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  • When we talk about orbitals in multi-electron atoms, they're actually lower in energy than the corresponding H atom orbitals.

    当我们讨论多电子原子的轨道时,它们的能量实际上比对应的氢原子轨道要低。

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  • Doing those probability density dot graphs, we can get an idea of the shape of those orbitals, and we know that they're spherically symmetrical.

    通过那些概率密度图,我们可以知道轨道的形状,我们知道它们是球形对称的。

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  • So these are atomic orbitals.

    这是原子轨道。

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  • So now let's fill the orbitals.

    现在让我们把这些轨道填满。

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  • So, bonding orbitals are down here.

    所以成键轨道在下面。

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  • Let's occupy the orbitals.

    让我们占据这些轨道。

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  • So we end up having 2 orbitals here.

    所以我们得到2个轨道。

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  • What will we call that in terms of orbitals?

    我们从轨道的角度,怎么命名它?

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  • What is the filling sequence of electrons in orbitals?

    什么是电子在轨道上的排布顺序呢?

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  • And then we are going to construct molecular orbitals.

    接着我们就建立分子轨道。

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  • So the first is that the orbitals are similar in shape.

    首先是轨道的形状相似。

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  • So now let's go ahead and fill in our molecular orbitals.

    让我们继续填充分子轨道。

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  • Electrons fill orbitals from lowest energy to highest energy.

    电子从最低能级到最高能级,填满轨道。

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  • Linear combination of atomic orbitals into molecular orbitals.

    原子轨道的线性叠加,成分子轨道。

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  • That's what we call degenerate orbitals, they're the same energy.

    我们称之为简并轨道,它们具有相同的能量。

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  • So actually, first let's take a look at how we got these orbitals.

    首先我们来看一看我们怎么得到这些轨道的。

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  • When we're talking about orbitals, we're talking about wave functions.

    当我们说轨道的时候,我们说的是波函数。

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  • So we'll see specifically why it is that the s orbitals are lower in energy.

    所以我们会特别地看到,为什么s轨道的能量是较低的。

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  • We did it for the s orbitals, we can also do it for the p, we can do it for the d.

    我们对s轨道这样做了,我们也可以对p轨道这样做,对d轨道这样做。

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  • So we can add three hydrogen atoms here, and fill in our other orbitals right here.

    我们可以加三个氢原子到这里,填满其它的轨道。

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  • The only thing that is different about these orbitals is their orientation in space.

    这些轨道唯一的不同之处,是在空间的方向不同。

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  • Well, essentially what that tells is that these s orbitals are spherically symmetrical.

    实际上它告诉我们,这些s轨道,是球对称的。

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  • We'd started on Monday talking about radial probability distributions for the s orbitals.

    我们从星期一开始讨论了,s轨道的径向概率分布。

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  • So we would label our anti-bonding orbital higher in energy than our 1 s atomic orbitals.

    我们应该把反键轨道标在,高于1s原子轨道能量的地方。

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  • So in molecular orbital theory, what we did was we named orbitals based on their symmetry.

    在分子轨道理论中,我们基于轨道的对称性给它们命名。

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  • All right, so let's consider our methane situation now that we have our hybrid orbitals.

    好,让我们考虑甲烷的情形,既然我们有了杂化轨道。

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