本文评述了近年来在手性高分子金属络合催化的不对称有机反应方面的研究进展。
Recent advances in asymmetric organic reactions catalyzed by chiral polymeric metal complexes are reviewed in this paper with 16 references.
手性金属络合物催化硫醚的不对称氧化是合成手性亚砜最有效的方法。
The most efficient way to generate chiral sulfoxides is asymmetric oxidation of prochiral sulfides Catalyzed by chiral metal complexes.
过渡金属氢化物在络合催化中占有重要的地位。
Metal hydride compounds play a central role in coordination catalysis.
用双金属氰化物(DMC)络合催化剂可制得相对分子质量高、相对分子质量分布窄和不饱和度低的聚醚多元醇。
The polyether polyols which has higher molecular weight, narrower molecular weight distribution and lower unsaturation can be prepared by using double metal cyanide (DMC) complex catalysts.
络合反应使一氧化碳活化，因此，金属羰合物是有机合成中的优良催化剂。
Complexing reaction activates the carbon monoxide, so that the metallic carbonyl complexes are excellent catalysts in the organic synthesis.
杂环卡宾金属络合物对许多反应有催化作用，它们是一类有潜在应用价值的催化剂。
N-heterocyclic carbene metal complexes have catalytic activities for many organic reactions, and they are a type of catalyst with potential value.
综述了各种金属络合物催化剂在分子氧作为氧化剂在醇的氧化、烯烃的环氧化上的应用。
The application of metal complex as the catalysts of aerobic oxidation of alcohols and epoxidation of alkenes are reviewed.
对后过渡金属镍络合物及其催化烯烃聚合的研究进展进行综述。
Progress on synthesis of post transition metal nickel complex and its application as catalyst in olefin polymerization was reviewed.
当紫外—可见光谱证明表面活性剂与金属催化剂有明显络合作用时，表面活性剂的加入便会显著改变振荡反应的t。
The addition of the surfactant can change considerably the oscillating lasting time when there is an obvious coordination between the surfactant and the metal catalyst.
络合及键合型高分子金属催化剂是高分子催化剂的重要研究方向之一，具有独特的催化效应及一定的应用前景。
The complex and bonded types of polymer-metal catalysts are the important researching direction on polymeric catalysts. And they have excellent catalytic efficiency and certainly applying prospect.
综述了异羟肟酸类化合物的合成及其近年来在催化氧化和高选择性络合金属离子的应用研究新进展。
This article reviews the synthesis of hydroxamic acid, and its new applications in the fields of catalytic oxidation as well as highly selective complexation with metal ions.
概括了近年来C_2轴手性双恶唑啉试剂及其金属络合物的合成及在催化不对称合成应用上的研究进展。
This review describes recent advances in the synthesis of C_2-symmetric chiral bis (oxazoline) ligands and the utility of its metal complexes in the catalysis of asymmetric syn - thesis.
综述了手性配体金属络合物催化剂催化1,3 -偶极环加成反应的研究进展。
The research advances of the chiral ligands metal complexes catalysts used in asymmetric 1, 3-dipolar cycloaddition reactions were reviewed in this paper.
对近年来过渡金属络合物对酮类化合物不对称催化氢化反应研究进展进行了综述。
The recent progress of the ketones in catalytic asymmetric hydrogenation is reviewed in this paper.
采用共沉淀法和金属有机络合物固载法，分别制备了钴氧化物负载的纳米金催化剂。
Cobalt oxide supported nanometer gold catalysts were prepared by coprecipitation and organo-gold complex grafting method respectively.
双核金属络合物是当前金属有机化学的研究热点之一，由于两个金属中心可以协同作用，从而显示出较高的反应活性和催化性能。
Increasing attention has been paid to dinuclear metal complexes, due to the significant cooperative effect of both metal centers on their reactivity and catalytic applications.
双核金属络合物是当前金属有机化学的研究热点之一，由于两个金属中心可以协同作用，从而显示出较高的反应活性和催化性能。
Increasing attention has been paid to dinuclear metal complexes, due to the significant cooperative effect of both metal centers on their reactivity and catalytic applications.
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