Diastereoselective transfer of the diazene hydrogen to one face of the prochiral alkene was studied.
研究了重氮烯氢向前手性烯烃单侧的非对映选择性转移。
The review is focused on the recent development of asymmertric synthesis of chiral epoxides by biocatalyzing prochiral alkenes.
手性环氧化物在合成上具有重要的应用价值。
In this review, asymmetric reduction of prochiral ketones and its recent advances have been described according to the reaction types.
按反应类型分类，综述了酮的不对称还原方法及其近年来的新进展。
The most efficient way to generate chiral sulfoxides is asymmetric oxidation of prochiral sulfides Catalyzed by chiral metal complexes.
手性金属络合物催化硫醚的不对称氧化是合成手性亚砜最有效的方法。
One of the applicable strategies for construction of these moleculars is asymmetric transformations of prochiral trifluoromethylated compounds.
其中通过催化不对称转化潜手性三氟甲基化合物是合成这类化合物的重要策略之一。
Asymmetric hydroboration is a kind of widely applied and valuable reaction, in which borane reduction of prochiral ketones reaction is an important method.
不对称催化硼氢化反应是应用广泛且具有工业价值的反应，其中的硼烷还原前手性酮反应有着举足轻重的作用。
Recent advances in asymmetric hydrosilylation of prochiral carbonyl compounds catalyzed by chiral transition metal complexes are reviewed in this paper with47 references.
评述了近年来手性金属配合物催化的前手性羰基化合物的不对称硅氢化反应研究进展。
Abstract: Recent advances in asymmetric hydrosilylation of prochiral carbonyl compounds catalyzed by chiral transition metal complexes are reviewed in this paper with 47 references.
文摘：评述了近年来手性金属配合物催化的前手性羰基化合物的不对称硅氢化反应研究进展。
This review deals with the recent progress in asymmetric synthesis using chiral polymeric reagents and catalysts for oxidation, reduction, alkylation and addition of prochiral compounds.
本文综述了应用手性高分子试剂和催化剂对潜手性化合物通过不对称氧化、还原、烷基化、加成反应进行不对称合成的进展情况。
Biocatalytic reduction of the carbonyl groups or the carbon-carbon double bonds of the compounds has been utilized as a method for transforming the prochiral substrate into chiral product.
生物催化的还原反应能使分子内的羰基或碳-碳双键立体选择性的还原，将潜手性底物转化为手性产物，在不对称合成中有着重要的作用。
In this article, the recent application in recent years of metal complexes composed of binaphthyl derivatives in asymmetric hydrogenation of prochiral alkenes, ketones and imines are reviewed.
综述了近年来联萘衍生物作为手性配体构成的金属络合物在前手性烯、酮及亚胺的不对称氢化反应中的应用。
In this article, the recent application in recent years of metal complexes composed of binaphthyl derivatives in asymmetric hydrogenation of prochiral alkenes, ketones and imines are reviewed.
综述了近年来联萘衍生物作为手性配体构成的金属络合物在前手性烯、酮及亚胺的不对称氢化反应中的应用。
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