Anything else, which is to say any spontaneous process, it'll be less than zero.
其它任何情况下,也就是任何自发过程,都将小于零。
We discovered that the quantity dA, under conditions of constant volume and temperature, dA TS And A is u minus TS.
我们发现在恒定的体积和温度下,亥姆赫兹自由能的变化,小于零,is,less,than,zero。,亥姆赫兹自由能A等于内能u减去。
A corporation is an entity that could be sued or could lose more money than it's worth, but the value of a corporation can never fall below zero to the investors because the investors are not liable for the mistakes of the corporation.
公司是一个实体,它可能被起诉,或者亏损额超过了自身的价值,但是对于投资者而言,公司的价值永远不会小于零,因为投资者对公司的过失,不负有责任
du external dV minus T surroundings dS is less than zero.
加上压强p,du,plus,p,乘以dV减去环境温度T乘以dS小于零。
So, du plus p dV is less than zero.
因此,du加上pdV需要小于零。
I can write this as d less than zero.
我可以把这个写成的d小于零。
Going around in a cycle the integral of dq over T is less than or equal to zero.
对一个循环过程作dq除以T的积分,小于等于零。
So we immediately get du at constant S and V is less than zero.
这样我们马上就得到以下结论:,在等熵,等容条件下dU必须小于零。
So all that's left is negative T dS is less than zero.
只剩下TdS小于零。
So if you had a high temperature, this a small compared to b. If you're negative which means that dT/dp at constant H is less than zero.
高于反转温度,这一项相比于b很小,意味着H恒定时,偏T偏p小于零。
So we could write that criterion as dH less than zero.
我们可以认为dH小于零即为我们的判据。
It means du is less than zero.
这意味着du小于零。
So in this experiment here, delta p is less than zero. You need to have this whole thing greater than zero. So delta T is less than zero as well. So if you're below the inversion temperature and you do the Joule-Thomson experiment, you're going to end up with something that's colder on this side than that side.
所以在这个实验中,Δp小于零,这全部都大于零,因此ΔT也小于零,所以如果在低于转变,温度的情况下做焦耳-汤姆孙实验,最后的结果是,这边的温度比这边低。
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