第三章，过渡金属配位聚合物研究概况；
Third chapter, transition metal coordinate polymer research survey;
本发明涉及一种高核锌配位聚合物及其制备方法与应用。
The invention relates to a high nuclear zinc coordination polymer, and a coordination preparation process and the application thereof.
叙述了国际、国内金属配位聚合物的研究现状及应用前景。
This paper discusses current domestic and international research and the application prospect of metallic coordination polymer.
以二茂铁甲酸根为配体合成了一维链状结构的锰配位聚合物。
A one-dimensional structure coordination polymer of manganese with ferrocenecarboxylato as ligand has been synthesized.
多羧酸类化合物在配位聚合物的合成中是很有价值的配体之一。
Polycarboxylic acids are one of the valuable donators in the synthesis of coordinate polymers.
构筑配位聚合物时首先要考虑配体的几何构型和金属离子的配位倾向性。
The geometric configuration of ligand and the coordination tendency of metal cation should be considered when constructing the coordination polymers.
三维结构配位聚合物的自聚焦或自散焦效应主要受中心金属离子价层电子构型的影响。
Three dimensional coordination polymers show self defocusing or self focusing effects depending on the valence shell structures of the central ions.
因此，有目的的控制合成具有预期结构与性能的配位聚合物一直是化学家所追求的目标。
So, chemists have been pursuing to design and synthesize the expected structures of coordination polymers with excellent properties.
讨论了影响配合物结构的一些因素；金属离子和配体等。也研究了配位聚合物的反应条件。
The factors of influencing coordinate polymer structure, such as metal ions and ligand, were discussed. The reaction conditions of coordinate polymer were studied.
近年来，人们利用含氧多羧酸配体构筑出大量具有新颖拓扑结构的金属-有机配位聚合物。
Recently, people have synthesized a lot of metal-organic coordination polymers with novel topological structure by using N-heterocyclic carboxylic acid ligands.
稀土金属的双膦酸酯配合物及配位聚合物的合成、结构和催化性质已引起了人们的广泛关注。
The syntheses, structures and catalysis properties of rare earth complexes and polymers with diphosphonate have been extensively attracted.
本文概括了配位聚合物的三阶非线性光学性质，并总结了其结构与三阶非线性光学性质之间的关系。
In this paper, we review the third order NLO properties of coordination polymers, and summarize the relationship between the crystal structures and the third order NLO properties.
本文对柔性、刚性有机羧酸配体的新型金属-有机配位聚合物的合成、表征及催化性能进行了研究。
In this paper, the synthesis, characterization and the catalytic performance of the coordinated polymers constructed by the flexible or rigid carboxylic ligands were studied.
过渡金属配位聚合物的研究，不仅沟通了无机与有机化学的研究，而且集基础研究与应用研究于一体。
The research on transition metal coordination polymers not only connects inorganic and organic chemistry but also involves basic theory and applications.
因此，我们开展了以水杨醛缩取代苯氧乙酰腙的铜、锰配位单元为节点的配位聚合物的结构化学的研究。
So we developed the study on structural chemistry of Cu and Mn coordination polymers with substituted phenoxyacetyl ligands.
将金属原子运用于配位聚合物里可能会有几个优点，即由非共价作用组装在一起的单一的有机链，网格或骨架。
The use of metal atoms in coordination polymers offers several possible advantages over purely organic chains, grids or frameworks which are organized by non-covalent interactions .
同时，还可以通过选择功能性的中心金属离子和具有功能官能团的有机配体赋予目标金属配位聚合物以光、电、磁等功能。
At the same time, metal coordination polymers can be endowed with optics, electric and magnetism by selecting functional metal ions and organic ligands with functional groups.
根据配位聚合物的研究状况并结合本研究组的近期工作，分析讨论了配位聚合物的分子设计和组装，及其组成-结构-性能关系。
As new optical functional complexes, coordination polymers have been synthesized via molecular design and spontaneous assembly, and their composition-structure-property relationships are cons...
结果表明，聚合体系符合配位聚合的机理，聚合物结构具有一定的有序性。
The results indicate that the polymerization mechanism is coordination polymerization and the polymer has stereospecific structure.
助催化剂是烯烃配位聚合催化剂的重要组成部分。它不仅可以影响聚合活性，而且对所得聚合物的结构和性质也有明显的影响。
Activator is an important component of catalyst system for olefin coordination polymerization, which affects not only polymerization activity but also structure and property of resulting polymer.
助催化剂是烯烃配位聚合催化剂的重要组成部分。它不仅可以影响聚合活性，而且对所得聚合物的结构和性质也有明显的影响。
Activator is an important component of catalyst system for olefin coordination polymerization, which affects not only polymerization activity but also structure and property of resulting polymer.
应用推荐