• We said that's the 1 s orbital.

    我们1s轨道

    youdao

  • And how many nodes do you see in the 3 s orbital?

    3s轨道多少个节点呢?

    youdao

  • The graph to the left, this is the s orbital, symmetric.

    左边对称S轨道,对称的。

    youdao

  • So we can also look at this in terms of the 3 s orbital.

    我们可以同样来看3s轨道

    youdao

  • So for a 2 s orbital, how many total nodes will we have?

    对于2s轨道多少节点

    youdao

  • And we call that, for this case, our sigma 2 s orbital.

    对于这种情况我们可以叫sigma2s轨道。

    youdao

  • So we expect to see two nodes right here in the 3 s orbital.

    所以3s轨道中我们预计看到两个节点

    youdao

  • And yet, we know that the shape of the s orbital is spherical.

    并且我们知道S轨道球状

    youdao

  • In both cases we're taking an electron out of the 2 s orbital.

    这两种情况下我们拿走了一个2s,电子。

    youdao

  • So that's the 1 s orbital - we have n squared or 1 degenerate orbitals.

    所以1s轨道,我们n平方,或者1个简并轨道

    youdao

  • And it turns out that for a 2 s orbital, that's equal to 6 times a nought.

    对于2s轨道等于6a0

    youdao

  • We talked about the wave function for a 2 s orbital, and also for a 3 s orbital.

    我们2s轨道函数讲过3s轨道。

    youdao

  • And for a 2 s orbital, you get a graph that's going to look something like this.

    对于2s轨道你们可以得到一个大致是这样

    youdao

  • But you should see that there are four radial nodes here since we have a 5 s orbital.

    你们应该知道这里4个节点因为它是5s轨道

    youdao

  • The space shuttle Columbia was the first space worthy shuttle in NASA 's orbital fleet.

    哥伦比亚号航空航天飞机美国航天局轨道船队第一有价值空间航天飞机。

    youdao

  • And in the case of the 3 s orbital, that's going to be equal to 11. 5 times a nought.

    对于3s轨道等于11.5a0

    youdao

  • Swe don't have to hybridize it, it already has only one unpaired electron in a 1 s orbital.

    s -我们不用杂化,它已经而且仅有一个未配对电子s轨道里

    youdao

  • Let's consider again an s orbital for argon, so let's say we're looking at the 1 s orbital for argon.

    我们考虑一次s轨道所以我们我们1s轨道。

    youdao

  • First of all, this is the two s orbitals in hydrogen, 1s plus 1s smearing to give us this sigma molecular orbital.

    首先氢气中的两个s轨道1s与1s轨道重叠,产生sigma分子轨道

    youdao

  • Because we have paired set in a 2 s orbital, so all we're left essentially is two electrons that are available for bonding.

    因为我们一对2s轨道里已经配对了,所以剩下两个电子可以用来成键。

    youdao

  • If you compare the s orbital with the bottom lobe, these have a different sign so they're going to destructively interfere.

    如果你们比较s轨道下面它们正负号相反,所以它们干涉

    youdao

  • So, what you find with the s orbital, and this is general for all s orbitals is that all of your nodes end up being radial nodes.

    对于s轨道你们会发现所有节点径向节点。

    youdao

  • For example, for the 2 s, again what you see is that the multi-electron atom, its 2 s orbital is lower in energy than it is for the hydrogen.

    举例来说对于2s轨道,在多电子原子,可以看到的2s轨道能量低于氢原子

    youdao

  • So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.

    所以沿着轴方向的,而且这里sp2杂化轨道一个1s轨道的结合,在这里我们可以合并他们。

    youdao

  • This is the radial probability distribution formula for an s orbital, which is, of course, dealing with something that's spherically symmetrical.

    这个s轨道径向概率分布公式对于对称情形成立。

    youdao

  • For example, when we're talking about radial probability distributions, the most probable radius is closer into the nucleus than it is for the s orbital.

    举例来说我们讨论径向概率分布时,距离原子核可能半径s轨道半径,更的可以离原子核多近。

    youdao

  • And if we think about the six hydrogens, now each of those are going to bind by combining one of the carbon hybrid orbitals to a 1 s orbital of hydrogen.

    如果我们考虑六个氢原子每个会合起来化轨道成键,每个氢1s轨道

    youdao

  • So for example, if you know how to draw an s orbital for a hydrogen atom, then you already know how to draw the shape of an s orbital or a p orbital for argon.

    个例子,如果你们知道如果,氢原子s轨道那么你们已经知道如何,画氩s轨道p轨道的形状

    youdao

  • So for example, if you look at the 1 s orbital here, you can see that actually it is lower in the case of the multi-electron atom than it is for the hydrogen atom.

    所以举例来说,如果看到这里1s轨道,你可以看到实际上多电子原子情况

    youdao

  • Another thing to point out in these two graphs is that we do have nodes, and we figured out last time, we calculated how many nodes we should have in a 2 s orbital.

    另外张图上指出我们可以看到节点上次我们知道,我们算了2s轨道多少个节点。

    youdao

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