And so, each hydrogen has access to each electron, and now we have a satisfied system.
每个氢原子都有两个电子,这是一个令人满意的体系。
If we want to talk about two hydrogen atoms, then we just need to double that, so that's going to be negative 2 6 2 4 kilojoules per mole that we're talking about in terms of a single hydrogen atom.
而要讨论两个氢原子,我们只需要把它乘以二,因此应该是负的,2624,千焦每摩尔,这就是单个的氢原子的情况。
This is the diagram taken right from your text, there are the two electrodes coming in and this is atomic hydrogen in the gas tube.
这是从教科书上复制下来的图表,这里有两个电极进来,这是气体管中的氢原子。
So, we see that the two h atoms separate have a certain energy that's lower than when the electron's not with the atom.
那么,我们看到两个分开的氢原子所具有的能量,比原子中没有电子时更低。
We don't have two different species of hydrogen here, so the electrons are perfectly shared.
我们没有两个不同源的氢原子,所以电子很好的而得到了平分。
Essentially it would only allow for us to bond to two hydrogen atoms.
本质上,它只能允许我们,和两个氢原子成键。
So, if we talk about dissociating h 2, we're going from the h 2 molecule, and breaking this bond right in half, so we now have two individual hydrogen atoms here.
那么,如果我们讨论的是离解氢分子,我们将从氢分子开始,使这个键断裂,一分为二,那么就得到了两个分开的氢原子。
So there's one electron in each hydrogen atom.
所以每个氢原子中有两个电子。
We've got an electron from each of the hydrogens.
然后我们从氢原子那得到了两个电子。
So, let's change our graph where we now have this zero point set as the two individuals hydrogen atoms, and then we see that our h 2 molecule is at the negative of the dissociation energy, or the negative what that bond strength is.
那么让我们把曲线图中的零点能改到,两个分离的氢原子处,那我们就会看到,氢分子就是负的离解能,或者负的键的强度。
Now here are these two isolated hydrogen atoms.
现在这是两个分别独立的氢原子。
Both hydrogens are going to share equally.
两个氢原子将平分能量。
So we can have our two hydrogen atoms come in here, and what we will find is - now that we have all of our orbitals filled up -- so thinking about what this angle is here, would you expect it to be less than or greater than what we saw for ammonia before?
我们在这里有两个氢原子,我们会发现,现在我们所有的轨道都填满了-,考虑一下这里的角度,你们觉得它比在氨中看到的,要大还是要小?
So, if we look at this graph where what we're charting is the internuclear distance, so the distance between these two hydrogen atoms, as a function of energy, -- what we are going to see is a curve that looks like this -- this is the general curve that you'll see for any covalent bond, and we'll explain where that comes from in a minute.
因此,如果我们来看一看这幅曲线图,这里我们画的横坐标是核间距,也就是这两个氢原子之间的距离,纵坐标是能量,我们看到的这是能量关于核间距的曲线-,这是一条普遍的曲线,在研究任何共价键时你都会遇到,我们马上就会解释一下它是怎么来的。
So you can see here in this slide we have the atomic orbitals for the two hydrogen atoms, each of them have one electron in them, hydrogen has one electron in a 1 s orbital.
从这个幻灯片你们可以看到我们,有这两个氢原子的原子轨道,每个上面有个电子,氢原子上面有一个电子在1s轨道上。
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