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And that will end up winning out at basically any realistic temperature where the stuff really is a gas.
在体系仍然处于气体状态的温度下,熵战胜了能量。
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A It tells me that the partial of A with respect to T at constant V is minus S. Right?
他告诉我们,在恒定体积下对温度的微分等于负S，对吗？
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We know how the volume and temperature vary with respect to each other at constant pressure.
知道在恒定压强下,体积如何随着温度变化。
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There's our condition for equilibrium at constant temperature and pressure.
这就是我们在,恒定温度和压强下的平衡条件。
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State one goes to state two. Let's have constant T.
在恒定的温度下。
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And where does that happen, At what temperature and pressure and so forth.
在什么温度，和压强下。
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If I'm working under conditions of constant temperature and volume, that's very useful.
如果在恒定的温度和体积下,进行一个过程，这是非常方便的。
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We discovered that the quantity dA, under conditions of constant volume and temperature, dA TS And A is u minus TS.
我们发现在恒定的体积和温度下，亥姆赫兹自由能的变化，小于零，is，less，than，zero。,亥姆赫兹自由能A等于内能u减去。
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p dA/dV, at constant T, must be negative p.
在恒定温度下，dA/dV等于。
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The dA/dV is calculated at constant temperature.
就像这样，dA/dV是在恒定温度下的偏导数。
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