对巯基丙酸自组装膜的酸碱平衡进行研究。
The acid base equilibrium of self assembly monolayer (SAM) of mercaptopropionic acid was studied.
目的建立一种形成高分子自组装膜的新方法。
Objective To set up a new method of forming macromolecule self-assembled monolayers.
自组装膜的增长和结构取决于体系中吸附和解吸的平衡。
The multilayer growth and architecture depend on the adsorption and desorption equilibrium in the systems.
对固体表面树枝状分子自组装膜的制备策略进行了综述。
The recent progress in the synthetic strategy of dendritic self-assembled molecular layers was reviewed.
讨论了不同的端基对偶氮生色团在自组装膜中初始取向的影响。
Influences of substituents on the orientation of the azo chromophores were discussed in detail.
结果表明，热自组装膜改善了镁基生物材料的腐蚀抗力和生物活性。
The results showed that the corrosion resistance and bioactivity of the bio-magnesium materials with heat-self-assembled monolayer were improved.
藉金硫键将二苯基硫脲组装在金电极上，形成二苯基硫脲自组装膜电极。
Diphenylthiourea were assembled onto the gold electrode surface with Au-S bond to form a diphenylthiourea self-assembled monolayers(SAMs) Au electrode.
比较了不同金属离子对叶琳自组装膜性质的改变和对自组装膜催化能力的影响。
The difference of the catalytic capacity with different metal ions in SAMs were compared.
用偏振紫外光谱研究了两种侧链偶氮聚电解质静电逐层自组装膜中偶氮生色团的初始取向。
Orientation of azobenzene units in self assembled multilayer films of two side chain azo polyelectrolytes was investigated by using polarized UV Vis absorption spectroscopy.
利用本实验室自制的电容实时测量装置对巯基丙酸自组装膜的表面酸度进行电容滴定研究。
The acid base equilibrium of self assembly monolayer(SAM) of mercaptopropionic acid on gold electrode was studied by capacitance titration.
本文将纳米金与自组装膜相结合制备的修饰电极，可应用到复杂体系中重金属离子的溶出伏安分析。
In this thesis, gold nanoparticles and self-assembled monolayer doubly modified electrode were used for the stripping voltammetric determination of heavy metal ions in the complex samples.
利用磷脂自组装膜在分子水平上研究生物分子的结构和性能，在生物学和仿生学方面有重要研究意义。
Self-assembled lipid films provide new insights into the structure-function relationships of biomolecules at the molecular level. It has potential applications in biology and bionics.
用循环伏安法和电化学交流阻抗谱技术，对上述自组装膜进行了表征，初步研究了这些自组装膜的结构。
The electrochemical cyclic voltammetry and electrochemical impendence spectra were employed to characterize the structures and the properties of the above mentioned SAMs on gold.
通过自组装修饰金电极的界面微分充电电容和膜的覆盖率考察了NS在环己烷中自组装膜的成膜动力学。
Using electrode interface capacitance and surface coverage to investigate the formation kinetics of NS monolayer in hexahydrobenzene solvent.
较低的溶液浓度和适宜的反应时间有利于MPS分子在羟基化表面形成排列规则、结合紧密的自组装膜层。
With both low MPS concentration and suitable immersion time, a well-ordered and closely self-assembled MPS layers could be prepared on the hydroxylated surface.
结果表明，6 -MHA在金电极表面能够形成一层稳定的自组装膜，并对叶绿素的氧化还原过程具有明显的催化作用。
The results show that 6 MHA can form stable SAM on gold electrode, and this 6 MHA SAM electrode has obvious catalysis for the REDOX reaction of chlorophylls.
首先采用传统自组装方法在氢终止的硅表面上制备了十六烯自组装分子膜，并利用X射线光电子能谱和拉曼光谱技术对自组装膜进行了检测。
First of all, 1-hexadecene self-assembled monolayers was fabricated on hydrogen-terminated silicon surface by traditional way and was checked by XPS and Raman spectrum technology.
还利用短链硫醇分子和短链、长链硫醇分子形成的混合自组装膜，研究了自组装膜表面的酸性基团的解离性质和混合自组装膜的选择性解吸研究。
The mixed SAMs have also been prepared, the features of dissociation activity of acidic group in the interface and selective desorption have also been studied.
实验结果表明，下面的几个因素影响着吡咯在自组装膜上的聚合：L-半胱胺酸在混合膜中的比例、支持电解质p H的大小以及聚合单体分子的大小。
The results show that the following factors affect the polymer growth. They are the pH value of the supporting solution, the ratio of the reductive desorption L …
用扫描电化学显微镜的线扫描的方法研究咪唑啉分子吸附在铁的表面形成的自组装单分子膜。
The performance of corrosion inhibition of self-assembled monolayers of imidazoline formed on iron substrate was characterized by means of scanning electrochemical microscopy.
酶电极制作中，先在金电极表面自组装一层半胱胺单层膜，再用戊二醛交联hrp。
For the fabrication of HRP electrode, cysteamine was first self-assembled onto the surface of the gold electrode, and then HRP was immobilized onto the electrode through glutaraldehyde.
对于致密有序的自组装分子膜，在摩擦力与载荷间存在“平台”效应。
There existed a "Platform" effect between the frictional force and the load for fine packed OTS self-assembled molecule film.
本文围绕阻止生物膜形成这一主线，并采用层层静电自组装技术，构建了以下抗菌涂层。
The chitosan as an antibacterial agent and the heparin as an anti-adhesion agent were successfully deposited onto the aminolyzed PET by the layer-by-layer self assembly technology.
试验结果表明，该体系成膜过程为单体分子先自组装，然后再聚合，通过一步工序即可制得完整的保护膜。
The experiments results showed that, in the course of forming film, first monomer molecule assembled, then polymerized, through one process complete film was prepared.
研究了离子自组装技术成膜原理、特点及应用，探讨了影响离子自组装技术的因素。
The paper studies the principle of film fabrication, characteristic and application of this technology. In additional discusses on the influencing factors.
缓蚀剂的作用机理与缓蚀剂分子在金属表面形成的自组装单分子膜及其作用密切相关。
The working mechanism of corrosion inhibitors is in close relationship with the formation of inhibitor self- assembled monolayers (SAMs) on metal surfaces.
从苯胺单体出发，通过原位聚合、现场掺杂以及基于静电力的层层自组装制备了聚苯胺复合膜。
Polyaniline (PANI) composite films were prepared from aniline monomers by in situ polymerization, acid-doping and layer-by-layer self-assembly through the electrostatic force.
用电聚合的方法在金电极上制备了以对硫磷为模板分子的自组装邻氨基硫酚分子印迹膜传感器。
A novel electrochemical sensor for the detection of parathion based on molecularly imprinted polymer of self-assembled o-aminothiophenol onto gold electrode was constructed.
相反电荷的聚电解质在溶液中通过静电相互作用自组装形成超薄多层膜，这种膜的结构可实现分子水平上的控制。
The ultrathin multilayer films were built-up by self-assemble of oppositely charged polyelectrolytes in aqueous solution. Its structure can be designed at molecular scale.
相反电荷的聚电解质在溶液中通过静电相互作用自组装形成超薄多层膜，这种膜的结构可实现分子水平上的控制。
The ultrathin multilayer films were built-up by self-assemble of oppositely charged polyelectrolytes in aqueous solution. Its structure can be designed at molecular scale.
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