• So again, when we check these, what we want to see is that our z effective falls in between the two extreme cases that we could envision for shielding.

    所以当我们再一次检查这些时,我们想看到的是,有效电荷处于两种极端案例中,这两种极端案例。

    麻省理工公开课 - 化学原理课程节选

  • Again we have the charge of the nucleus on plus 2, +2 but let's say this time the electron now is going to be very, very close to the nucleus.

    对于我们的氦原子,我们有一次得到了原子核电荷为,但是我们说这次电子。

    麻省理工公开课 - 化学原理课程节选

  • So in other words, every time I merge the point that I kept emphasizing verbally there and that I'm only touching each number once, means that we have to account for the amount of time it takes to merge N which is going to be just N. Now, this is again one of these cyclical answers.

    换言之,之前在做合并时,我不停地强调,对每个数字我只碰了一次,这就是说,我们要记录合并所花的时间,也就是这里的,这又是一种循环性的答案。

    哈佛公开课 - 计算机科学课程节选

  • We want to have that definition clear because in fact we're going to, we might want tabulate heats of reaction, right, and of course want to know what the conditions are for the tabulated values apply. And we're going to want to calculate them from other quantities and again, we're going to need to know each case what are the relevant conditions?

    我们想要明确这个定义,因为实际上我们会想把,反应热制成表格,当然我们会,想知道表中的数据在什么样的,条件下是有效的,我们会,想要从其他的中算出它们,再一次,我们需要知道,每种情形下相关的条件是什么?

    麻省理工公开课 - 热力学与动力学课程节选

  • So we know that we can relate to z effective to the actual energy level of each of those orbitals, and we can do that using this equation here where it's negative z effective squared r h over n squared, we're going to see that again and again.

    我们知道我们可以将有效电荷与,每个轨道的实际能级联系起来,我们可以使用方程去解它,乘以RH除以n的平方,它等于负的有效电荷的平方,我们将会一次一次的看到它。

    麻省理工公开课 - 化学原理课程节选

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