• And so, each hydrogen has access to each electron, and now we have a satisfied system.

    每个氢原子都有两个电子,这是一个令人满意的体系。

    麻省理工公开课 - 固态化学导论课程节选

  • If we want to talk about two hydrogen atoms, then we just need to double that, so that's going to be negative 2 6 2 4 kilojoules per mole that we're talking about in terms of a single hydrogen atom.

    而要讨论两个氢原子,我们只需要把它乘以二,因此应该是负的,2624,千焦每摩尔,这就是单个的氢原子的情况。

    麻省理工公开课 - 化学原理课程节选

  • This is the diagram taken right from your text, there are the two electrodes coming in and this is atomic hydrogen in the gas tube.

    这是从教科书上复制下来的图表,这里有两个电极进来,这是气体管中的氢原子

    麻省理工公开课 - 固态化学导论课程节选

  • So, we see that the two h atoms separate have a certain energy that's lower than when the electron's not with the atom.

    那么,我们看到两个分开的氢原子所具有的能量,比原子中没有电子时更低。

    麻省理工公开课 - 化学原理课程节选

  • We don't have two different species of hydrogen here, so the electrons are perfectly shared.

    我们没有两个不同源的氢原子,所以电子很好的而得到了平分。

    麻省理工公开课 - 固态化学导论课程节选

  • Essentially it would only allow for us to bond to two hydrogen atoms.

    本质上,它只能允许我们,和两个氢原子成键。

    麻省理工公开课 - 化学原理课程节选

  • So, if we talk about dissociating h 2, we're going from the h 2 molecule, and breaking this bond right in half, so we now have two individual hydrogen atoms here.

    那么,如果我们讨论的是离解氢分子,我们将从氢分子开始,使这个键断裂,一分为二,那么就得到了两个分开的氢原子

    麻省理工公开课 - 化学原理课程节选

  • So there's one electron in each hydrogen atom.

    所以每个氢原子中有两个电子。

    麻省理工公开课 - 化学原理课程节选

  • We've got an electron from each of the hydrogens.

    然后我们从氢原子那得到了两个电子。

    麻省理工公开课 - 固态化学导论课程节选

  • So, let's change our graph where we now have this zero point set as the two individuals hydrogen atoms, and then we see that our h 2 molecule is at the negative of the dissociation energy, or the negative what that bond strength is.

    那么让我们把曲线图中的零点能改到,两个分离的氢原子处,那我们就会看到,氢分子就是负的离解能,或者负的键的强度。

    麻省理工公开课 - 化学原理课程节选

  • Now here are these two isolated hydrogen atoms.

    现在这是两个分别独立的氢原子

    麻省理工公开课 - 固态化学导论课程节选

  • Both hydrogens are going to share equally.

    两个氢原子将平分能量。

    麻省理工公开课 - 固态化学导论课程节选

  • So we can have our two hydrogen atoms come in here, and what we will find is - now that we have all of our orbitals filled up -- so thinking about what this angle is here, would you expect it to be less than or greater than what we saw for ammonia before?

    我们在这里有两个氢原子,我们会发现,现在我们所有的轨道都填满了-,考虑一下这里的角度,你们觉得它比在氨中看到的,要大还是要小?

    麻省理工公开课 - 化学原理课程节选

  • So, if we look at this graph where what we're charting is the internuclear distance, so the distance between these two hydrogen atoms, as a function of energy, -- what we are going to see is a curve that looks like this -- this is the general curve that you'll see for any covalent bond, and we'll explain where that comes from in a minute.

    因此,如果我们来看一看这幅曲线图,这里我们画的横坐标是核间距,也就是这两个氢原子之间的距离,纵坐标是能量,我们看到的这是能量关于核间距的曲线-,这是一条普遍的曲线,在研究任何共价键时你都会遇到,我们马上就会解释一下它是怎么来的。

    麻省理工公开课 - 化学原理课程节选

  • So you can see here in this slide we have the atomic orbitals for the two hydrogen atoms, each of them have one electron in them, hydrogen has one electron in a 1 s orbital.

    从这个幻灯片你们可以看到我们,有这两个氢原子的原子轨道,每个上面有个电子,氢原子上面有一个电子在1s轨道上。

    麻省理工公开课 - 化学原理课程节选

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