And then we are going to construct molecular orbitals.
接着我们就建立分子轨道。
So now let's go ahead and fill in our molecular orbitals.
让我们继续填充分子轨道。
Linear combination of atomic orbitals into molecular orbitals.
原子轨道的线性叠加，成分子轨道。
This means we need a total of eight electrons in our molecular orbitals.
这意味着分子轨道里，一共有八个点子。
So, this means we have a total of six electrons that we need to put into molecular orbitals.
这意味着我们一共有，6个电子要放进分子轨道。
Degenerate outermost molecular orbitals is more easily formed when cluster has higher symmetry.
对称性较高的团簇容易形成近简并的最外层分子轨道。
So any time in a molecular orbital diagram you draw in orbitals, you need to draw the corresponding molecular orbitals.
任何时候你在分子轨道图里画轨道，你都要画出相对应的分子轨道。
So, we'll start today talking about the two kinds of molecular orbitals, we can talk about bonding or anti-bonding orbitals.
今天我们先来，讨论两种分子轨道，我们要讨论成键和反键轨道。
The relationship between the molecular orbitals energy levels and the biochemistry properties, electron spectrum are discussed.
分析分子轨道能级与生化性质和电子光谱的关系。
So we have a total of 2, 4, 6, 8, 10 valence electrons, so I'll make sure I count to 10 as we fill up our molecular orbitals here.
我们一共有2,4,6,8,10个价电子，所以我一边填一边要确认，我数到10。
So again you can see as we're filling up our molecular orbitals, we're using the exact same principle we used to fill up atomic orbitals.
当我们填充轨道的时候可以看到，我们用的是和，填充原子轨道一样的原则。
So specifically, what we do associate them instead is within molecular orbitals, and what we say is that they can be either in bonding or anti-bonding orbitals.
特别的，我们把它们和，分子轨道相联系起来，我们说它们可以成为，成键轨道或者反键轨道。
A novel tri-al function has been employed in the calculation, its determinant being composed of the localized molecular orbitals on the basis of the hydrogen-like functions.
在计算中使用了一种新的试探函数，其行列式部分由以类氢函数为基的定域分子轨道组成。
So, we'll start by taking a look at constructive interference, and another way to explain this is just to say again, molecular orbitals are a linear combination of atomic orbitals.
我们先来看一看相长干涉，另外一个解释它的方法就是说，分子轨道是原子轨道的组合。
So in molecular orbital theory, what we did was we named orbitals based on their symmetry.
在分子轨道理论中，我们基于轨道的对称性给它们命名。
Here is the atomic nitrogen, here is the atomic nitrogen and these are the orbitals of molecular nitrogen.
这是氮原子，这是氮原子，然后这是氮气的分子轨道。
So, if we look at the molecular orbital, that's actually going to be lower in energy than either of the two atomic orbitals.
如果我们看分子轨道的话，它实际上要比，两个原子轨道都要低。
Pi orbitals are a molecular orbital that have a nodal plane through the bond axis.
轨道是沿着键轴,有节面的分子轨道。
First of all, this is the two s orbitals in hydrogen, 1s plus 1s smearing to give us this sigma molecular orbital.
首先，这是氢气中的两个s轨道，1s与1s轨道重叠，产生sigma分子轨道。
The 1 s just comes from the fact that the molecular orbital is a combination of two 1 s atomic orbitals.
是因为分子轨道是两个,1s原子轨道的组合。
This paper briefly introduces the isolobal analogy model from 8 electron rule, 16-18 electron rule and molecular hybrid orbitals theory.
本文从八隅规则、16—18电子规则及杂化分子轨道内在联系简单地介绍了等叶片相似模型。
I am going to sum up the atomic orbitals that go into the molecular orbital, and they are going to have some coefficients.
我准备将原子轨道组合起来，进行分子轨道计算，这个过程还需添加一些系数。
So, let's think of the energy of interaction when we're comparing atomic orbitals to molecular bonding orbitals.
当我们比较原子轨道和分子轨道的时候，我们来考虑一下相互作用能。
So, let's think of the energy of interaction when we're comparing atomic orbitals to molecular bonding orbitals.
当我们比较原子轨道和分子轨道的时候，我们来考虑一下相互作用能。
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