近年来,人们利用含氧多羧酸配体构筑出大量具有新颖拓扑结构的金属-有机配位聚合物。
Recently, people have synthesized a lot of metal-organic coordination polymers with novel topological structure by using N-heterocyclic carboxylic acid ligands.
本文对柔性、刚性有机羧酸配体的新型金属-有机配位聚合物的合成、表征及催化性能进行了研究。
In this paper, the synthesis, characterization and the catalytic performance of the coordinated polymers constructed by the flexible or rigid carboxylic ligands were studied.
过渡金属配位聚合物的研究,不仅沟通了无机与有机化学的研究,而且集基础研究与应用研究于一体。
The research on transition metal coordination polymers not only connects inorganic and organic chemistry but also involves basic theory and applications.
将金属原子运用于配位聚合物里可能会有几个优点,即由非共价作用组装在一起的单一的有机链,网格或骨架。
The use of metal atoms in coordination polymers offers several possible advantages over purely organic chains, grids or frameworks which are organized by non-covalent interactions .
同时,还可以通过选择功能性的中心金属离子和具有功能官能团的有机配体赋予目标金属配位聚合物以光、电、磁等功能。
At the same time, metal coordination polymers can be endowed with optics, electric and magnetism by selecting functional metal ions and organic ligands with functional groups.
同时,还可以通过选择功能性的中心金属离子和具有功能官能团的有机配体赋予目标金属配位聚合物以光、电、磁等功能。
At the same time, metal coordination polymers can be endowed with optics, electric and magnetism by selecting functional metal ions and organic ligands with functional groups.
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