氖,但是我们可以想一想,有没有其它离子具有这种电子排布呢?
So if you flip the info page over on the back here, what you'll see is the periodic table, this is the same one that I've handed out in the last two lectures - the periodic table without any electron configurations.
将这张纸翻过来,你可以看到一个元素周期表,这与我们前两次课发过的,是一样的,-没有任何电子排布的周期表。
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