气体通过金属-有机骨架材料吸附,随后改变条件以释放气体。
The gas is absorbed by the organometallic skeleton material and the conditions are subsequently modified in such a way that the gas is released.
得出,结构变形对吸附分子在柔性金属-有机骨架中的吸附和扩散性质有重要影响。
It could be concluded that structure deformation strongly affected the adsorption and diffusion characteristic of adsorbate in flexible metal-organic frameworks (MOFs).
然而,进一步的增加介孔孔径,多级孔道金属-有机骨架的比表面积降低,导致反应速率的降低。
However, further increase in mesopore size led to a decrease in the reaction rate, which is due to low surface area of the MOF material.
三嵌段共聚物P123,F127被选择作为超分子模板用以设计和构筑微-介孔多级孔道金属-有机骨架。
Triblock copolymers P123 and F127 were also chosen as supramolecular template to design and construct hierarchically micro-and mesoporous metal-organic framework.
然而,到目前为止多孔金属-有机骨架一直限制在微孔范围,其较小的孔道不利于物质扩散和传输,从而限制其实际应用。
However, to date porous MOFs are still largely restricted to the microporous regime despite negative impact of their small pore size on diffusion and mass transfer for their practical applications.
综述了多孔金属有机骨架配合物的性能特点、合成方法、控制途径及最新的研究方向。
This paper reviews functional properties, synthesis method, controlled path and the latest research methods of organic skeleton complex with porous metal.
金属有机骨架配合物是催化、分离、储存气体的理想材料,尤其在储存气体方面更是得到人们的广泛认可。
Metal organic frameworks are widely regarded as promising material for application in catalysis, separation, gas storage, especially attract considerable attention in gas storage.
将金属原子运用于配位聚合物里可能会有几个优点,即由非共价作用组装在一起的单一的有机链,网格或骨架。
The use of metal atoms in coordination polymers offers several possible advantages over purely organic chains, grids or frameworks which are organized by non-covalent interactions .
混合层包含不含氮原子的有机化合物,即不含有芳胺骨架的有机化合物,和金属氧化物。
The mixed layer contains an organic compound which contains no nitrogen atoms, i. e. , an organic compound which dose not have an arylamine skeleton, and a metal oxide.
根据所述方法,在有利于气体吸附的条件下,使所要存储的气体与电化学制备的有机金属骨架材料 接触。
According to said method, the gas to be stored is brought into contact with an electrochemically produced, organometallic skeleton material in conditions that are favourable for gas absorption.
根据所述方法,在有利于气体吸附的条件下,使所要存储的气体与电化学制备的有机金属骨架材料 接触。
According to said method, the gas to be stored is brought into contact with an electrochemically produced, organometallic skeleton material in conditions that are favourable for gas absorption.
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