研究了含吡啶-3-磺酸配体的超分子体系的构筑。
The supramolecular compounds with ligand of pyridine-3- sulfonate were prepared .
研究发现它们能引起脂质膜超分子体系液晶态结构的变化。
It was found that they can make conformational change of super-molecular system in the liquid crystalline state.
化学计量法表明,所有的氨基酸均与环糊精衍生物形成了1:1的超分子体系。
The supramolecular system stoichiometry is 1:1 for all amino acid inclusion complexation with host compounds (1) and (3).
并以荧光光谱法测定了超分子体系的包结常数和包结比,对其包结机理进行了初步研究。
The formation ratio and binding constants of the supramolecular systems were determined by fluorescence spectrometry and an elementary research on its mechanism was performed.
在人工双层膜囊泡表面,构建了一个通过人工受体的分子识别行为控制酶反应活性的超分子体系。
Functionalized lipid bilayer vesicles on which molecular recognition by an artificial receptor synchronized with catalytic reaction by an enzyme were prepared in aqueous media.
通过这个系统,可以确定超分子体系中各个组成单元之间的相互作用,超分子体系的结构以及形成过程。
Using this system, we can study the intramolecular interaction in a supramolecular system and determine the molecular structures and the formation process of a supramolecular system.
结合笔者的工作,总结了近几年四氮杂卟啉及其金属配合物、聚合物和超分子体系研究的主要新进展和新成果。
Combined with the series of works made by the authors, the recent progresses in the research of porphyrazines and their complexes were reviewed.
单体酶、寡聚酶、多酶体系和酶分子机器是理想的天然模型超分子。
Monomeric enzyme, oligomeric enzyme, multienzyme system and enzymatic molecular device are ideal model supramolecules.
合成双分子膜是近年来出现的一类重要的超分子化学体系。
Synthetic bilayer membrane exploited in the recent years is one of important supramolecular systems.
索烃这类具有重要拓扑学特征的分子体系在超分子化学、分子生物学及分子电子器件材料等领域具有十分重要的作用。
Catenanes have special topologic features and have important potential application future in supramolecular chemistry, molecular electronic devices and photo-electronic materials etc.
在新世纪的开始,将各种功能引入这些多金属体系已经成为金属超分子化学届的一大目标。
In the new century, the introduction of the various features into these multi-metal systems has become a major goal of the Supramolecular Chemistry.
超分子凝胶通过外界刺激可以可逆变化的性质为利用刺激可控催化体系提供了基础。
The reversible nature of supramolecular gels seems ideal for the use of stimulus-controlled catalytic systems by environmental stimuli.
若选择合适的构造子并将其作恰当修饰,则有可能通过调节构造子间的超分子作用来调控体系的流变学行为。
If the building blocks are chose and modified rightly, it is possible to control the rheology properties by tuning the supramolecular interactions between building blocks.
超分子化学的研究范围是由两个或更多的化学实体通过分子间弱相互作用而构建的高度有序及复杂性的体系。
The study field of supramolecular chemistry is high-order and complicated system constituted from two or more moleculars through weak interaction between different molecules.
这是因为有序超分子组装体系不仅能够增强有机功能分子的原有功能,而且往往赋予材料许多新的功能。
This is all the more true because the various functions of single molecules can be considerably enhanced within ordered supramolecular assemblies.
根据超分子化学基本原理,利用谱学方法和显微技术,以胶原蛋白、多糖等生物大分子为超分子模板,建立体外模拟体系。
Based on the primary principles of supramolecular chemistry, biomacromolecules such as polysaccharides or proteins are used as supramolecular template to found simulation systems in vitro.
双亲嵌段共聚物在不同体系下会自组装成各种形貌的超分子聚集体,是目前人们研究的热点,并在工业领域得到了广泛应用。
Amphiphilic block copolymers can form aggregates with various morphologies. As a result, they are an important class of surfactants and find widespread industrial applications.
双亲嵌段共聚物在不同体系下会自组装成各种形貌的超分子聚集体,是目前人们研究的热点,并在工业领域得到了广泛应用。
Amphiphilic block copolymers can form aggregates with various morphologies. As a result, they are an important class of surfactants and find widespread industrial applications.
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