And in this case, the tie-breaker goes to the molecule in which the negative charge is on the most electronegative atom.
而在这种情况下,我们需要进行“附加赛“,也就是看看分子中带有负的,形式电荷的原子是不是电负性最高的。
Now, chlorine I have to do a little bit more heavy lifting here because chlorine starts as a diatomic molecule.
现在,对于氯,我将会做更多的说明,因为氯元素起初存在于双原子分子中。
Step three in our Lewis structure rules is to figure out how many electrons we would need in order for every single atom in our molecule to have a full valence shell.
路易斯结构规则的第三步是,找出让分子中每个原子的价壳层,都排满应该需要多少个价电子。
Whereas in molecular orbital theory, what I'm telling you is instead we understand that the electrons are spread all over the molecule, they're not just associated with a single atom or a single bond.
而在分子轨道理论里,我要告诉你们的时,我们任为电子分布在整个分子中,它们不仅仅是和,一个原子或者一个键有关。
That is going to equal the energy of the electrons in H2 minus the energies of the electrons in H.
这等于H2分子的能量2,减去H原子中电子的能量。
And what you can see directly from looking at this energy level diagram, is that the molecule that we have is now more stable in the individual atoms.
你从直接看,能级图中会发现,分子比单个的,原子能量更低。
now we're dealing with a lot of different atoms in the molecule, much more complicated than the initial case of the cyanide ion where we only had two.
现在我们要面对的分子中有很多不同的原子,比我们一开始只有两个,原子的氰离子复杂多了。
And the last example that we're going to talk about is thionyl chloride, so it's s o c l 2. This is another good step forward, because now we actually have four different atoms in our molecule.
我们要讨论的最后一个例子,是氯化亚砜,就是硫,氧,氯,二,这又是一个进步,因为我们的分子中现在有四个不同的原子了。
if we have a very electronegative atom within a certain molecule, what you'll actually find is that it does affect how the molecule is going to take place or take part in different chemical or biological reactions.
如果在某个分子中有一个电负性很高的原子,你会发现它确实会影响到,这个分子所起的作用,在不同的化学反应或者生物反应中时。
So, we see is when we use the octet rule to look at fluorine molecule, we're combining two fluorine atoms, and what we end up with is an f f molecule where they're sharing two electrons, so making that covalent bond.
那么,我们看到把八隅体规则用到氟分子上,就是把两个氟原子组合起来,最终得到的氟分子中两个原子,共用一对电子,这就构成了共价键。
But you need to be able to predict what kind of properties a certain atom's going to have within a molecule, whether you're talking about something, for example, that's very electronegative, or something that is not electronegative at all, it is going to make a difference in terms of thinking about how molecules are structured and also how they interact with other molecules.
但是你需要能够预言,什么性质,某个原子在分子中能够具有,无论你讨论的是哪一种情况,比如,它有很高的电负性,还是它根本没有电负性,都将会产生影响,对这个分子的结构,以及与其它分子相互作用的情况。
So what I want to point out with this case in beryllium is that you don't have to use all of the electrons to figure out the bond order, and in fact, once you get to molecules 10 that are from atoms with atomic numbers of 8 or 10, you're not going to want to maybe draw out the full molecular orbital diagram.
我要指出的是,在Be这种情况下,你不需要利用,所有的电子来指导键序,实际上,一旦分子中,原子序数到达了8或者,你也许不想画出,整个分子轨道图。
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