• 讨论室温条件下转动配分函数应采用的形式。

    The rotational partition function and thermodynamical properties of hydrogen;

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  • 平动函数乘以,振动配分函数,乘以转动配分函数等等

    The translational partition function times the vibrational partition function, times the rotational partition function, et cetera.

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  • 其中,转动分函数考虑离心扭曲修正,振动配分函数采用谐振近似

    The calculation method for the vibrational partition sums Qvib used is the harmonic oscillator approximation.

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  • 考虑液体子间相互作用引入一个阻障因子修正转动振动对内配分函数贡献

    In consideration of the strong intermolecular interactions in liquids, a hindering factor is introduced to modify the contribution of their rotation and vibration to the internal partition function.

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  • 考虑液体子间相互作用引入一个阻障因子修正转动振动对内配分函数贡献

    In consideration of the strong intermolecular interactions in liquids, a hindering factor is introduced to modify the contribution of their rotation and vibration to the internal partition function.

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