结果在煎煮过程中双酯型生物碱溶解并发生水解反应 ,而脂类生物碱则难溶于水。
Results The results showed that the DDAs were solved and reduced by hydrolysis reaction, and the lipo-alkaloids were difficult to be soluted in the Decoction.
方法:采用酸性染料比色法测定附子总生物碱含量,反相高效液相色谱法测定双酯型生物碱含量,蒽酮-硫酸法测定多糖含量。
METHODS: The contents of total alkaloids, diester diterpenoid alkaloids and polysaccharides were measured by acid dye colorimetry, HPLC and sulphuric acid-anthrone colorimetric method respectively.
生川乌炮制后生物碱大多数由双酯型水解转化为单酯型,水解反应最容易发生的位置在C8位,水解反应的类型是烷氧键发生断裂的酯的碱性水解。
After processing of crude aconite roots, most of the diester diterpenoid alkaloids converted to the monoester form, while C8 was the major location for such reaction. It is a ty…
三酯型乌头生物碱的C位乙酰基被各种长链脂肪酰基取代的酯交换反应为首次报道。
It is the first time to report that C8-acetyl is displaced by long chain fatty acyl for triester-aconitines in the ester-exchange reactions.
三酯型乌头生物碱的C位乙酰基被各种长链脂肪酰基取代的酯交换反应为首次报道。
It is the first time to report that C8-acetyl is displaced by long chain fatty acyl for triester-aconitines in the ester-exchange reactions.
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