And what I want to point out here is this angular dependence for the p orbitals for the l equals 1 orbital.
这里我要指出的是,l等于1的p轨道随角度的变化。
So what I want to point out is that it creates an effect that is exactly opposite of a bond.
我要指出的是,它造成的效果和成键正好相反。
But I need to point out that there's another disadvantage that the fission case raises for the soul theory.
但我必须要指出,灵魂理论的裂变案例,其实还有一个缺点。
And again, this points out something I wanted to me-- I mentioned last time, list can be heterogeneous, in the sense that the elements can be multiple different types.
这儿又指出了一点我想要告诉大家的,我上节课也提到了,就是数组是多相的,也就是说元素可以是多种类型的。
I've begun to point out a few things that I think we miss: the fragmentation of bodies.
这就是我要指出的,我觉得大家错过了的东西。
So your position may be not believed, and I want to claim that that's connected to the idea that you can't commit yourself to your policies.
也就是说选民未必相信你的立场,我要指出的是这与,你无法执行相应政治策略是相关的
That was, I should point out, maybe about ten miles from the sea.
我要指出的是,那里距海大约有十英里远
I want to mention that 5 you're going to get problem-set five is posted today, and I'll write which ones you can already do so far, because you don't have class on Monday.
我要指出的是,今天会贴出来习题集,我会给出你们现在可以做的题目,因为周一没有课。
And I just want to point out here in terms of things that you're responsible for, you should know that the most probable radius for a 1 s hydrogen atom is equal a nought.
在这里,我想要指出的是,你们要知道氢原子1s轨道,最可能距离等于a0
So what I want to point out about them is that they're made up of two nodes, and what you can see is that nodes are shown in different colors here and those are different phases.
关于它们我要指出的是,它们有两个节点,你们可以看到在这里,这些节点的颜色不同,它们的相位不一样。
So I want to mention also, these are exactly equivalent, they're equivalent in energy, they're equivalent in shape.
我要指出的是,它们是完全等价的,它们在能量上等价,在形状上等价。
So even though we see a nodal plane down the center, I just want to really point out that it's only when we have a nodal plane in the internuclear or the bond axis that we're calling that a pi orbital.
虽然在中间有个节面,我想要指出的是,只有节面在核间轴,或者键轴上时,我们才叫它π轨道。
And again, I want to point out that a molecular orbital, we can also call that a wave function, they're the same thing.
同样,我要指出的是,一个分子轨道,我们也可以叫它波函数,这是一件事情。
The other thing I wanted to mention and I'm not sure if the exhibit's still there.
另外一个我想要指出的事情就是,我不确定它是不是还在展出。
So, this is really a pretty dangerous situation that's always interesting to point out.
所以我总要指出,这是个很危险的事情。
But still, let me quickly point out why you could resist the argument from free will to the existence of a soul.
但我还是要简短地指出,为什么你们会拒不认同,从自由意志的角度来论证灵魂的存在
The reason I want to point this out to you is, if we go back up to the kinds of data objects we started with, floats, ints, strings, they actually behave the same way.
我要为大家指出这一点的原因是,如果我们想一下以前讲过的,数据类型的种类,浮点数,整数,字符串,它们实际上有相同的行为方式。
Naming doesn't always make sense in chemistry, so I like to point out this is a place where naming does make a lot of sense.
在化学里,命名的意义不总是有的,我要指出,这里的命名是很有意义的。
The point I'm trying to make is, fixed-program computers is where we started, but it doesn't really get us to where we'd like to be.
我要指出的一点是,我们从固定程序计算机开始说起,但它并不能让我们到达我们想去的地方。
While I'm busy pointing out ways in which the argument doesn't succeed, I also want to just take a moment and mention that premise two is also subject to criticism.
当我竭力指出,为什么这种论证无法成功时,我也想要花点时间,顺便说说前提二也不能免于批评
And I also want to point out, it's guaranteed pretty much you may or may not be able to see, sometimes it's hard to see that one that's getting near the UV end of our visible spectrum. So we won't worry if we can't see that.
我要指出的是,我可以保证你们,但你们可能会看不到,有时候很难看到,这个可见光谱边缘接近紫外光地方的这根谱线,所以看不到也不用担心。
So, one thing they did, because it was so easy to measure kinetic energy of electrons, is plot the frequency of the light against the kinetic energy of the electron that's coming off here. And in your notes and on these slides here, just for your reference, I'm just pointing out what's going to be predicted from classical physics.
他们做的其中一件事,因为测量电子动能是很容易的,就是画出光的频率,和出射电子动能之间的关系,在讲义的这里,仅仅是,为了做个比较,我要指出,经典物理所给出的预测,这个不作为对你们的要求。
Something I'll also point out as you see these dashed line that tell you where the individual molecular orbitals are arising from, as you get to higher and higher atomic numbers of molecules that you're making, it makes a lot more sense to look at a diagram when you draw these dotted lines in, because they can start to get a little bit confusing.
我要指出的是,你们看这些虚线,它们告诉你,每个分子轨道的起源是什么,当你的原子数,越来越高的时候,画出这些点线,使图更容易理解,因为现在开始变得有一点混乱了。
So, I will point out, in terms of MO theory, because it rigorously does take into account quantum mechanics, it starts to become complicated once we go beyond diatomic molecules.
我要指出的是,对于MO理论,以为它严格的遵守量子力学,所以一旦超过双原子分子,就变得十分复杂了。
And what I want to point out that we just figured out for molecular orbital theory, is that o 2 is a biradical, because remember, the definition of a radical is when we have an unpaired electron.
我要指出的是,我们刚利用分子轨道理论,指导了O2是二价自由基,因为记住,自由基的定义是,有个未配对的电子。
Another thing I want to point out about every sigma orbital that you see, and it will make more sense when we contrast it with pi orbitals later.
另外一个我要指出的事情就是,关于每个sigma轨道你能看到,当我们把它和π轨道对比的时候会看的更清楚。
I can write it explicitly. I can write it inside of a FOR loop. And we've started to add, and we'll see a lot more of this, examples of collections of structures so that we don't just have to do something that can be easily described as walking through a set of things but can actually be a collection that you walk through.
我可以明确的写出来,我可以把它在FOR循环的内部写出来,然后我们开始学习了add这个运算符,我们会在以后学习很多的,集合的数据结构的例子,这样一来我们可以进行一些,很简单的遍历集合的操作,我想要为大家指出的最后一件事情是。
So what I want to point out with this case in beryllium is that you don't have to use all of the electrons to figure out the bond order, and in fact, once you get to molecules 10 that are from atoms with atomic numbers of 8 or 10, you're not going to want to maybe draw out the full molecular orbital diagram.
我要指出的是,在Be这种情况下,你不需要利用,所有的电子来指导键序,实际上,一旦分子中,原子序数到达了8或者,你也许不想画出,整个分子轨道图。
So what I want to point out when you're kind of looking at these numbers here, what the significance is, look at that huge difference between what the ionization energies are for what we call those valence electrons, -- those outer shell electrons, those are core electrons there.
我在这里想要指出的是,当大家在看这些数字的时候,最重要的是,要看到这些,巨大的差异,看到所谓价电子,即外层电子的电离能与,1,s,轨道,电离能之间的巨大差异。
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