• CO Right, so you take the co here, and we take the valence here, and out of that comes covalent.

    好了,然后我们看到,我们可以看到他的化合价,他们成共价键

    麻省理工公开课 - 固态化学导论课程节选

  • OK, so what we've gone through today is we've introduced covalent bonding, and we've figured out a way to quantify it.

    好的,那么我们已经经历了,是我们已经介绍了共价键,我们已经想出了一种定量的方法来。

    麻省理工公开课 - 固态化学导论课程节选

  • A covalent bond is any time we have a pair of electrons that is shared between two different atoms.

    所谓共价键就是我们有两个原子,共用一对电子。

    麻省理工公开课 - 化学原理课程节选

  • There's not actually chemical covalent bonds that are formed but it's a non-covalent interaction, usually dominated by hydrogen bonding.

    所以配体和受体之间不生成共价键,这是一种非共价化合反应,它们通常以氢键相联

    耶鲁公开课 - 生物医学工程探索课程节选

  • And when we talk about covalent bonds, there's 2 properties that we'll mostly focus on, and that's going to be thinking about the bond strength or the energy by which it stabilized when it bonds.

    而当我们讨论共价键的时候,有两点特性是我们最关注的,那就是键的强度,或者说成键之后能量降低了多少。

    麻省理工公开课 - 化学原理课程节选

  • So, somewhere in between, the bonds are, we have a range of bonds between ionic on the one hand, and perfectly covalent on the other hand.

    因此在中间,这些键,一方面是离子性,另一方面是完美的共价键

    麻省理工公开课 - 固态化学导论课程节选

  • On the other hand, if we have a perfect covalence bond, we have identical equal sharing.

    另一方面,如果我们有一个完美的共价键,有相同程度的电子共享。

    麻省理工公开课 - 固态化学导论课程节选

  • So as we said when we first introduced covalent bonds, it's a sharing of electrons, but it's not always an equal sharing.

    当我们刚开始介绍共价键的时候,我们说过电子是被共用的,但是共用却不一定是均等的。

    麻省理工公开课 - 化学原理课程节选

  • As we see a little bit later, I could talk about the carbon-hydrogen bond in methane where there is a plurality of bonds. In this case, there is only the one bond but I just want to get the formulas.

    因为我们后来看到一点点,我能讨论甲烷中的碳氢共价键,那有许多共价键,这种情况下,这只有一条共价键,但我想得到氟。

    麻省理工公开课 - 固态化学导论课程节选

  • So, that's basically the idea of how we are going to be thinking about covalent bonds.

    那么,这就是我们所应该想到的基本思路,在考虑共价键时。

    麻省理工公开课 - 化学原理课程节选

  • So, in fact, yes, we did confirm that these covalent bond, at least in the case of hydrogen, we have confirmed by the numbers that we are at a lower energy state when we talk about the bonded atom versus the individual atom.

    因此,事实上,是的,我们证实了共价键,至少在氢这种情况下,我们通过数据证实了,成键的原子处于能量更低的状态,当其与单个的原子相对比时。

    麻省理工公开课 - 化学原理课程节选

  • So, we see is when we use the octet rule to look at fluorine molecule, we're combining two fluorine atoms, and what we end up with is an f f molecule where they're sharing two electrons, so making that covalent bond.

    那么,我们看到把八隅体规则用到氟分子上,就是把两个氟原子组合起来,最终得到的氟分子中两个原子,共用一对电子,这就构成了共价键

    麻省理工公开课 - 化学原理课程节选

  • He introduced the concept of electronegativity which was a measure, therefore, it is quantitative, of the atom's ability to attract electrons within a covalent bond and developed a scale of electronegativity.

    他引入了电负性这一概念,一个反映着原子在成共价键时吸引电子的能力的数据标度,因此这是数量上的,在共价电子中,电子原子能吸引电子,并发展为一定规模的电负性。

    麻省理工公开课 - 固态化学导论课程节选

  • This is the homonuclear bond energy for hydrogen in pure hydrogen. There we have perfect covalency.

    这是氢的同原子的共价能,在纯氢中,我们有完美的共价键

    麻省理工公开课 - 固态化学导论课程节选

  • So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.

    那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。

    麻省理工公开课 - 化学原理课程节选

  • He said that is going to equal one minus the exponential.

    一根共价键中,离子百分数等于。

    麻省理工公开课 - 固态化学导论课程节选

  • That is what gets crunched down to covalent bonding.

    这就要归结与共价键

    麻省理工公开课 - 固态化学导论课程节选

  • And the key word for covalent bonds is the idea of being shared.

    而关于共价键最关键的一点就在于共用的概念。

    麻省理工公开课 - 化学原理课程节选

  • The ability of an atom to attract electrons, and in particular, in a covalent bond.

    原子对电子的吸引能力,特别是在共价键中。

    麻省理工公开课 - 固态化学导论课程节选

  • He's famous for a lot of things, one of which is covalent bonding.

    他有许多著名的发现,其中一个便是共价键

    麻省理工公开课 - 固态化学导论课程节选

  • Just so that we are clear, this is the bond in this compound.

    所以我们明白,这是化合物中的共价键

    麻省理工公开课 - 固态化学导论课程节选

  • OK, he also, let me see, he also, lastly, to close us out, he also developed an analytical expression for the energy of that covalent bond, which is really what we want.

    好的,他也,让我看看,他也,最终接近我们的,他也发明了一种分析方式,对于共价键能量来说,这是我们真正想要的。

    麻省理工公开课 - 固态化学导论课程节选

  • This should make sense because if something has a low ionization energy, that means it's not very electronegative, which means it's going to be a lot happier giving up electron density, which is essentially what you're doing -- when you're forming covalent bonds is you're sharing some of your electron density.

    这应该是合理的,因为如果某物的电离能很低,这也就意味着它的电负性也不高,那么它就会更愿意,放弃一定的电子密度,而本质上这正是你在,形成共价键时所需要做的,分享你的一些电子密度。

    麻省理工公开课 - 化学原理课程节选

  • And then even lower down, we have our bonded hydrogen molecule.

    然后继续降低,我们就有了通过共价键结合的氢分子。

    麻省理工公开课 - 化学原理课程节选

  • So specifically, today we're going to talk about covalent bonds.

    特别地,今天我们要专门讲一讲共价键

    麻省理工公开课 - 化学原理课程节选

  • And he coined the term "polar covalency."

    他创造出还提出了一个属于有极性共价键

    麻省理工公开课 - 固态化学导论课程节选

  • What's the definition of the covalent bond?

    共价键的定义是什么?

    麻省理工公开课 - 固态化学导论课程节选

  • Well, with covalent bonding, it's not so simple.

    但对于共价键就没这么简单了。

    麻省理工公开课 - 固态化学导论课程节选

  • And so this is the H-F bond in HF.

    所以这是氟化氢中的氢氟共价键

    麻省理工公开课 - 固态化学导论课程节选

  • And he coined the term covalent bonding.

    他创造了共价键这一概念。

    麻省理工公开课 - 固态化学导论课程节选

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