CO Right, so you take the co here, and we take the valence here, and out of that comes covalent.
好了,然后我们看到,我们可以看到他的化合价,他们成共价键。
OK, so what we've gone through today is we've introduced covalent bonding, and we've figured out a way to quantify it.
好的,那么我们已经经历了,是我们已经介绍了共价键,我们已经想出了一种定量的方法来。
A covalent bond is any time we have a pair of electrons that is shared between two different atoms.
所谓共价键就是我们有两个原子,共用一对电子。
There's not actually chemical covalent bonds that are formed but it's a non-covalent interaction, usually dominated by hydrogen bonding.
所以配体和受体之间不生成共价键,这是一种非共价化合反应,它们通常以氢键相联
And when we talk about covalent bonds, there's 2 properties that we'll mostly focus on, and that's going to be thinking about the bond strength or the energy by which it stabilized when it bonds.
而当我们讨论共价键的时候,有两点特性是我们最关注的,那就是键的强度,或者说成键之后能量降低了多少。
So, somewhere in between, the bonds are, we have a range of bonds between ionic on the one hand, and perfectly covalent on the other hand.
因此在中间,这些键,一方面是离子性,另一方面是完美的共价键。
On the other hand, if we have a perfect covalence bond, we have identical equal sharing.
另一方面,如果我们有一个完美的共价键,有相同程度的电子共享。
So as we said when we first introduced covalent bonds, it's a sharing of electrons, but it's not always an equal sharing.
当我们刚开始介绍共价键的时候,我们说过电子是被共用的,但是共用却不一定是均等的。
As we see a little bit later, I could talk about the carbon-hydrogen bond in methane where there is a plurality of bonds. In this case, there is only the one bond but I just want to get the formulas.
因为我们后来看到一点点,我能讨论甲烷中的碳氢共价键,那有许多共价键,这种情况下,这只有一条共价键,但我想得到氟。
So, that's basically the idea of how we are going to be thinking about covalent bonds.
那么,这就是我们所应该想到的基本思路,在考虑共价键时。
So, in fact, yes, we did confirm that these covalent bond, at least in the case of hydrogen, we have confirmed by the numbers that we are at a lower energy state when we talk about the bonded atom versus the individual atom.
因此,事实上,是的,我们证实了共价键,至少在氢这种情况下,我们通过数据证实了,成键的原子处于能量更低的状态,当其与单个的原子相对比时。
So, we see is when we use the octet rule to look at fluorine molecule, we're combining two fluorine atoms, and what we end up with is an f f molecule where they're sharing two electrons, so making that covalent bond.
那么,我们看到把八隅体规则用到氟分子上,就是把两个氟原子组合起来,最终得到的氟分子中两个原子,共用一对电子,这就构成了共价键。
He introduced the concept of electronegativity which was a measure, therefore, it is quantitative, of the atom's ability to attract electrons within a covalent bond and developed a scale of electronegativity.
他引入了电负性这一概念,一个反映着原子在成共价键时吸引电子的能力的数据标度,因此这是数量上的,在共价电子中,电子原子能吸引电子,并发展为一定规模的电负性。
This is the homonuclear bond energy for hydrogen in pure hydrogen. There we have perfect covalency.
这是氢的同原子的共价能,在纯氢中,我们有完美的共价键。
So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.
那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。
He said that is going to equal one minus the exponential.
一根共价键中,离子百分数等于。
That is what gets crunched down to covalent bonding.
这就要归结与共价键。
And the key word for covalent bonds is the idea of being shared.
而关于共价键最关键的一点就在于共用的概念。
The ability of an atom to attract electrons, and in particular, in a covalent bond.
原子对电子的吸引能力,特别是在共价键中。
He's famous for a lot of things, one of which is covalent bonding.
他有许多著名的发现,其中一个便是共价键。
Just so that we are clear, this is the bond in this compound.
所以我们明白,这是化合物中的共价键。
OK, he also, let me see, he also, lastly, to close us out, he also developed an analytical expression for the energy of that covalent bond, which is really what we want.
好的,他也,让我看看,他也,最终接近我们的,他也发明了一种分析方式,对于共价键能量来说,这是我们真正想要的。
This should make sense because if something has a low ionization energy, that means it's not very electronegative, which means it's going to be a lot happier giving up electron density, which is essentially what you're doing -- when you're forming covalent bonds is you're sharing some of your electron density.
这应该是合理的,因为如果某物的电离能很低,这也就意味着它的电负性也不高,那么它就会更愿意,放弃一定的电子密度,而本质上这正是你在,形成共价键时所需要做的,分享你的一些电子密度。
And then even lower down, we have our bonded hydrogen molecule.
然后继续降低,我们就有了通过共价键结合的氢分子。
So specifically, today we're going to talk about covalent bonds.
特别地,今天我们要专门讲一讲共价键。
And he coined the term "polar covalency."
他创造出还提出了一个属于有极性共价键“
What's the definition of the covalent bond?
共价键的定义是什么?
Well, with covalent bonding, it's not so simple.
但对于共价键就没这么简单了。
And so this is the H-F bond in HF.
所以这是氟化氢中的氢氟共价键。
And he coined the term covalent bonding.
他创造了共价键这一概念。
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